公开(公告)号：US3811972A

公开(公告)日：1974-05-21

申请号：US83022269

申请日：1969-06-02

申请人： ETHYL CORP

发明人： NIEBYLSKI L ,  BRENDEL G

IPC分类号： C01B3/12 ,  C01B13/08 ,  C06B27/00 ,  C06B15/00

CPC分类号： C06B27/00 ,  C01B3/12 ,  C01B13/086

摘要： LITHIUM-DOPED AMORPHOUS BERYLLIUM HYDRIDE SLURRIED WITH RELATIVELY SMALL AMOUNTS OF AN INERT LIQUID SLURRY MEDIUM CAN BE CRYSTALLIZED BY EXPOSURE FOR A SUFFICIENT TIME TO ELEVATED TEMPERATURE AND PRESSURE. SUITABLE SOLVENTS ARE HIGH-BOILING HYDROCARBONS. A VITREOUS COMPOSITE SUITABLE FOR USE IN THIS CRYSTALLIZATION PROCESS CAN BE PREPARED BY COMPRESSING LITHIUM-DOPED, AMORPHOUS BERYLLIUM HYDRIDE AND HEATING THE RESULTING COMPACT.

公开(公告)号：US2427707A

公开(公告)日：1947-09-23

申请号：US44968242

申请日：1942-07-03

申请人： LINDE AIR PROD CO

发明人： BRIMM EUGENE O

IPC分类号： C01B13/08

CPC分类号： C01B13/086

公开(公告)号：US4089938A

公开(公告)日：1978-05-16

申请号：US815983

申请日：1977-07-15

申请人： Nelson C. Turner

发明人： Nelson C. Turner

IPC分类号： C01B13/08

CPC分类号： C01B13/086

摘要： A process is provided for recovering oxygen from air and particularly providing a product stream comprising a mixture of oxygen and steam useful, for example, in coal gasification processes. The instant process involves contacting a suspension of manganese dioxide in an aqueous solution of sodium or potassium hydroxide with air in a low pressure absorbing zone. The resulting liquid oxygen enriched stream is then pumped into a relatively high pressure generating zone where it is contacted with steam to release oxygen absorbed in the absorbing zone and thereby provide the above mentioned product.

摘要翻译： 提供了一种用于从空气中回收氧的方法，特别是提供了一种包含例如在煤气化过程中有用的氧气和蒸汽的混合物的产物流。 本方法包括将二氧化锰悬浮液与氢氧化钠或氢氧化钾的水溶液与低压吸收区中的空气接触。 然后将所得的富含氧气的物流泵送到相对较高的压力产生区域中，在其中与蒸汽接触以释放在吸收区域中吸收的氧，从而提供上述产品。

公开(公告)号：US3833508A

公开(公告)日：1974-09-03

申请号：US18854071

申请日：1971-10-12

申请人： ITT

发明人： AUSTIN R ,  VINCENT A

IPC分类号： B01D53/50 ,  B01D53/52 ,  C01B13/08 ,  C01B31/16

CPC分类号： C01B13/086 ,  B01D53/501 ,  B01D53/523

摘要： A SELECTIVE METHOD OF REMOVING SULFUR DIOXIDE FROM FLUE GASES OR THE LIKE CONTAINING BOTH SULFU DIOXIDE AND HYDROGEN SULFIDE WITHOUT REMOVING THE HYDROGEN SULFIDE BY BUBBLING THE FLUE GAS THROUGH ABOUT A 5-95 PERCENT SOLUTION OF AN ORGANIC ACID AND AN ALKALI METAL SALT OF THE SAID ACID. THE ACID IS SELECTED FROM THE GROUP OF CITRIC, MALIC, LACTIC, SUCCINIC, ASCORBIC AND TARTARIC. THE ACID IS PREFERABLY CITRIC AND THE ALKALI METAL IS PREFERABLY POTASSIUM. THE RATIO OF THE WEIGHT OF THE SALT TO THAT OF THE ACID MAY BE WITHIN THE RANGE OF ABOUT 1S:2A TO 6S:1A OR SUCH AS IS NEEDED TO MAKE THE SOLUTION PH BETWEEN ABOUT 4.0 TO 6.0, WHERE S AND A ARE ONE MOLE EACH OF SAID SALT AND SAID ACID, RESPECTIVELY. THE SAID RATIO PREFERABLY IS 5S:1A OR THE PH IS PREFERABLY 5.7.

