Catalytic conversion of methanol to linear olefins
    7.
    发明授权
    Catalytic conversion of methanol to linear olefins 失效
    甲醇催化转化为直链烯烃

    公开(公告)号:US5491273A

    公开(公告)日:1996-02-13

    申请号:US340787

    申请日:1994-11-17

    IPC分类号: C07C1/20 C07C1/00

    摘要: This invention covers a process for converting a feed comprising at least one lower aliphatic alcohol having from 1 to 3 carbon atoms or a corresponding ether of such an alcohol to hydrocarbon products comprising linear olefins. The process comprises contacting the feed in a reaction zone with a catalyst comprising material having a large crystal ferrierite aluminosilicate structure. An effluent is withdrawn from the reaction zone, which comprises linear olefins. Linear olefins may then be separated from the effluent. The aliphatic alcohol having from 1 to 3 carbons is generally methanol and the preferred ether is dimethyl ether. ZSM-35 is the preferred large crystal ferrierite structure of this invention.

    摘要翻译: 本发明涵盖了将包含至少一种具有1至3个碳原子的低级脂族醇或这种醇的相应醚转化为包含线性烯烃的烃产物的方法。 该方法包括使反应区中的进料与含有大晶体镁碱沸石硅铝酸盐结构的材料的催化剂接触。 从反应区取出流出物,该反应区包含直链烯烃。 然后可以将线性烯烃与流出物分离。 具有1至3个碳的脂族醇通常是甲醇,优选的醚是二甲醚。 ZSM-35是本发明优选的大晶体镁碱沸石结构。

    Methane conversion process
    9.
    发明授权
    Methane conversion process 有权
    甲烷转化过程

    公开(公告)号:US08981169B2

    公开(公告)日:2015-03-17

    申请号:US13184954

    申请日:2011-07-18

    摘要: A process for converting a gaseous hydrocarbon feed comprising methane to an aromatic hydrocarbon is integrated with liquefied natural gas (LNG) and/or pipeline gas production. The gaseous hydrocarbon feed is supplied to a conversion zone comprising at least one dehydroaromatization catalyst and is contacted with the catalyst under conversion conditions to produce a gaseous effluent stream comprising at least one aromatic compound, unreacted methane and H2. The gaseous effluent stream is then separated into a first product stream comprising said at least one aromatic compound and a second product stream comprising unreacted methane and H2. The second product stream is further separated into a methane-rich stream and a hydrogen-rich stream and at least part of the methane-rich stream is passed to LNG and/or pipeline gas production.

    摘要翻译: 将包含甲烷的气态烃进料转化成芳烃的方法与液化天然气(LNG)和/或管道气生产相结合。 将气态烃进料供给到包含至少一种脱氢芳族化催化剂的转化区,并在转化条件下与催化剂接触以产生包含至少一种芳族化合物,未反应甲烷和H 2的气态流出物流。 然后将气态流出物流分离成包含所述至少一种芳族化合物的第一产物流和包含未反应的甲烷和H 2的第二产物流。 第二产物流进一步分离成富甲烷流和富氢流,至少部分富甲烷流被送到LNG和/或管道气生产。

    Methane Conversion Process
    10.
    发明申请
    Methane Conversion Process 有权
    甲烷转化过程

    公开(公告)号:US20120036889A1

    公开(公告)日:2012-02-16

    申请号:US13184954

    申请日:2011-07-18

    IPC分类号: F25J3/08 C07C2/00

    摘要: A process for converting a gaseous hydrocarbon feed comprising methane to an aromatic hydrocarbon is integrated with liquefied natural gas (LNG) and/or pipeline gas production. In the integrated process, the gaseous hydrocarbon feed is supplied to a conversion zone comprising at least one dehydroaromatization catalyst and is contacted with the catalyst under conversion conditions to produce a gaseous effluent stream comprising at least one aromatic compound, unreacted methane and H2. The gaseous effluent stream is then separated into a first product stream comprising said at least one aromatic compound and a second product stream comprising unreacted methane and H2. The second product stream is further separated into a methane-rich stream and a hydrogen-rich stream and at least part of the methane-rich stream is passed to LNG and/or pipeline gas production. The gaseous hydrocarbon feed supplied to the conversion zone has at least one of the following properties: (i) a sulfur level of at least 25 ppm by volume; (ii) a CO2 level of at least 50 ppm by volume; and (iii) a dew point of at least 203° K.

    摘要翻译: 将包含甲烷的气态烃进料转化成芳烃的方法与液化天然气(LNG)和/或管道气生产相结合。 在一体化方法中,将气态烃进料供给至包含至少一种脱氢芳烃化催化剂的转化区,并在转化条件下与催化剂接触以产生包含至少一种芳族化合物,未反应甲烷和H 2的气态流出物流。 然后将气态流出物流分离成包含所述至少一种芳族化合物的第一产物流和包含未反应的甲烷和H 2的第二产物流。 第二产物流进一步分离成富甲烷流和富氢流,至少部分富甲烷流被送到LNG和/或管道气生产。 供应到转化区的气态烃进料具有以下特性中的至少一个:(i)至少25ppm体积的硫含量; (ii)至少50ppm体积的CO 2水平; 和(iii)至少203°K的露点。