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    Method for the heterogeneously catalyzed partial gas phase oxidation of propene into acrylic acid
    4.
    发明申请
    Method for the heterogeneously catalyzed partial gas phase oxidation of propene into acrylic acid 审中-公开
    丙烯非均相催化部分气相氧化丙烯的方法

    公开(公告)号：US20060135813A1

    公开(公告)日：2006-06-22

    申请号：US10543060

    申请日：2004-03-20

    申请人： Martin Dieterle ,  Jochen Petzoldt ,  Klaus Muller-Engel ,  Hans Martan

    发明人： Martin Dieterle ,  Jochen Petzoldt ,  Klaus Muller-Engel ,  Hans Martan

    IPC分类号： C07C51/16

    CPC分类号： C07C51/252 ,  C07C57/04

    摘要： In a process for partially oxidizing propene to acrylic acid in the gas phase under heterogeneous catalysis, a starting reaction gas mixture comprising propene and oxygen and having a specific composition is oxidized in a first reaction stage over a first fixed catalyst bed having a volume-specific activity which is constant or increases in the flow direction and the acrolein-containing product gas mixture of the first reaction stage is subsequently oxidized in a second reaction stage over a second fixed catalyst bed having a volume-specific activity increasing in the flow direction, and the shaped catalyst bodies of both fixed catalyst beds are annular and each have a specific multimetal oxide composition.

    摘要翻译： 在非均相催化下在气相中将丙烯部分氧化为丙烯酸的方法中，包含丙烯和氧并具有特定组成的起始反应气体混合物在第一反应阶段在具有体积特异性的第一固定催化剂床上被氧化 随后在第二反应阶段，在流动方向上具有体积比活度增加的第二固定催化剂床上氧化第一反应段的流动方向恒定或增加的含丙烯醛的产物气体混合物的活性，以及 两个固定催化剂床的成形催化剂体是环状的，并且各自具有特定的多金属氧化物组合物。

    Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation
    7.
    发明申请
    Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation 有权
    通过非均相催化气相部分氧化制备至少一种有机靶化合物的方法

    公开(公告)号：US20060199975A1

    公开(公告)日：2006-09-07

    申请号：US11357300

    申请日：2006-02-21

    申请人： Martin Dieterle ,  Klaus Muller-Engel ,  Jochen Petzoldt ,  Ulrich Hammon

    发明人： Martin Dieterle ,  Klaus Muller-Engel ,  Jochen Petzoldt ,  Ulrich Hammon

    IPC分类号： C07C51/16

    CPC分类号： C07C51/252 ,  C07C57/04

    摘要： A process for preparing an organic target compound by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound with molecular oxygen in two oxidation reactor lines operated in parallel and removal of the target compound from the mixture of the product gas streams in a workup line, wherein the catalyst charge of one of the oxidation lines comprises a portion of catalyst over which the heterogeneously catalyzed gas phase partial oxidation has already been carried out for longer than over the portions of catalyst of the catalyst charge of the other oxidation reactor line.

    摘要翻译： 通过在两个平行操作的氧化反应器管线中的有机前体化合物与分子氧的非均相催化气相部分氧化来制备有机靶化合物的方法，并且从处理线中的产物气流的混合物中除去目标化合物， 其中一个氧化线的催化剂装料包括催化剂的一部分，在该部分的催化剂上已经进行非均相催化的气相部分氧化比在另一个氧化反应器管线的催化剂装料的催化剂的部分长的时间。

    Heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid
    9.
    发明授权
    Heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid 有权
    丙烯醛的异相催化部分气相氧化成丙烯酸

    公开(公告)号：US06982347B2

    公开(公告)日：2006-01-03

    申请号：US10806460

    申请日：2004-03-23

    申请人： Martin Dieterle ,  Jochen Petzoldt ,  Klaus Joachim Müller-Engel ,  Heiko Arnold

    发明人： Martin Dieterle ,  Jochen Petzoldt ,  Klaus Joachim Müller-Engel ,  Heiko Arnold

    IPC分类号： C07C51/235

    CPC分类号： C07C51/252 ,  C07C57/04

    摘要： In a process for partially oxidizing acrolein to acrylic acid in the gas phase under heterogeneous catalysis, the starting reaction gas mixture is oxidized at an acrolein loading of ≦145 and ≧70 l (STP) of acrolein/l of fixed catalyst bed·h over a fixed catalyst bed which is accommodated in two successive reaction zones A, B, the highest temperature of the reaction gas mixture within reaction zone A being above the highest temperature of the reaction gas mixture within reaction zone B.

    摘要翻译： 在非均相催化下在气相中将丙烯醛部分氧化为丙烯酸的方法中，起始反应气体混合物以丙烯醛负载<= 145和> = 70l（STP）的丙烯醛/ l固定催化剂床进行氧化。 h在固定的催化剂床上，其被容纳在两个连续的反应区A，B中，反应区A内的反应气体混合物的最高温度高于反应区B内的反应气体混合物的最高温度。

    Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid
    10.
    发明授权
    Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid 有权
    将丙烯非均相催化部分气相氧化成丙烯酸

    公开(公告)号：US07164039B2

    公开(公告)日：2007-01-16

    申请号：US10808282

    申请日：2004-03-25

    申请人： Jochen Petzoldt ,  Martin Dieterle ,  Heiko Arnold ,  Wilhelm Ruppel ,  Klaus Joachim Mueller-Engel

    发明人： Jochen Petzoldt ,  Martin Dieterle ,  Heiko Arnold ,  Wilhelm Ruppel ,  Klaus Joachim Mueller-Engel

    IPC分类号： C07C51/16

    CPC分类号： C07C51/252 ,  C07C57/04

    摘要： In a process for heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid, the propene-containing starting reaction gas mixture is oxidized in a first reaction stage using a fixed catalyst bed 1 which consists of a plurality of fixed catalyst bed zones and is accommodated in two successive temperature zones A, B, and the acrolein-containing product gas mixture of the first reaction stage is then oxidized in a second reaction stage using a fixed catalyst bed 2 which consists of a plurality of fixed catalyst bed zones and is accommodated in two successive temperature zones C, D, and the transition from one temperature zone to another temperature zone within one reaction stage does not spatially coincide with a transition from one fixed catalyst bed zone to another fixed catalyst bed zone.

    摘要翻译： 在将丙烯非均相催化的部分气相氧化成丙烯酸的方法中，含丙烯的起始反应气体混合物在第一反应阶段中使用由多个固定催化剂床区组成的固定催化剂床1被氧化， 在两个连续的温度区A，B和第一反应阶段的含丙烯醛的产物气体混合物然后在第二反应阶段中使用由多个固定催化剂床区组成的固定催化剂床2进行氧化， 两个连续的温度区域C，D以及在一个反应​​阶段内从一个温度区域到另一个温度区域的过渡在空间上与从一个固定催化剂床区域到另一个固定催化剂床区域的过渡不一致。