公开(公告)号：US5501883A

公开(公告)日：1996-03-26

申请号：US281029

申请日：1994-07-27

申请人： Takao Ishikawa ,  Tomoji Oishi ,  Sachiko Maekawa

发明人： Takao Ishikawa ,  Tomoji Oishi ,  Sachiko Maekawa

IPC分类号： C01G55/00 ,  G02F1/1343 ,  H01B1/08 ,  H01B13/00 ,  C09K19/00

CPC分类号： G02F1/13439 ,  H01B1/08 ,  Y10T428/1055

摘要： A material for use as a transparent conductive film contains tin oxide to which antimony is added, an oxide of at least one metal of Group VIII except for Fe, Co and Ni, and an organic solvent. The transparent conductive film has good characteristics for use as a transparent electrode for liquid crystal display devices and as an antistatic film on the display surface of Braun tubes.

摘要翻译： 用作透明导电膜的材料包含加入锑的氧化锡，除Fe，Co和Ni以外的至少一种第Ⅷ族金属的氧化物和有机溶剂。 透明导电膜具有用作液晶显示装置的透明电极和布劳恩管显示面上的抗静电膜的良好特性。

公开(公告)号：US5449534A

公开(公告)日：1995-09-12

申请号：US942397

申请日：1992-09-09

申请人： Tomoji Oishi ,  Sachiko Maekawa ,  Akira Kato ,  Masahiro Nishizawa ,  Yoshifumi Tomita ,  Kojiro Okude ,  Kenji Tochigi ,  Yutaka Misawa

发明人： Tomoji Oishi ,  Sachiko Maekawa ,  Akira Kato ,  Masahiro Nishizawa ,  Yoshifumi Tomita ,  Kojiro Okude ,  Kenji Tochigi ,  Yutaka Misawa

IPC分类号： G02B1/11 ,  H01J29/89 ,  B05D3/06 ,  B05D5/06 ,  B05D5/12

CPC分类号： G02B1/11 ,  H01J29/896 ,  H01J2209/012

摘要： An anti-reflection film is produced on the panel surface of a cathode-ray tube by:(A) preparing a solution for forming an anti-reflection film, which contains water and a metal alkoxide having the formula,M(OR).sub.nwherein M is a metal selected from the group consisting of Si, Ti, Al, Zr, Sn, In, Sb and Zn; R is an alkyl group having 1-10 carbon atoms; n is an integer of from 1 to 8; and when n is not 1, the alkyl groups represented by R may be the same or different,(B) coating the solution for forming an anti-reflection film on the outermost surface of the panel of a cathode-ray tube, and(C) applying an ultraviolet light to the solution for forming an anti-reflection film coated on said surface to cure the solution to form a transparent film with fine roughness.This production method is carried out using an apparatus having:(a) a coating means for coating the above solution for forming an anti-reflection film on the outermost surface of the panel of a cathode-ray tube,(b) a transferring means for transferring the solution-coated cathode-ray tube, and(c) an ultraviolet light-applying means for photocuring the solution coated on the cathode-ray tube during the transfer of the solution-coated cathode-ray tube.In the above method, when a silicon alkoxide is used as the metal alkoxide, there can be obtained a cathode-ray tube having an anti-reflection film made of alkali-free silica on the outermost surface of the panel, said anti-reflection film giving a ratio of Si-O-Si peak intensity to Si-OH peak intensity of 4 or more when measured for infrared spectrum.

摘要翻译： 在阴极射线管的面板表面上制造防反射膜：（A）制备含有水和金属醇盐的抗反射膜的溶液，所述金属醇盐具有式M（OR）n，其中 M是选自Si，Ti，Al，Zr，Sn，In，Sb和Zn的金属; R是具有1-10个碳原子的烷基; n为1〜8的整数， 当n不为1时，由R表示的烷基可以相同或不同，（B）在阴极射线管的面板的最外表面上涂布形成抗反射膜的溶液，（C ）向所述溶液施加紫外光以形成涂覆在所述表面上的抗反射膜，以使溶液固化以形成具有精细粗糙度的透明膜。 该制造方法使用以下装置进行：（a）在阴极射线管的面板的最表面上涂布上述用于形成防反射膜的溶液的涂布装置，（b）转印装置， 转移溶液涂覆的阴极射线管，以及（c）紫外线照射装置，用于在涂覆阴极射线管的转印期间光固化涂覆在阴极射线管上的溶液。 在上述方法中，当使用硅醇盐作为金属醇盐时，可以获得在面板的最外表面上具有由无碱二氧化硅制成的防反射膜的阴极射线管，所述防反射膜 当测量红外光谱时，Si-O-Si峰强度与Si-OH峰强度之比为4以上。

