公开(公告)号：US20160184806A1

公开(公告)日：2016-06-30

申请号：US14959981

申请日：2015-12-04

申请人： Shanghai HuaYi Acrylic Acid Co., Ltd ,  Shanghai HuaYi New Material Co., Ltd

发明人： Desheng Xiong ,  Yibin Wang ,  Yan Zhuang ,  Ge Luo ,  Tonghao Wu ,  Fupeng Zhai ,  Xiaoxia Wang ,  Jianxue Ma ,  Xiaodong Chu ,  Jinhua Ji

IPC分类号： B01J23/889 ,  B01J37/04 ,  B01J37/00 ,  B01J23/80 ,  B01J23/78

CPC分类号： B01J23/8892 ,  B01J23/002 ,  B01J23/78 ,  B01J23/80 ,  B01J23/887 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/04 ,  B01J2523/00 ,  C07C5/48 ,  C07C2529/65 ,  C07C2529/68 ,  C07C2529/69 ,  B01J2523/27 ,  B01J2523/842 ,  B01J2523/22 ,  B01J2523/845 ,  B01J2523/72 ,  C07C11/167

摘要： Disclosed are a ferrite catalyst, its preparation method and use. The catalyst has a formula of FeAaDbOc, wherein A is Mg atom, Zn atom or a mixture of these two atoms in any ratio; D is one or more atoms elected from the group consisting of Ni, Co, Mn, Ca, Mo or V; a=0.01˜0.6; b=0˜0.30; c is a number satisfying the valence. The catalyst is prepared by a method comprising mixing the metal oxide precursors according to the chemical ratios and grinding by ball milling to obtain the ferrite catalyst. The catalyst exhibits excellent activity and selectivity when used in a reaction for preparing butadiene by oxidative dehydrogenation of butene. The preparation of the catalyst is simple, controllable and well repeatable, with reduced waste water and waste gas during preparation.

摘要翻译： 公开了一种铁氧体催化剂及其制备方法和用途。 催化剂具有FeAaDbOc的式，其中A是Mg原子，Zn原子或这两个原子的任何比例的混合物; D是从由Ni，Co，Mn，Ca，Mo或V组成的组中选出的一个或多个原子; a = 0.01〜0.6; b = 0〜0.30; c是满足价态的数。 该催化剂通过包括根据化学比混合金属氧化物前体并通过球磨研磨获得铁氧体催化剂的方法制备。 当用于通过丁烯的氧化脱氢制备丁二烯的反应中时，催化剂表现出优异的活性和选择性。 催化剂的制备简单，可控，重复性好，在制备过程中减少废水和废气。