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1.发明公开公开(公告)号：US20240286973A1
公开(公告)日：2024-08-29
申请号：US18659092
申请日：2024-05-09
发明人： Masud M. Monwar , Jared L. Barr , Carlos A. Cruz , Kathy S. Clear , Max P. McDaniel , William C. Ellis
IPC分类号： C07B33/00 , B01J21/06 , B01J21/08 , B01J21/12 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/39 , B01J35/61 , B01J35/63 , B01J37/08 , B01J37/16 , B01J37/34 , B01J38/02 , C07C29/48 , C07C29/50 , C07C45/27 , C07C45/28 , C07C51/16 , C07C51/225
CPC分类号： C07B33/00 , B01J21/063 , B01J21/08 , B01J21/12 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/39 , B01J35/613 , B01J35/615 , B01J35/617 , B01J35/618 , B01J35/633 , B01J35/635 , B01J35/638 , B01J37/082 , B01J37/16 , B01J37/34 , B01J37/345 , B01J38/02 , C07C29/48 , C07C29/50 , C07C45/27 , C07C45/28 , C07C51/16 , C07C51/225
摘要： Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and a supported transition metal catalyst—containing molybdenum, tungsten, or vanadium—are irradiated with a light beam at a wavelength in the UV-visible spectrum, optionally in an oxidizing atmosphere, to form a reduced transition metal catalyst, followed by hydrolyzing the reduced transition metal catalyst to form a reaction product containing the alcohol compound and/or the carbonyl compound.
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2.发明授权公开(公告)号：US12017970B2
公开(公告)日：2024-06-25
申请号：US18459534
申请日：2023-09-01
发明人： Masud M. Monwar , Jared Barr , Carlos A. Cruz , Kathy S. Clear , Max P. McDaniel , William C. Ellis
IPC分类号： C07B33/00 , B01J21/06 , B01J21/08 , B01J21/12 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/39 , B01J35/61 , B01J35/63 , B01J37/08 , B01J37/16 , B01J37/34 , B01J38/02 , C07C29/48 , C07C29/50 , C07C45/27 , C07C45/28 , C07C51/16 , C07C51/225
CPC分类号： C07B33/00 , B01J21/063 , B01J21/08 , B01J21/12 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/39 , B01J35/613 , B01J35/615 , B01J35/617 , B01J35/618 , B01J35/633 , B01J35/635 , B01J35/638 , B01J37/082 , B01J37/16 , B01J37/34 , B01J37/345 , B01J38/02 , C07C29/48 , C07C29/50 , C07C45/27 , C07C45/28 , C07C51/16 , C07C51/225 , C07C29/50 , C07C31/20 , C07C29/50 , C07C33/025 , C07C45/28 , C07C47/02 , C07C45/28 , C07C49/04 , C07C29/50 , C07C31/08 , C07C29/50 , C07C31/10 , C07C51/225 , C07C53/02 , C07C51/225 , C07C53/08 , C07C51/225 , C07C53/124 , C07C29/50 , C07C31/04 , C07C29/50 , C07C31/125
摘要： Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and a supported transition metal catalyst—containing molybdenum, tungsten, or vanadium—are irradiated with a light beam at a wavelength in the UV-visible spectrum, optionally in an oxidizing atmosphere, to form a reduced transition metal catalyst, followed by hydrolyzing the reduced transition metal catalyst to form a reaction product containing the alcohol compound and/or the carbonyl compound.