公开(公告)号：US3807957A

公开(公告)日：1974-04-30

申请号：US51102165

申请日：1965-11-24

申请人： GEN DYNAMICS CORP

发明人： SEVIER W

IPC分类号： B01D53/46 ,  C01B13/02 ,  C01B13/08 ,  B01J7/00

CPC分类号： B01D53/46 ,  C01B13/0233 ,  C01B13/086 ,  C01B2210/0046

摘要： A chemical separator for extracting oxygen from air having a ram air inlet opening into a venturi. High velocity, high temperature venturi air is ducted into the high pressure chambers of a plurality of radially disposed, peripherally driven, cylinders or drums rotated by air turbines. The cylinders are divided into high and low pressure chambers by a stationary panel fixed at its opposite ends to the frame of the separator. Cylinders are of double wall construction having a multiplicity of screened openings therein. Chemicals are contained between the cylinder walls for collecting and discharging oxygen as the chemicals are cycled between the high and low pressure chambers of the cylinders. Heat exchangers positioned in the low pressure chambers of the cylinders, cool the oxygen released by the chemicals to a liquid state for convenience in storage or direct ducting to a power plant.

摘要翻译： 一种用于从具有冲压进气孔的空气中提取氧气到文丘里管的化学分离器。 高速，高温文丘里管空气被引导到由空气涡轮机旋转的多个径向设置的外围驱动的气缸或滚筒的高压室中。 气缸通过固定在其相对端固定在分离器的框架上的固定板分成高压室和低压室。 气缸是双壁结构，其中具有多个筛选的开口。 当化学品在气缸的高压室和低压室之间循环时，化学物质被包含在气缸壁之间用于收集和排出氧气。 位于气缸的低压室中的热交换器将化学品释放的氧气冷却至液体状态，以方便储存或直接运送至发电厂。

公开(公告)号：US20110300060A1

公开(公告)日：2011-12-08

申请号：US13116255

申请日：2011-05-26

申请人： Florent GUILLOU ,  Ali Hoteit

发明人： Florent GUILLOU ,  Ali Hoteit

IPC分类号： C01B13/02 ,  B01J8/18

CPC分类号： C01B13/08 ,  C01B13/086 ,  F23C10/005 ,  F23C2900/99008 ,  F23L7/007 ,  Y02E20/344 ,  Y02E20/346 ,  Y02P20/584

摘要： The invention relates to a method and to a plant for producing high-purity oxygen, said method comprising a chemical loop wherein circulates a fluidized bed material having the capacity to release gaseous oxygen through oxygen partial pressure lowering, at a temperature ranging between 400° C. and 700° C. The oxygen thus produced can be used in applications such as oxycombustion methods, production of syngas under pressure or FCC catalyst regeneration.

摘要翻译： 本发明涉及用于生产高纯氧的方法和设备，所述方法包括一种化学回路，其中循环具有通过氧分压降低释放气态氧的能力的流化床材料，温度范围为400℃ 和700℃。由此产生的氧气可用于例如氧燃烧方法，在压力下生产合成气或FCC催化剂再生。

公开(公告)号：US3903010A

公开(公告)日：1975-09-02

申请号：US27776972

申请日：1972-08-03

申请人： CONS NATURAL GAS SVC

发明人： MASSEY LESTER G ,  TARMAN PAUL B ,  PUNWANI DHARAMVIR

IPC分类号： C01B13/08

CPC分类号： C01B13/086 ,  C01B13/083

摘要： Process of preparing special oxygen acceptor compositions for the production of oxygen in modified Brin-type processes. The preparation process comprises forming a physical mixture of finely ground barium carbonate and a composition or compound containing Mg and Ca carbonates, e.g., dolomite, in predetermined proportions, and heating them under an inert gas, such as nitrogen, or in a vacuum to convert the barium carbonate to barium monoxide and the dolomite dolomitic quicklime. Thereafter, the composition is heated in a dry, CO2-free atmosphere of air or oxygen to convert the barium monoxide to barium peroxide to form the final composition of barium peroxide-dolomitic quicklime. Pellets, powders, granules and coatings of the material may be formed. The mixture may be pelletized before or after either conversion step. Other decomposable compounds of magnesium and calcium may be used in place of the preferred dolomite. The end product compositions should have a carbon dioxide level such that the CO2/BaO2 mole ratio in the mixture is less than 1.0. Modified Brin-type processes employing pellets of this composition show improved oxidation and reduction rates and SORT conversion values for times in excess of typical static bed cycle time or fluidized bed residence time.

