公开(公告)号：US20170349524A1

公开(公告)日：2017-12-07

申请号：US15538582

申请日：2015-12-18

Applicant: RHODIA OPERATIONS

Inventor： Sandra CHOUZIER ,  Fabien OCAMPO ,  Sergio MASTROIANNI ,  Avelino CORMA ,  Mercedes BORONAT ,  Javier Tirso LOPEZ AUSENS

IPC: C07C51/31 ,  C07C45/53 ,  C07C29/132 ,  C08G69/28 ,  C07C407/00 ,  C07C2601/14

CPC classification number: C07C51/316 ,  C07C29/132 ,  C07C29/48 ,  C07C45/28 ,  C07C45/53 ,  C07C407/00 ,  C07C2601/14 ,  C08G69/28 ,  C07C35/06 ,  C07C35/08 ,  C07C35/02 ,  C07C49/395 ,  C07C49/403 ,  C07C49/385

Abstract: The present invention concerns a method of oxidizing a cycloalkane to form a product mixture containing a corresponding alcohol and ketone, said method comprising contacting a cycloalkane with a hydroperoxide compound in the presence of a catalytic effective amount of a cerium oxide based catalyst.

公开(公告)号：US20170266651A1

公开(公告)日：2017-09-21

申请号：US15531114

申请日：2015-11-20

Applicant: RHODIA OPERATIONS

Inventor： Sandra CHOUZIER ,  Luis Fernando RASCON CRUZ ,  Bert WECKHUYSEN ,  Sergio MASTROIANNI

IPC: B01J37/08 ,  C07C45/53 ,  B01J23/26 ,  B01J27/24 ,  B01J37/06 ,  B01J37/00

CPC classification number: B01J37/086 ,  B01J23/26 ,  B01J23/75 ,  B01J27/24 ,  B01J29/0308 ,  B01J29/84 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0018 ,  B01J37/06 ,  B01J37/08 ,  C07C29/132 ,  C07C37/08 ,  C07C45/53 ,  C07C2523/24 ,  C07C2523/26 ,  C07C2601/14 ,  Y02P20/52 ,  C07C49/403 ,  C07C49/08 ,  C07C39/04 ,  C07C35/08 ,  C07C31/12

Abstract: Process for the manufacture of at least one alcohol and/or at least one ketone, which comprises a step during which at least one organic peroxide compound is put into contact with at least one catalyst responding to formula (I) CrNxOy Formula (I) in which x is a number varying from 0.10 to 1.00 and y is a number varying from 0.00 to 1.50, in order to produce the at least one alcohol and/or at least one ketone.