公开(公告)号：US06416569B1

公开(公告)日：2002-07-09

申请号：US09648802

申请日：2000-08-28

申请人： Martin Bülow ,  Adeola F. Ojo ,  Frank R. Fitch ,  Baldur Unger ,  Alfons Brandt

发明人： Martin Bülow ,  Adeola F. Ojo ,  Frank R. Fitch ,  Baldur Unger ,  Alfons Brandt

IPC分类号： B01D5304

CPC分类号： C01B39/023 ,  B01J20/186 ,  B01J2220/42 ,  Y02C10/08 ,  Y02C20/10

摘要： Nitrogen oxides and low molecular weight hydrocarbons are removed from air by subjecting the air to a temperature swing adsorption process using as the adsorbent a composite zeolite product containing both zeolite type A and zeolite type X. The composite zeolite product is prepared by crystallizing a sodium ion- or sodium ion- and potassium ion-containing alumina-silica hydrogel under conditions which result in the production of a zeolitic composite which contains both zeolite type A and zeolite type X crystal domains. In a preferred embodiment, calcium ions constitute a substantial number of the composite's exchangeable cations and the type X portion of the composite zeolite product has a silicon-to-aluminum atomic ratio in the range of 0.9 to less than 1.15. The nitrogen oxide- and hydrocarbon-selective adsorbent can be incorporated into an atmospheric air prepurification plant downstream of a water vapor-selective adsorbent and a carbon dioxide-selective adsorbent.

摘要翻译： 通过使空气进行变温吸附方法，从空气中除去氮氧化物和低分子量烃，使用含有沸石A型和沸石型X的复合沸石产物作为吸附剂。复合沸石产物通过使钠离子 - 或含钠离子和钾离子的氧化铝 - 二氧化硅水凝胶在导致生成含有A型沸石和X型晶体结构域的沸石复合材料的条件下进行。 在优选的实施方案中，钙离子构成了大量的复合材料的可交换阳离子，并且复合沸石产品的X型部分的硅 - 铝原子比在0.9至小于1.15的范围内。 氮氧化物和烃选择性吸附剂可以并入到水蒸汽选择性吸附剂和二氧化碳选择性吸附剂下游的大气空气预纯化装置中。

公开(公告)号：US06284021B1

公开(公告)日：2001-09-04

申请号：US09388883

申请日：1999-09-02

申请人： Yaping Lu ,  Shain-Jer Doong ,  Martin Bülow ,  Dongmin Shen ,  Divyanshu R. Acharya ,  Mark J. Andrecovich ,  Frank R. Fitch ,  Adeola Florence Ojo

发明人： Yaping Lu ,  Shain-Jer Doong ,  Martin Bülow ,  Dongmin Shen ,  Divyanshu R. Acharya ,  Mark J. Andrecovich ,  Frank R. Fitch ,  Adeola Florence Ojo

IPC分类号： B01D53047

CPC分类号： B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/0476 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2253/304 ,  B01J20/08 ,  B01J20/165 ,  B01J20/28004 ,  B01J20/28014 ,  B01J20/28016 ,  B01J20/28019 ,  B01J20/28021 ,  B01J20/2803 ,  B01J20/28078 ,  B01J20/3007 ,  B01J20/3042 ,  B01J20/3204 ,  B01J20/3238 ,  B01J20/3293 ,  B01J20/3433 ,  B01J20/3483 ,  B01J20/3491 ,  B01J2220/42

摘要： A gas separation process comprising feeding a gaseous mixture comprising at least two components having different adsorption characteristics into an adsorption vessel containing at least one adsorbent material capable of preferentially adsorbing at least one of the gaseous components in the gaseous mixture and subjecting the gaseous mixture to non-cryogenic conditions which enable the preferentially adsorbable gaseous component in the gaseous mixture to adsorb onto the adsorbent material and separate from the non-adsorbed component in the gaseous mixture which pass through the adsorbent vessel wherein at least one adsorbent material in the adsorbent vessel comprises a composite particle having an inner core comprising a non-porous, non-adsorbent material and at least one outer layer comprising the adsorbent material. In another embodiment of the process of the present invention a hollow particulate adsorbent material is utilized.

