摘要:
A process for preparing acrylic acid by heterogeneously catalyzed partial oxidation of at least one C3 hydrocarbon precursor compound, in which the secondary component formation is ≦1.5 mol %.
摘要翻译:通过至少一种C 3 O 3烃前体化合物的非均相催化部分氧化制备丙烯酸的方法,其中第二组分形成<= 1.5mol%。
摘要:
A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of acrolein to acrylic acid, in which the temperature of the fixed catalyst bed is increased over time and partial oxidation is interrupted and an oxygen-containing gas is conducted through the fixed catalyst bed before the temperature increase is 8° C.
摘要:
A process for preparing an organic target compound by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound with molecular oxygen in two oxidation reactor lines operated in parallel and removal of the target compound from the mixture of the product gas streams in a workup line, wherein the catalyst charge of one of the oxidation lines comprises a portion of catalyst over which the heterogeneously catalyzed gas phase partial oxidation has already been carried out for longer than over the portions of catalyst of the catalyst charge of the other oxidation reactor line.
摘要:
A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of propene to acrolein, in which the temperature of the fixed catalyst bed is increased over the time and the gas phase partial oxidation is interrupted at least once per calendar year and the gas mixture G consisting of molecular oxygen, inert gas and optionally steam is conducted through the fixed catalyst bed at a temperature of the fixed catalyst bed of from 250 to 550° C.
摘要:
A process for preparing (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound over a fresh fixed catalyst bed, in which the process is started up at a reduced hourly space velocity of charging gas mixture on the fixed catalyst bed.
摘要:
In a process for partially oxidizing propene to acrylic acid in the gas phase under heterogeneous catalysis, a starting reaction gas mixture comprising propene and oxygen and having a specific composition is oxidized in a first reaction stage over a first fixed catalyst bed having a volume-specific activity which is constant or increases in the flow direction and the acrolein-containing product gas mixture of the first reaction stage is subsequently oxidized in a second reaction stage over a second fixed catalyst bed having a volume-specific activity increasing in the flow direction, and the shaped catalyst bodies of both fixed catalyst beds are annular and each have a specific multimetal oxide composition.
摘要:
A process for the long-term operation of a two-stage heterogeneously catalyzed gas phase partial oxidation of propene to acrylic acid, in which the temperature of the fixed catalyst beds is increased over the time and the gas phase partial oxidation is interrupted from time to time and an oxygen-containing gas mixture is conducted through the fixed catalyst beds at elevated temperature of the fixed catalyst beds.
摘要:
The present invention relates to a process for charging a reactor with a catalyst, to the resulting charged reactors, and to the use thereof for carrying out catalytic gas phase reactions.
摘要:
The present invention relates to a process for charging a reactor with a catalyst, to the resulting charged reactors, and to the use thereof for carrying out catalytic gas phase reactions.
摘要:
An annular unsupported catalyst for the heterogeneously catalyzed partial gas phase oxidation of propene to acrolein at a propene hourly space velocity on the fixed catalyst bed of ≧120 1 (STP)/l·h and a total CO2 and saturated hydrocarbon content of the starting reaction gas mixture of below 15 mol %, the catalysts of the fixed catalyst bed are the annular unsupported catalysts whose active composition is a multimetal oxide in which the molar Co/Fe ratio=from 2 to 4 and the molar Co/Mo ratio=from 0.3 to 0.7.