Low viscosity terminally functionalized isoprene polymers
    7.
    发明授权
    Low viscosity terminally functionalized isoprene polymers 失效
    低粘度的末端官能化异戊二烯聚合物

    公开(公告)号:US5376745A

    公开(公告)日:1994-12-27

    申请号:US160341

    申请日:1993-12-01

    CPC分类号: C08F136/06

    摘要: The anionic polymerization of isoprene with monolithium initiators and functionalized initiators having the structure R.sup.1 R.sup.2 R.sup.3 Si--O--A'--Li wherein R.sup.1, R.sup.2, and R.sup.3 are preferably alkyl, alkoxy, aryl, or alkaryl groups having from 1 to 10 carbon atoms, and A' is preferably a branched or straight chain bridging group having at least 2 carbon atoms produces unsaturated and hydrogenated isoprene polymers having high 1,4-addition of the isoprene, from about one to two terminal functional groups per molecule, and low viscosity.

    摘要翻译: 具有单键引发剂的异戊二烯和具有结构R1R2R3Si-O-A'-Li的官能化引发剂的异戊二烯的阴离子聚合,其中R1,R2和R3优选为具有1至10个碳原子的烷基,烷氧基,芳基或烷芳基,A 优选具有至少2个碳原子的支链或直链桥连基产生具有异戊二烯高1,4-加成,每分子约1至2个末端官能团和低粘度的不饱和和氢化异戊二烯聚合物。