摘要翻译： 一种气体分离方法，包括将含有至少两种具有不同吸附特性的组分的气体混合物进料到含有至少一种能够优先吸附气态混合物中至少一种气态组分的吸附材料的吸附容器中， 使气态混合物中优先吸附的气体组分吸附在吸附材料上并与通过吸附剂容器的气态混合物中的未吸附组分分离的高温条件，其中吸附剂容器中的至少一种吸附材料包含 复合颗粒具有包含非多孔非吸附材料的内芯和至少一个包含吸附材料的外层。 在本发明方法的另一个实施方案中，使用中空颗粒吸附剂材料。

公开(公告)号：US06200366B1

公开(公告)日：2001-03-13

申请号：US09388105

申请日：1999-09-01

申请人： Martin Bülow ,  Chang Jie Guo ,  Dongmin Shen ,  Frank R. Fitch ,  Arthur I. Shirley ,  Virginia A. Malik

发明人： Martin Bülow ,  Chang Jie Guo ,  Dongmin Shen ,  Frank R. Fitch ,  Arthur I. Shirley ,  Virginia A. Malik

IPC分类号： B01D53047

CPC分类号： C07C7/13 ,  Y10S95/902 ,  C07C11/02

摘要： Ethene is separated from a gas mixture containing ethane by a pressure swing adsorption process carried out at a temperature in the range of about 50 to about 200° C., wherein the adsorption step of the process is conducted by passing the gas mixture through an adsorption zone containing type A zeolite whose exchangeable cations are preferably made up of at least about 60 but not more than 75% sodium ions and more than 25 and up to about 40 percent potassium ions.

摘要翻译： 通过在约50至约200℃的温度下进行的变压吸附方法将乙烯与含乙烷的气体混合物分离，其中该方法的吸附步骤是通过使气体混合物通过吸附 含有A型沸石的区域，其可交换阳离子优选由至少约60但不超过75％的钠离子和大于25和高达约40％的钾离子组成。

公开(公告)号：US07347887B2

公开(公告)日：2008-03-25

申请号：US11005579

申请日：2004-12-06

申请人： Martin Bülow ,  Jürgen Böer ,  Wolfgang Burckhardt ,  Hans Ulrich Guth ,  Helmut Ullmann ,  Vladimir V. Vashook

发明人： Martin Bülow ,  Jürgen Böer ,  Wolfgang Burckhardt ,  Hans Ulrich Guth ,  Helmut Ullmann ,  Vladimir V. Vashook

IPC分类号： B01D53/04

CPC分类号： C01B13/0255 ,  C01B3/382 ,  C01B2203/0244 ,  C01B2203/0844 ,  C01B2203/1258 ,  C01B2203/142 ,  C01B2203/82 ,  C01B2210/0046 ,  Y10S502/525

摘要： Composites and methods useful for oxygen sorption and other uses are presented, the composites comprising: (A) one or more crystalline ceramic oxides selected from compounds within general formula (1): AxA′x′ByB′y′O3-δ and   (1) (B) one or more crystalline ceramic oxides selected from compounds within general formulas (2), (3), (4), (5), (6), (7), and (8): A2BO4-δ  (2) A2B2O5-δ  (3) AO(ABO3-δ)n  (4) AM2Cu3O7-δ  (5) Bi4V2(1-x)Me2xO11-3x,  (6) A″B″O3  (7) A2B2O7-δ.   (8)

公开(公告)号：US06436171B1

公开(公告)日：2002-08-20

申请号：US09592351

申请日：2000-06-12

申请人： Qing Min Wang ,  Dongmin Shen ,  Miu Ling Lau ,  Martin Bülow ,  Frank R. Fitch ,  Norberto O. Lemcoff ,  Philip Connolly

发明人： Qing Min Wang ,  Dongmin Shen ,  Miu Ling Lau ,  Martin Bülow ,  Frank R. Fitch ,  Norberto O. Lemcoff ,  Philip Connolly

IPC分类号： B01D53047

CPC分类号： C07D487/22 ,  B01D53/02 ,  B01D2253/202 ,  B01D2257/104 ,  B01J20/22 ,  B01J20/26 ,  C01B13/0262 ,  C01B2210/0046 ,  C07C255/24 ,  C07C255/30 ,  Y10S95/90

摘要： The present invention provides for novel solid state O2-selective metal complex-based adsorbents and their utility for separating oxygen from a gas stream. In particular, the invention provides for an adsorption complex which contains four-coordinate O2-selective metal complexes including oligomeric/polymeric metal complexes, and organic base-containing polymers supported on porous materials.