公开(公告)号：US5817421A

公开(公告)日：1998-10-06

申请号：US446512

申请日：1995-05-22

申请人： Tomoji Oishi ,  Sachiko Maekawa ,  Akira Kato ,  Masahiro Nishizawa ,  Yoshifumi Tomita ,  Kojiro Okude ,  Kenji Tochigi ,  Yutaka Misawa

发明人： Tomoji Oishi ,  Sachiko Maekawa ,  Akira Kato ,  Masahiro Nishizawa ,  Yoshifumi Tomita ,  Kojiro Okude ,  Kenji Tochigi ,  Yutaka Misawa

IPC分类号： G02B1/11 ,  H01J29/89 ,  B32B9/04

CPC分类号： G02B1/11 ,  H01J29/896 ,  H01J2209/012

摘要： An anti-reflection film is produced on the panel surface of a cathode-ray tube by: (A) preparing a solution for forming an anti-reflection film, which contains water and a metal alkoxide having the formula, M(OR).sub.n wherein M is a metal selected from the group consisting of Si, Ti, Al, Zr, Sn, In, Sb and Zn; R is an alkyl group having 1-10 carbon atoms; n is an integer of from 1 to 8; and when n is not 1, the alkyl groups represented by R may be the same or different, (B) coating the solution for forming an anti-reflection film on the outermost surface of the panel of a cathode-ray tube, and (C) applying an ultraviolet light to the solution for forming an anti-reflection film coated on said surface to cure the solution to form a transparent film with fine roughness. This production method is carried out using an apparatus having: (a) a coating means for coating the above solution for forming an anti-reflection film on the outermost surface of the panel of a cathode-ray tube, (b) a transferring means for transferring the solution-coated cathode-ray tube, and (c) an ultraviolet light-applying means for photocuring the solution coated on the cathode-ray tube during the transfer of the solution-coated cathode-ray tube. In the above method, when a silicon alkoxide is used as the metal alkoxide, there can be obtained a cathode-ray tube having an anti-reflection film made of alkali-free silica on the outermost surface of the panel, said anti-reflection film giving a ratio of Si-O-Si peak intensity to Si-OH peak intensity of 4 or more when measured for infrared spectrum.

摘要翻译： 在阴极射线管的面板表面上，通过以下方法在阴极射线管的面板表面上产生防反射膜：（A）制备形成抗反射膜的溶液，该防反射膜含有水和具有式M（OR）n的金属醇盐，其中M 是选自由Si，Ti，Al，Zr，Sn，In，Sb和Zn组成的组的金属; R是具有1-10个碳原子的烷基; n为1〜8的整数， 当n不为1时，由R表示的烷基可以相同或不同，（B）在阴极射线管的面板的最外表面上涂布形成抗反射膜的溶液，（C ）向所述溶液施加紫外光以形成涂覆在所述表面上的抗反射膜，以使溶液固化以形成具有精细粗糙度的透明膜。 该制造方法使用以下装置进行：（a）在阴极射线管的面板的最表面上涂布上述用于形成防反射膜的溶液的涂布装置，（b）转印装置， 转移溶液涂覆的阴极射线管，以及（c）紫外线照射装置，用于在涂覆阴极射线管的转印期间光固化涂覆在阴极射线管上的溶液。 在上述方法中，当使用硅醇盐作为金属醇盐时，可以获得在面板的最外表面上具有由无碱二氧化硅制成的防反射膜的阴极射线管，所述防反射膜 当测量红外光谱时，Si-O-Si峰强度与Si-OH峰强度之比为4以上。