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公开(公告)号：US11999679B2
公开(公告)日：2024-06-04
申请号：US18454844
申请日：2023-08-24
发明人： Carlos A. Cruz , Masud M. Monwar , Max P. McDaniel , Jared Barr , Kathy S. Clear , William C. Ellis
IPC分类号： C07C29/72 , B01J21/06 , B01J21/08 , B01J23/26 , B01J37/08 , B01J37/34 , B01J38/02 , C07C29/09 , C07C29/48 , C07C29/50 , C07C31/20 , C07C37/08 , C07C37/58 , C07C45/33 , C07C51/215 , B01J35/40 , B01J35/61 , B01J35/63 , C07C29/17 , C07C31/04 , C07C45/29
CPC分类号： C07C29/72 , B01J21/063 , B01J21/08 , B01J23/26 , B01J37/08 , B01J37/34 , B01J37/345 , B01J38/02 , C07C29/09 , C07C29/48 , C07C29/50 , C07C31/20 , C07C37/58 , C07C45/33 , C07C51/215 , B01J35/40 , B01J35/615 , B01J35/617 , B01J35/635 , C07C29/17 , C07C31/04 , C07C45/292 , C07C29/48 , C07C31/202 , C07C29/48 , C07C31/20 , C07C45/292 , C07C49/04 , C07C45/292 , C07C47/02
摘要： Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of forming a supported chromium catalyst comprising chromium in a hexavalent oxidation state, irradiating the hydrocarbon reactant and the supported chromium catalyst with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. The supported chromium catalyst can be formed by heat treating a supported chromium precursor, contacting a chromium precursor with a solid support while heat treating, or heat treating a solid support and then contacting a chromium precursor with the solid support.
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公开(公告)号：US20230399279A1
公开(公告)日：2023-12-14
申请号：US18249825
申请日：2021-10-07
发明人： Holger WIEDERHOLD , David Bolz , Jürgen Glenneberg
CPC分类号： C07C29/48 , C07C29/80 , B01D3/143 , B01J31/0255 , B01J23/42
摘要： A method for preparing 1,2-propanediol involves reacting propene with hydrogen peroxide in the presence of a catalyst mixture, containing a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase. The method then involves separating the reaction mixture into an aqueous phase (Pa) containing 1,2-propanediol and formic acid and an organic phase (Po); recycling at least part of the separated organic phase (Po) to the reaction; contacting at least a part of the separated aqueous phase (Pa) with a palladium catalyst; and recovering 1,2 propanediol from the aqueous phase provided by the contacting. The contacting of at least a part of the separated aqueous phase (Pa) with the palladium catalyst reduces the content of formic acid.
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5.发明公开公开(公告)号：US20230382839A1
公开(公告)日：2023-11-30
申请号：US18249980
申请日：2021-10-07
发明人： Holger Wiederhold , David Bolz , Jürgen Glenneberg
摘要： A method can be used for preparing 1,2-propanediol, dipropylene glycol, and tripropylene glycol. The method involves reacting propene with hydrogen peroxide containing nitrate, in the presence of a catalyst mixture containing a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase. The method then involves separating the reaction mixture into an aqueous phase containing 1,2-propanediol, dipropylene glycol, tripropylene glycol, and nitrate and an organic phase. The method further involves recycling at least part of the separated organic phase to the reaction; hydrogenating the separated aqueous phase using a heterogeneous hydrogenation catalyst to provide a hydrogenated aqueous phase with a reduced nitrate content; and recovering 1,2-propanediol, dipropylene glycol, and tripropylene glycol from the hydrogenated aqueous phase by a sequential multiple-step distillation.
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6.发明公开公开(公告)号：US20230321634A1
公开(公告)日：2023-10-12
申请号：US18295302
申请日：2023-04-04
发明人： Max P. McDaniel , Mitchell D. Refvik , Jeremy M. Praetorius , Kathy S. Clear , Jared L. Barr , Carlos A. Cruz , Masud M. Monwar
摘要： A hydrocarbon compound and carbon monoxide are reacted in the presence of either a supported chromium (VI) catalyst or a supported chromium (II) catalyst, optionally with UV-visible light irradiation and/or exposure to an oxidizing atmosphere, followed by removing a reaction product containing an alcohol compound and/or a carbonyl compound from the respective chromium catalyst. Often, the reaction product contains one or more ketone and/or aldehyde compounds.