摘要翻译： 本发明提供新的固态O 2选择金属络合物基吸附剂及其从气流中分离氧的实用性。 特别地，本发明提供了一种吸附复合物，其包含四配位的O 2选择性金属络合物，包括低聚/聚合物金属络合物和负载在多孔材料上的含有机碱的聚合物。

公开(公告)号：US06432171B1

公开(公告)日：2002-08-13

申请号：US09648984

申请日：2000-08-28

申请人： Ravi Kumar ,  Madhusudhan Huggahalli ,  Martin Bülow

发明人： Ravi Kumar ,  Madhusudhan Huggahalli ,  Martin Bülow

IPC分类号： B01D5304

CPC分类号： B01D53/02 ,  B01D53/0462 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2257/404 ,  B01D2257/504 ,  B01D2257/702 ,  B01D2257/80 ,  B01D2259/4146 ,  B01D2259/416 ,  Y02C10/08 ,  Y10S95/902

摘要： The present invention provides for a thermal swing adsorption process for the removal of trace impurities such as oxides of nitrogen and hydrocarbons from air prior to its separation by cryogenic distillation. The process may utilize three adsorbent layers, the first primarily removes water; the second primarily removes carbon dioxide; and the third layer is a composite adsorbent layer which removes the oxides of nitrogen and hydrocarbons from the air stream. Another embodiment employs a two layer adsorbent system to remove the impurities. Additionally, a single layer of composite adsorbent may be used to remove water, carbon dioxide, oxides of nitrogen, and hydrocarbons from the air stream.

摘要翻译： 本发明提供一种用于在通过低温蒸馏分离之前从空气中除去微量杂质如氮氧化物和烃的热变形吸附方法。 该方法可以使用三个吸附剂层，第一个主要是去除水; 第二个主要是去除二氧化碳; 并且第三层是从空气流中除去氮和碳氢化合物的复合吸附剂层。 另一个实施方案采用双层吸附剂系统来除去杂质。 此外，单层复合吸附剂可用于从空气流中除去水，二氧化碳，氮氧化物和碳氢化合物。

公开(公告)号：US06407025B1

公开(公告)日：2002-06-18

申请号：US09501905

申请日：2000-02-10

申请人： Alfons Brandt ,  Baldur Unger ,  Hartmut Tschritter ,  Martin Bülow ,  Frank R. Fitch ,  Adeola F. Ojo

发明人： Alfons Brandt ,  Baldur Unger ,  Hartmut Tschritter ,  Martin Bülow ,  Frank R. Fitch ,  Adeola F. Ojo

IPC分类号： B01J2908

CPC分类号： B01J29/061 ,  B01J20/186 ,  B01J29/70 ,  B01J29/7049 ,  B01J37/30 ,  C01B39/026

摘要： Zeolites exchanged with lithium cations and polyvalent cations are prepared by first partially ion-exchanging a sodium-containing zeolite, a potassium-containing zeolite or a sodium- and potassium-containing zeolite with polyvalent cations, then heat-treating the partially polyvalent cation-exchanged zeolite, then ion exchanging the heat-treated zeolite with ammonium cations, and then reacting the ammonium cation-exchanged zeolite with a water-soluble lithium compound under conditions which result in the removal of ammonia from the reaction zone.

摘要翻译： 与锂阳离子和多价阳离子交换的沸石通过首先将含钠沸石，含钾沸石或含钠和钾的沸石与多价阳离子部分离子交换，然后热处理部分多价阳离子交换 沸石，然后将热处理的沸石与铵阳离子进行离子交换，然后使铵阳离子交换的沸石与水溶性锂化合物在导致从反应区除去氨的条件下反应。

公开(公告)号：US06238460B1

公开(公告)日：2001-05-29

申请号：US09277306

申请日：1999-03-26

申请人： Shuguang Deng ,  Ravi Kumar ,  Martin Bülow ,  Frank R. Fitch ,  Adeola Florence Ojo ,  Craig S. Gittleman

发明人： Shuguang Deng ,  Ravi Kumar ,  Martin Bülow ,  Frank R. Fitch ,  Adeola Florence Ojo ,  Craig S. Gittleman

IPC分类号： B01D53049

CPC分类号： B01D53/02 ,  B01D53/047 ,  B01D53/261 ,  B01D2253/104 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2256/22 ,  B01D2259/40052 ,  B01D2259/416 ,  Y02C10/08

摘要： Substantially all of the carbon dioxide is removed from a gas containing up to about 1% by volume carbon dioxide by subjecting the gas to a pressure swing adsorption process using a two layer adsorption system, wherein the first layer contains activated alumina and the second layer is a zeolite or a combination of zeolites having a silicon to aluminum atomic ratio of at least 1.5. The process is particularly suitable for removing substantially all carbon dioxide and water vapor contained in air prior to subjecting the air to cryogenic distillation.

