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    SULFIDE SOLID ELECTROLYTE MATERIAL, BATTERY, AND PRODUCING METHOD FOR SULFIDE SOLID ELECTROLYTE MATERIAL
    4.
    发明申请
    SULFIDE SOLID ELECTROLYTE MATERIAL, BATTERY, AND PRODUCING METHOD FOR SULFIDE SOLID ELECTROLYTE MATERIAL 有权
    硫化固体电解质材料，电池和硫化固体电解质材料的生产方法

    公开(公告)号：US20150357673A1

    公开(公告)日：2015-12-10

    申请号：US14760344

    申请日：2013-12-18

    Applicant: TOKYO INSTITUTE OF TECHNOLOGY ,  TOYOTA JIDOSHA KABUSHIKI KAISHA

    Inventor： Ryoji KANNO ,  Masaaki HIRAYAMA ,  Yuki KATO ,  Hisatsugu YAMASAKI

    IPC: H01M10/0562 ,  H01M10/052

    CPC classification number: H01M10/0562 ,  H01B1/10 ,  H01B1/122 ,  H01M4/62 ,  H01M10/052 ,  H01M2220/30 ,  H01M2300/0068 ,  Y02T10/7011

    Abstract: The problem is to provide a sulfide solid electrolyte material with favorable Li ion conductivity in a low-temperature environment. The problem is overcome by providing a sulfide solid electrolyte material comprising an M1 element (such as an Li element and an Mg element), an M2 element (such as a Ge element and a P element) and a S element, wherein the sulfide solid electrolyte material has a peak at a position of 2θ=29.58°±0.50° in X-ray diffraction measurement using a CuKα ray, does not have a peak at a position of 2θ=27.33°±0.50° or slightly having the peak, and a substituted amount δ(%) of the divalent element in the M1 element is in such a range that the sulfide solid electrolyte material exhibits higher Li ion conductance at 0° C. than the case of δ=0.

    Abstract translation: 问题在于提供在低温环境下具有良好的Li离子传导性的硫化物固体电解质材料。 通过提供包含M1元素（例如Li元素和Mg元素），M2元素（例如Ge元素和P元素）和S元素的硫化物固体电解质材料来克服该问题，其中硫化物固体 在使用CuKα射线的X射线衍射测定中，电解质材料在2θ= 29.58°±0.50°的位置处具有峰值，在2θ的位置处没有峰值; = 27.33°±0.50°或略高于峰值 ，并且M1元素中的二价元素的取代量δ（％）在使得硫化物固体电解质材料在0℃下表现出比δ= 0的情况下更高的Li离子传导的范围。

    SULFIDE SOLID ELECTROLYTE
    5.
    发明申请
    SULFIDE SOLID ELECTROLYTE 审中-公开

    公开(公告)号：US20190074541A1

    公开(公告)日：2019-03-07

    申请号：US16083597

    申请日：2017-03-10

    Applicant: Tokyo Institute of Technology

    Inventor： Ryoji Kanno ,  Masaaki HIRAYAMA ,  Kota SUZUKI ,  Yulong SUN

    IPC: H01M10/0562 ,  H01M10/0525 ,  C04B35/547 ,  C04B35/626 ,  C04B35/64

    Abstract: To provide a sulfide solid electrolyte material which does not include Ge and which has excellent electrochemical stability and high lithium ion conductivity.A sulfide solid electrolyte, including a sulfide-based solid electrolyte represented by the composition formula: Li4-4z-x[SnySi1-y]1+z-xPxS4 (where 0.5≤x≤0.6, y=0.2, and 0≥z≥−0.2), wherein the sulfide solid electrolyte has a peak at position 2θ=29.58°±0.50° in X-ray diffraction measurement using CuKα radiation and does not have a peak at position 2θ=27.33°±0.50° in X-ray diffraction measurement using CuKα radiation, or when the sulfide solid electrolyte has a peak at the position 2θ=27.33°±0.50°, the value of IB/IA is less than 0.50 (where IA is the diffraction intensity of the 2θ=29.58°±0.50° peak and IB is the diffraction intensity of the 2θ=27.33°±0.50° peak).

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