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公开(公告)号：US11767279B2
公开(公告)日：2023-09-26
申请号：US17864492
申请日：2022-07-14
IPC分类号： C07C29/72 , C07C45/33 , B01J23/26 , B01J21/06 , B01J21/08 , B01J38/02 , C07C29/50 , C07C37/58 , C07C51/215 , C07C31/20 , B01J37/08 , C07C29/48 , C07C29/09 , B01J37/34 , C07C31/04 , B01J35/02 , B01J35/10 , C07C29/17 , C07C45/29
CPC分类号： C07C29/72 , B01J21/063 , B01J21/08 , B01J23/26 , B01J37/08 , B01J37/34 , B01J37/345 , B01J38/02 , C07C29/09 , C07C29/48 , C07C29/50 , C07C31/20 , C07C37/58 , C07C45/33 , C07C51/215 , B01J35/023 , B01J35/1019 , B01J35/1023 , B01J35/1042 , C07C29/17 , C07C31/04 , C07C45/292 , C07C29/48 , C07C31/202 , C07C29/48 , C07C31/20 , C07C45/292 , C07C49/04 , C07C45/292 , C07C47/02
摘要： Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of irradiating the hydrocarbon reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. In addition, these processes can further comprise a step of calcining all or a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.
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公开(公告)号：US20190210006A1
公开(公告)日：2019-07-11
申请号：US16303278
申请日：2017-05-16
发明人： Wugeng LIANG , Sagar SARSANI , David WEST
IPC分类号： B01J23/34 , B01J23/00 , B01J23/04 , B01J21/08 , B01J37/04 , B01J37/08 , C07C2/84 , C07C11/04 , C07C27/14 , C07C29/48 , C07C31/08
CPC分类号： B01J23/34 , B01J21/08 , B01J23/002 , B01J23/04 , B01J35/0013 , B01J37/0236 , B01J37/04 , B01J37/08 , B01J2523/00 , B01J2523/12 , B01J2523/69 , B01J2523/72 , C07C2/84 , C07C11/04 , C07C27/14 , C07C29/48 , C07C31/08 , C07C2523/30 , C07C2523/34 , Y02P20/52 , B01J2523/41
摘要： Disclosed is a supported catalyst and methods to prepare and use the supported catalyst in an oxidative coupling of methane (OCM) reaction. The supported catalyst can contain MnWO4 or MnWO4 nanostructures that are in contact with the surface of a sodium containing silicon dioxide support material. The supported MnWO4 catalyst can have an active MnWO4 crystal phase.
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公开(公告)号：US20180354876A1
公开(公告)日：2018-12-13
申请号：US15780694
申请日：2016-12-02
申请人： e-Therapeutics plc
IPC分类号： C07C29/143 , C07C45/64 , C07C29/48 , C07C35/28 , C07C49/733 , C07D311/80
CPC分类号： C07C29/143 , C07B2200/07 , C07C29/48 , C07C35/28 , C07C45/28 , C07C45/64 , C07C49/733 , C07C67/14 , C07C67/29 , C07C2602/42 , C07D311/80 , C07F7/1804 , Y02P20/55 , C07C69/24 , C07C69/28
摘要： There is described a method of preparing a compound of formula I, and optical isomers thereof; in which R1 is hydrogen or a protecting group; said method comprising oxidising verbenone and optical isomers thereof.
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公开(公告)号：US20180280949A1
公开(公告)日：2018-10-04
申请号：US15966784
申请日：2018-04-30
IPC分类号： B01J31/12 , B01J35/00 , C07C29/48 , C07C45/28 , B01J35/10 , C07C51/285 , C07F1/08 , C07F3/06 , C07F15/02 , C07C27/16 , C07C45/29 , C07C35/08 , C07C49/403 , C07C47/54 , C07C63/06
CPC分类号： B01J31/123 , B01J35/002 , B01J35/1023 , B01J35/1028 , B01J35/1057 , B01J35/1061 , C07C27/16 , C07C29/48 , C07C45/28 , C07C45/294 , C07C47/54 , C07C51/285 , C07C2101/14 , C07C2601/14 , C07F1/08 , C07F3/06 , C07F15/025 , C07C35/08 , C07C49/403 , C07C63/06
摘要： A metal organic framework comprising zinc (II) ions and second metal ions, such as iron (II) ions, cobalt (II) ions, and copper (II) ions as nodes or clusters and coordinated 1,3,5-benzenetricarboxylic acid struts or linkers between them forming a porous coordination network in the form of polyhedral crystals that are isostructural to HKUST-1. Transmetallation processes for producing the metal organic frameworks, as well as methods for applications of the metal organic frameworks as catalysts, specifically catalysts for the oxidation of cyclic hydrocarbons, such as toluene, cyclohexane, and methylcyclohexane.
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