摘要翻译： 通过使用双层吸附系统对气体进行变压吸附过程，基本上所有的二氧化碳从含有高达约1体积％二氧化碳的气体中除去，其中第一层含有活性氧化铝，第二层为 硅铝原子比至少为1.5的沸石或沸石的组合。 该方法特别适用于在空气进行低温蒸馏之前基本上除去空气中所含的二氧化碳和水蒸气。

公开(公告)号：US07338549B2

公开(公告)日：2008-03-04

申请号：US11005411

申请日：2004-12-06

申请人： Martin Bülow ,  Jürgen Böer ,  Wolfgang Burckhardt ,  Hans Ulrich Guth ,  Helmut Ullmann ,  Vladimir V. Vashook

发明人： Martin Bülow ,  Jürgen Böer ,  Wolfgang Burckhardt ,  Hans Ulrich Guth ,  Helmut Ullmann ,  Vladimir V. Vashook

IPC分类号： B01D53/02 ,  B01J20/00

CPC分类号： C01B13/0255 ,  C01B3/382 ,  C01B2203/0244 ,  C01B2203/0844 ,  C01B2203/1258 ,  C01B2203/142 ,  C01B2203/82 ,  C01B2210/0046 ,  Y10S502/525

摘要： Compositions and methods useful for oxygen sorption and other uses are presented, the compositions A composite material comprising components (A) and (B), wherein component (A) is selected from crystalline ceramic materials capable of forming a stable, reversible perovskite crystal phase at elevated temperatures (T>500° C.), and combinations thereof, and component (B) comprises a metal selected from rhodium (Rh), platinum (Pt), palladium (Pd), nickel (Ni) and silver (Ag), and combinations and alloys of these metals.

摘要翻译： 提供了可用于氧气吸附和其它用途的组合物和方法，组合物A包含组分（A）和（B）的复合材料，其中组分（A）选自能够形成稳定的可逆钙钛矿结晶相的结晶陶瓷材料 高温（T> 500℃）及其组合，组分（B）包括选自铑（Rh），铂（Pt），钯（Pd），镍（Ni）和银（Ag） 以及这些金属的组合和合金。

公开(公告)号：US06409800B1

公开(公告)日：2002-06-25

申请号：US09648982

申请日：2000-08-28

申请人： Adeola F. Ojo ,  Frank R. Fitch ,  Martin Bülow

发明人： Adeola F. Ojo ,  Frank R. Fitch ,  Martin Bülow

IPC分类号： B01D5304

CPC分类号： B01D53/02 ,  B01D53/0462 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2257/404 ,  B01D2257/504 ,  B01D2257/702 ,  B01D2257/80 ,  B01D2259/4143 ,  B01D2259/4146 ,  B01D2259/416 ,  Y02C10/08 ,  Y10S95/902

摘要： Nitrogen oxides and low molecular weight hydrocarbons are removed from air by subjecting the air to a temperature swing adsorption process using as the adsorbent a composite zeolite product containing both zeolite A and zeolite X. The composite zeolite product is preferably prepared by forming a mixture of an agglomerate of silica and sodium zeolite X having a Si/Al atomic ratio in the range of about 0.9 to less than about 1.2 and a water-soluble sodium aluminate salt; maintaining the mixture at a temperature in the range of about 25 to about 100° C. for a period of time sufficient to convert at least 50% of the silica to sodium zeolite A; and at least partially exchanging the zeolite A-containing product with divalent cations, preferably calcium ions.

摘要翻译： 通过使空气进行变温吸附方法从空气中除去氮氧化物和低分子量烃，使用含有沸石A和沸石X的复合沸石产物作为吸附剂。复合沸石产物优选通过形成 Si / Al原子比在约0.9至小于约1.2范围内的二氧化硅和钠沸石X的附聚物和水溶性铝酸钠盐; 将混合物保持在约25至约100℃范围内的温度下足以将至少50％的二氧化硅转化为沸石A的时间; 并且至少部分地将含沸石A的产物与二价阳离子，优选钙离子交换。