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公开(公告)号:US12215199B2
公开(公告)日:2025-02-04
申请号:US17440475
申请日:2020-03-12
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Artur Rozanski , Lidia Jasinska-Walc , Miloud Bouyahyi , Lanti Yang , Robbert Duchateau , Thomas Defize , Katrien Veerle Bernaerts
IPC: C08G81/02 , B01D67/00 , B01D71/26 , B01D71/48 , B01D71/78 , C02F1/44 , H01M50/414 , H01M50/417 , H01M50/449 , H01M50/489 , H01M50/491 , H01M50/406
Abstract: The invention relates to a film Film comprising a random graft copolymer having a polypropylene (PP) backbone and from 3 to 8 polyester segments covalently bonded to said backbone, wherein the number average molecular weight (Mn) of the polypropylene backbone ranges between 10.000 and 100.000 Dalton (as determined with HT-SEC in o-DCB at 150° C.), wherein the Mn of each polyester segment ranges between 5.000 and 25.000 Daltons, wherein the amount of PP ranges between 45 and 80 mol %, wherein the amount of polyester segments ranges between 55 and 20 mol %, wherein the film has a thickness in the range of 0.01-10 mm, wherein the polypropylene and polyester domains form independently continuous phases, and wherein the mol % is calculated relative to the total moles of monomer units present in the copolymer. The invention further relates to a nano porous PP membrane and its use.
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公开(公告)号:US11603419B2
公开(公告)日:2023-03-14
申请号:US16467127
申请日:2017-12-04
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Robbert Duchateau , Miloud Bouyahyi , Lidia Jasinska-Walc
IPC: C08F4/69 , C08F4/6592 , C08F216/02 , C08F210/02
Abstract: The present invention concerns a process for the preparation of a copolymer comprising the steps of copolymerizing under suitable reaction conditions at least one first type of olefin monomer and at least one second type of functionalized olefin monomer using a catalyst system to obtain a polyolefin main chain having one or multiple functionalized short chain branches, the catalyst system comprising: i) a single-site catalyst or catalyst precursor comprising a metal selected from Ti3+ or Cr3+; ii) a co-catalyst; iii) optionally a scavenger.
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公开(公告)号:US11472900B2
公开(公告)日:2022-10-18
申请号:US16954364
申请日:2018-12-24
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Miloud Bouyahyi , Lidia Jasinska-Walc , Robbert Duchateau
IPC: C08F210/16 , C08F220/04 , C08F210/06 , C08F8/42 , C08F8/44 , C08F210/14 , C08F2/06 , C08F4/659 , C08F4/6592 , C08F8/12 , C08F220/64
Abstract: The present invention relates to an ethylene and propylene ionomer and a process for the preparation of an ethylene and propylene ionomer.
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公开(公告)号:US20220267550A1
公开(公告)日:2022-08-25
申请号:US17631689
申请日:2020-07-17
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Robbert Duchateau , Miloud Bouyahyi , Lidia Jasinska-Walc
Abstract: The present invention relates to the use of a composition comprising 60-98 wt. % of polypropylene, 2-40 wt. % of low density polyethylene, 0.1-10 wt. % of compatibiliser wherein the compatibiliser is a BAB or AB type of block copolymer comprising a polypropylene block A and a polyester block B, or wherein the compatibiliser is a graft copolymer of the type ABn having a polypropylene backbone A and polyester block(s) B grafted thereon, with n being at least 1, and the polyester block(s) B have an average M/F ratio from 8-32, wherein M is the number of backbone carbon atoms in the polyester not including carbonyl carbon atoms, and F is the number of ester groups in the polyester block(s), wherein the wt. % is based on the sum of the amount polypropylene, low density polyethylene and compatibiliser, for the manufacture of a foamed article.
