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1.发明授权Process for removing catalyst metal residues from high density polyethylenes 失效从高密度聚乙烯中除去催化剂金属残留物的方法
公开(公告)号：US3689473A
公开(公告)日：1972-09-05
申请号：US3689473D
申请日：1970-11-06
Applicant: SNAM PROGETTI
Inventor： BALDUCCI AGOSTINO , BARADEL AGOSTINO , MARENA MASSIMO
Abstract: HIGH DENSITY POLYETHYLENE IS FREED OF CATALYST METAL RESIDUES BY CONTACTING WITH A MIXTURE OF AN ANHYDROUS ALCOHOL AND A HYDROCARBON, WHICH IS THE SAME AS THAT USED AS THE SUSPENSION MEDIUM IN THE FORMATION OF THE POLYETHYLENE. IT IS PREFERRED TO CARRY OUT THE CONTACTING IN A COUNTERCURRENT APPARATUS IN WHICH THE POLYETHYLENE FLOWS DOWNWARDLY AGAINST AN UPWARDLY MOVING STREAM FORMED FROM THE ANHYDROUS ALCOHOL AND THE HYDROCARBON.
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2.发明授权Catalyst system for the homo- and co-polymerization of olefins, conjugated or unconjugated dienes 失效用于烯烃，共轭或非共轭二烯的均聚和共聚的催化剂体系
公开(公告)号：US3905913A
公开(公告)日：1975-09-16
申请号：US39559273
申请日：1973-09-10
Applicant: SNAM PROGETTI
Inventor： CORBELLINI MARGHERITA , BALDUCCI AGOSTINO
IPC: C08F4/00 , B01J27/04 , C07F5/06 , C08F4/06 , C08F4/12 , C08F4/60 , C08F4/642 , C08F4/72 , C08F10/00 , C08F36/00 , C08F36/04 , C08F110/02 , C08F110/06 , C08F136/08 , B01J27/10 , B01J31/14
CPC classification number: C08F36/04 , C07F5/069 , C08F10/00 , C08F4/6495 , C08F4/643
Abstract: A new catalyst system, for the homo- and copolymerization of olefins, conjugated or unconjugated dienes or mixtures thereof, is composed of a Ziegler catalyst transition metal compound and an aluminum compound having the general formula:
wherein X is hydrogen or halogen; both R''s are hydrocarbon radicals; and R'' is an unsaturated or saturated aliphatic divalent hydrocarbon radical, unsubstituted cycloalkyl radical or unsubstituted aryl radical.-
3.发明授权Catalyst composition useful for the diene polymerization and polymerization process using the above catalyst system 失效可用于使用上述催化剂体系的二烯聚合和聚合方法的催化剂组合物
公开(公告)号：US3875133A
公开(公告)日：1975-04-01
申请号：US27751272
申请日：1972-08-03
Applicant: SNAM PROGETTI
Inventor： BALDUCCI AGOSTINO , BERANGER ALESSANDRO , CORBELLINI MARGHERITA
IPC: C07F5/06 , C08F36/04 , C08F136/04
CPC classification number: C08F36/04 , C07F5/069 , C08F10/00 , C08F136/04 , C08F136/08 , C08F4/643
Abstract: A process for the stercospecific polymerization of conjugated diene by polymerizing in the presence of a catalyst comprising a compound of a transition metal of titanium vanadium zirconium, cobolt, manganese and nickel and a polyiminic polymer.
Abstract translation: 通过在包含钛钒锆，钴矿，锰和镍的过渡金属的化合物的催化剂和聚亚胺系聚合物的存在下进行聚合，共轭二烯的空间特异性聚合的方法。
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