摘要翻译： 制备用于在改性Brin型工艺中生产氧气的特殊氧受体组合物的方法。 制备方法包括以预定比例形成精细研磨的碳酸钡和含有Mg和Ca的碳酸钙（例如白云石）的组合物或化合物的物理混合物，并在惰性气体如氮气或真空中加热，以转化 碳酸钡与一氧化一氧化铅和白云石白云石生石灰。 此后，将该组合物在空气或氧气的无CO2无氧气氛中加热，以将一氧化钡转化成过氧化钡，形成过氧化二砷 - 白云石生石灰的最终组合物。 可以形成材料的颗粒，粉末，颗粒和涂层。 混合物可以在转化步骤之前或之后造粒。 可以使用镁和钙的其它可分解化合物代替优选的白云石。 最终产品组合物应具有二氧化碳水平，使得混合物中的CO 2 / BaO 2摩尔比小于1.0。 使用该组合物的颗粒的改性的布林型方法在超过典型的静态床循环时间或流化床停留时间的时间内显示改进的氧化和还原速率和SORT转化值。

公开(公告)号：US3276846A

公开(公告)日：1966-10-04

申请号：US21938762

申请日：1962-08-27

申请人： UNIVERSELLE DE PROD CHIM ET D

发明人： JEAN MONI ,  DE SCDOUY PHILIPPE LE CHARTIER ,  JACQUES THEVENEAU

IPC分类号： A62B21/00 ,  A62D9/00 ,  B63C11/18 ,  C01B13/00 ,  C01B13/02 ,  C01B13/08

CPC分类号： C01B13/086 ,  A62B21/00 ,  B63C11/184 ,  C01B13/0218 ,  C01B13/0296

公开(公告)号：US2642340A

公开(公告)日：1953-06-16

申请号：US66867246

申请日：1946-05-10

申请人： STANDARD OIL DEV CO

发明人： MARTIN HOMER Z

IPC分类号： C01B13/08

CPC分类号： C01B13/086

公开(公告)号：US3757488A

公开(公告)日：1973-09-11

申请号：US3757488D

申请日：1972-12-05

申请人： ITT

发明人： AUSTIN R ,  VINCENT A

IPC分类号： B01D53/50 ,  B01D53/52 ,  C01B13/08 ,  B01D53/16

CPC分类号： C01B13/086 ,  B01D53/501 ,  B01D53/523

摘要： A selective method of removing sulfur dioxide from flue gases or the like containing both sulfur dioxide and hydrogen sulfide without removing the hydrogen sulfide by bubbling the flue gas through about a 5-95 percent solution of an organic acid and an alkali metal salt of the said acid. The acid is selected from the group of: citric malic, lactic, succinic, ascorbic and tartaric. The acid is preferably citric and the alkali metal is preferably potassium. The ratio of the weight of the salt to that of the acid may be within the range of about 1s: 2a to 6s: 1a as such as is needed to make the solution pH between about 4.0 and 6.0, where s and a are one mole each of said salt and said acid, respectively. The said ratio preferably is 5s:1a or the pH is preferably 5.7.

摘要翻译： 一种从含有二氧化硫和硫化氢的烟气等中除去二氧化硫的选择性方法，而不用通过使烟道气通过约5-95％的所述有机酸和碱金属盐的5-95％溶液来除去硫化氢 酸。 酸选自：柠檬酸苹果酸，乳酸，琥珀酸，抗坏血酸和酒石酸。 酸优选为柠檬酸，碱金属优选为钾。 盐的重量与酸的重量比可以在约1s：2a至6s：1a的范围内，因为使溶液pH在约4.0和6.0之间是需要的，其中s和a是1摩尔 分别是所说的盐和所说的酸。 所述比例优选为5s：1a或pH优选为5.7。