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公开(公告)号:US20220153977A1
公开(公告)日:2022-05-19
申请号:US17602812
申请日:2020-03-31
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Robbert Duchateau , Lidia Jasinska-Walc , Miloud Bouyahyi , Lanti Yang , Peter Degenhart , Enrico Troisi
Abstract: The present invention relates to the use of a composition comprising from 60-98 wt. % of polypropylene, from 2-40 wt. % of aromatic polycarbonate and from 0.1-10 wt. % of compatibiliser for the manufacture of a foamed article, wherein the compatibiliser is a BAB or AB type of block copolymer comprising a polypropylene block A and a polyester or polycarbonate block B, or wherein the compatibiliser is a graft copolymer of the type ABn having a polypropylene backbone A and polyester or polycarbonate block(s) B grafted thereon, with n being at least 1, and wherein the polyester or polycarbonate blocks B have an average M/F ratio from 2-25, wherein M is the number of backbone carbon atoms in the polyester or polycarbonate not including carbonyl carbon atoms, and F is the number of ester or carbonate groups in the polyester or polycarbonate block, and wherein the wt. % is based on the sum of the amount polypropylene, polycarbonate and compatibiliser.
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公开(公告)号:US20210087313A1
公开(公告)日:2021-03-25
申请号:US16954750
申请日:2018-12-24
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Miloud Bouyahyi , Lidia Jasinska-Walc , Robbert Duchateau
IPC: C08F210/16 , C08F8/44 , C08F8/12 , C08F4/6592 , C08F4/659 , C08F2/06
Abstract: The present invention relates to a process for the manufacture of a functionalized ethylene and propylene copolymer composition. The invention further relates to such functionalized ethylene and propylene copolymer composition.
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公开(公告)号:US10787545B2
公开(公告)日:2020-09-29
申请号:US15781628
申请日:2016-11-21
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Robbert Duchateau , Lidia Jasinska-Walc , Miloud Bouyahyi
Abstract: The present invention relates to a process for the preparation of polyolefin-based graft copolymers comprising a first functionalized short chain branched polyolefin block and one or multiple polymer side chains. The functionalized short chain branched polyolefin is produced via the copolymerization of an olefin monomer and an olefin bearing a main group metal hydrocarbyl functionality. Subsequently the graft copolymers according to the invention can be produced for example by ring-opening polymerization of cyclic monomers or by transesterification of a preformed transesterifiable polymer, especially polyesters or polycarbonates. The invention moreover relates to polyolefin-based graft copolymers obtained by said process.
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公开(公告)号:US10717826B2
公开(公告)日:2020-07-21
申请号:US15781796
申请日:2016-11-21
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Robbert Duchateau , Miloud Bouyahyi , Lidia Jasinska-Walc
IPC: C08G81/02 , C08G63/82 , C08F8/06 , C08F2/38 , C08F8/14 , C08F210/02 , C08F4/6592 , C08F4/659
Abstract: The present invention relates to a process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains. The functionalized long chain branched polyolefin is produced via the copolymerization of an olefin monomer and an olefin bearing a main group metal hydrocarbyl functionality. The invention moreover relates to polyolefin obtained by said process ends. Subsequently the graft copolymers according to the invention can be produced for example by ring-opening polymerization of cyclic monomers or by transesterification of a preformed transesterifiable polymer, especially polyesters or polycarbonates. The invention moreover relates to polyolefin-based graft copolymers obtained by said process.
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公开(公告)号:US20250019470A1
公开(公告)日:2025-01-16
申请号:US18711202
申请日:2022-11-14
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
IPC: C08F4/64 , C08F210/00
Abstract: The present invention relates to a process for solution copolymerization process to produce a functionalized polyolefin using a catalyst system comprising a bis-phenolate hafnium or zirconium complex and a co-catalyst selected from the group: MAO, MMAO, DMAO, SMAO or ammonium salts or trityl salts of fluorinated tetraarylborates.
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公开(公告)号:US20210309775A1
公开(公告)日:2021-10-07
申请号:US16956001
申请日:2018-12-24
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Lidia Jasinska-Walc , Robbert Duchateau , Miloud Bouyahyi , Anton Ginzburg , Enrico Troisi
IPC: C08F210/06 , C08F4/6592 , C08F4/659 , C08F210/14 , C08F8/42 , C08F2/06
Abstract: The present invention relates to a semi-crystalline polyolefinic ionomer and a process for the preparation of a semi-crystalline polyolefinic ionomer.
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