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公开(公告)号:US11746299B1
公开(公告)日:2023-09-05
申请号:US17861543
申请日:2022-07-11
Applicant: Saudi Arabian Oil Company , SABIC Global Technologies B.V.
Inventor: Miao Sun , Sohel K Shaikh , Wojciech Andrzej Supronowicz , Chandrasekar Subramani , Eman Z Albaher
CPC classification number: C10G47/04 , B01J19/24 , B01J23/002 , B01J23/83 , C10G69/06 , C10G2300/4006 , C10G2300/4012 , C10G2300/706 , C10G2400/30
Abstract: A method for upgrading mixed pyrolysis oil may include contacting the mixed pyrolysis oil with hydrogen in the presence of a mixed metal oxide catalyst at reaction conditions to produce a reaction effluent including light aromatic compounds. The mixed pyrolysis oil includes multi-ring aromatic compounds and is formed from light pyrolysis oil and heavy pyrolysis oil at a ratio of 10:90 to 40:60 with light pyrolysis oil representing a bottom stream of a gas steam cracker and heavy pyrolysis oil representing a bottom stream of a naphtha steam cracker. The mixed metal oxide catalyst includes a plurality of catalyst particles with each catalyst particles including a plurality of metal oxides. An associated system for upgrading mixed pyrolysis oil may include a pyrolysis upgrading unit housing the mixed metal oxide catalyst and a separation unit operable to separate used mixed metal oxide catalyst from the reaction effluent.
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公开(公告)号:US20240010934A1
公开(公告)日:2024-01-11
申请号:US18347923
申请日:2023-07-06
Applicant: Saudi Arabian Oil Company , SABIC Global Technologies B.V.
Inventor: Miao Sun , Sohel K. Shaikh , Wojciech Andrzej Supronowicz , Chandrasekar Subramani , Eman Z. Albaher
CPC classification number: C10G47/04 , B01J19/24 , B01J23/83 , B01J23/002 , C10G69/06
Abstract: A method for upgrading mixed pyrolysis oil may include contacting the mixed pyrolysis oil with hydrogen in the presence of a mixed metal oxide catalyst at reaction conditions to produce a reaction effluent including light aromatic compounds. The mixed pyrolysis oil includes multi-ring aromatic compounds and is formed from light pyrolysis oil and heavy pyrolysis oil at a ratio of 10:90 to 40:60 with light pyrolysis oil representing a bottom stream of a gas steam cracker and heavy pyrolysis oil representing a bottom stream of a naphtha steam cracker. The mixed metal oxide catalyst includes a plurality of catalyst particles with each catalyst particles including a plurality of metal oxides. An associated system for upgrading mixed pyrolysis oil may include a pyrolysis upgrading unit housing the mixed metal oxide catalyst and a separation unit operable to separate used mixed metal oxide catalyst from the reaction effluent.
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公开(公告)号:US12227706B2
公开(公告)日:2025-02-18
申请号:US18046034
申请日:2022-10-12
Applicant: Saudi Arabian Oil Company , SABIC Global Technologies B.V.
Inventor: Miao Sun , Sohel K. Shaikh , Wojciech Andrzej Supronowicz , Chandrasekar Subramani , Eman Z. Albaher
Abstract: In accordance with one or more embodiments of the present disclosure, a multi-stage process for upgrading a mixed pyrolysis oil comprising polyaromatic compounds to benzene, toluene, ethylbenzene, and xylenes (BTEX) includes combining light pyrolysis oil with heavy pyrolysis oil to form the mixed pyrolysis oil; upgrading the mixed pyrolysis oil in a slurry-phase reactor zone to produce intermediate products, wherein the slurry-phase reactor zone comprises a mixed metal oxide catalyst; and hydrocracking the intermediate products in a fixed-bed reactor zone to produce the BTEX, wherein the fixed-bed reactor zone comprises a mesoporous zeolite-supported metal catalyst.
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公开(公告)号:US20240351964A1
公开(公告)日:2024-10-24
申请号:US18685628
申请日:2022-09-12
Applicant: SABIC Global Technologies B.V.
Abstract: A process for producing isopentane and isoamylene can comprise passing a feed stream comprising C5 hydrocarbons through a hydrodesulfurization assembly to produce a first stream: passing the first stream to a first separation assembly to produce a second stream and a first separated stream: passing the second stream to a deisopentanizer assembly to produce a second separated stream comprising isopentane, a third separated stream comprising C6+ hydrocarbons, and a raffinate stream comprising C5 hydrocarbons; and passing the raffinate stream to a reactor assembly to produce a reaction product stream comprising isoamylene. The present disclosure also provides for a system for producing isopentane and isoamylene.
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公开(公告)号:US12091619B2
公开(公告)日:2024-09-17
申请号:US18347923
申请日:2023-07-06
Applicant: Saudi Arabian Oil Company , SABIC Global Technologies B.V.
Inventor: Miao Sun , Sohel K Shaikh , Wojciech Andrzej Supronowicz , Chandrasekar Subramani , Eman Z Albaher
CPC classification number: C10G47/04 , B01J19/24 , B01J23/002 , B01J23/83 , C10G69/06 , C10G2300/4006 , C10G2300/4012 , C10G2300/706 , C10G2400/30
Abstract: A method for upgrading mixed pyrolysis oil may include contacting the mixed pyrolysis oil with hydrogen in the presence of a mixed metal oxide catalyst at reaction conditions to produce a reaction effluent including light aromatic compounds. The mixed pyrolysis oil includes multi-ring aromatic compounds and is formed from light pyrolysis oil and heavy pyrolysis oil at a ratio of 10:90 to 40:60 with light pyrolysis oil representing a bottom stream of a gas steam cracker and heavy pyrolysis oil representing a bottom stream of a naphtha steam cracker. The mixed metal oxide catalyst includes a plurality of catalyst particles with each catalyst particles including a plurality of metal oxides. An associated system for upgrading mixed pyrolysis oil may include a pyrolysis upgrading unit housing the mixed metal oxide catalyst and a separation unit operable to separate used mixed metal oxide catalyst from the reaction effluent.
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公开(公告)号:US20240124789A1
公开(公告)日:2024-04-18
申请号:US18046034
申请日:2022-10-12
Applicant: Saudi Arabian Oil Company , SABIC Global Technologies B.V.
Inventor: Miao Sun , Sohel K Shaikh , Wojciech Andrzej Supronowicz , Chandrasekar Subramani , Eman Z. Albaher
CPC classification number: C10G69/04 , B01J21/04 , B01J23/83 , B01J29/045 , C10G11/14 , C10G45/68 , C10G47/20 , C10G2300/70 , C10G2400/30
Abstract: In accordance with one or more embodiments of the present disclosure, a multi-stage process for upgrading a mixed pyrolysis oil comprising polyaromatic compounds to benzene, toluene, ethylbenzene, and xylenes (BTEX) includes combining light pyrolysis oil with heavy pyrolysis oil to form the mixed pyrolysis oil; upgrading the mixed pyrolysis oil in a slurry-phase reactor zone to produce intermediate products, wherein the slurry-phase reactor zone comprises a mixed metal oxide catalyst; and hydrocracking the intermediate products in a fixed-bed reactor zone to produce the BTEX, wherein the fixed-bed reactor zone comprises a mesoporous zeolite-supported metal catalyst.
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