摘要:
Methods for producing hydrogen from ammonia are described. The methods involve the use of a two-stage hydrogen PSA configuration. The effluent stream from the ammonia cracking reaction zone is sent to the first hydrogen PSA unit where it is separated into a high purity, high-pressure hydrogen stream and a low-pressure tail gas stream. The high-pressure hydrogen stream can be recovered. The low-pressure tail gas stream is compressed and sent to the second hydrogen PSA unit where it is separated into a second high-pressure stream and a second low-pressure tail gas stream. The second high-pressure hydrogen stream can be recycled to the first hydrogen PSA unit for further separation.
摘要:
A temperature swing adsorption process for the removal of a target species, such as an acid gas, from a gas mixture, such as a natural gas stream. Herein, a novel multi-step temperature swing/pressure swing adsorption is utilized to operate while maintaining very high purity levels of contaminant removal from a product stream. The present process is particularly effective and beneficial in removing contaminants such as CO2 and/or H2S from a natural gas at relatively high adsorption pressures (e.g., at least 500 psig) to create product streams of very high purity (i.e., very low contaminant levels).
摘要:
The present invention relates to a pressure-temperature swing adsorption process wherein gaseous components that have been adsorbed can be recovered from the adsorbent bed at elevated pressures. In particular, the present invention relates to a pressure-temperature swing adsorption process for the separation of C2+ hydrocarbons (hydrocarbons with at least 2 carbon atoms) from natural gas streams to obtain a high purity methane product stream. In more preferred embodiments of the present processes, the processes may be used to obtain multiple, high purity hydrocarbon product streams from natural gas stream feeds resulting in a chromatographic-like fractionation with recovery of high purity individual gaseous component streams.
摘要:
System for producing an oxygen-rich gas comprising (a) a primary gas mover including a first and a second compressor, wherein the primary gas mover is characterized by a weight Wp; (b) a drive motor adapted to drive the first and second compressors; (c) a rechargeable power supply characterized by a weight, Wb; and (d) a pressure/vacuum swing adsorption unit adapted to separate the pressurized feed air into an oxygen-rich product at a product flow rate Fp and an oxygen-depleted waste gas, wherein the adsorption unit comprises a plurality of adsorber beds containing an adsorbent and characterized by a total adsorbent weight Wa; and wherein the combined weight, Wt, of the adsorbent, the primary gas mover, and the rechargeable power supply is characterized by the expression 0.75 Fp
摘要:
The present invention is directed to an improved integrated process for the removal of heavy hydrocarbons, carbon dioxide, hydrogen sulfide, and water from a raw natural gas feed stream. More specifically, the integrated process of the present invention comprises a three step process involving the adsorption of heavy hydrocarbons and water on an adsorbent bed selective for the same, a subsequent aqueous lean amine treatment for the absorptive removal of acid gases, such as carbon dioxide and hydrogen sulfide, and an adsorptive removal of water. The process of the present invention results in a highly purified natural gas product stream.
摘要:
A pressure swing adsorption method for separating gas components includes pressurizing an adsorption bed to an adsorption pressure using a first gas component of a feed gas, the adsorption bed including an adsorbent for substantially adsorbing a second gas component of a feed gas; introducing the feed gas to the pressurized adsorption bed, wherein the first gas component of the feed gas substantially passes through the pressurized adsorption bed and the second gas component of the feed gas substantially adsorbs onto the adsorbent; and depressurizing the pressurized adsorption bed to recover at least a portion of the second gas component of the feed gas in the pressurized adsorption bed.
摘要:
The present invention is directed to an improved integrated process for the removal of heavy hydrocarbons, carbon dioxide, hydrogen sulfide, and water from a raw natural gas feed stream. More specifically, the integrated process of the present invention comprises a three step process involving the adsorption of heavy hydrocarbons and water on an adsorbent bed selective for the same, a subsequent aqueous lean amine treatment for the absorptive removal of acid gases, such as carbon dioxide and hydrogen sulfide, and an adsorptive removal of water. The process of the present invention results in a highly purified dry natural gas product stream.
摘要:
Process step in a pressure swing adsorption process using multiple parallel adsorbent beds operating in cyclic process steps to recover a less strongly adsorbable component from a feed gas mixture containing at least one less strongly adsorbable component and at least one more strongly adsorbable component, wherein each adsorbent bed has a feed end and a product end, wherein each bed is subjected to at least a feed/product step, one or more depressurization steps, a purge step in which a purge gas enriched in the less strongly adsorbable component is introduced into the product end of the bed and a purge effluent gas is withdrawn from the feed end of the bed, and one or more repressurization steps. The process step comprises introducing at least a portion of the purge effluent gas from a first bed into the feed end of a second adsorbent bed at any time other than during the feed/product step in the second adsorbent bed.
摘要:
Disclosed embodiments of the apparatus address the challenges of rotary PSA systems, both axial and radial flow, with M>1 by providing interpenetrating, layered manifolds to accommodate all of the steps of a complex PSA cycle, suitable with equal compactness for any value of nullMnull. This approach extends readily to accommodate a plurality of rotary PSA modules and their cooperating compression machinery within a single layered manifold assembly for a single PSA plant train. Described embodiments of the rotary PSA apparatus include stators that define fluid ports. In particular embodiments of the described apparatus, a second stator defines pressure swing adsorption cycle sectors, each sector being defined by a light product delivery port, light product withdrawal ports, and light reflux return ports. The adsorber elements may directly contact one or more of the stators in a fluidly sealing manner (i.e., have a clearance gap of from about 0 to about 50 microns) using described reinforced adsorbers. The method comprises providing an embodiment of the described apparatus and then supplying at least one feed fluid to pressurize an adsorber element of the adsorber sets to substantially a higher pressure to initiate a pressure swing adsorption cycle.
摘要:
Each adsorber (1, 2) is dimensioned in such a way that it operates in substantially adiabatic mode and its production dead volume (27), which is the free volume in permanent communication with the outlet side end of the mass of adsorbent (6), is between about 10% and 60% of the volume of the mass of adsorbent. Oxygen may thus be produced from atmospheric air.