公开(公告)号：US20150344663A1

公开(公告)日：2015-12-03

申请号：US14818943

申请日：2015-08-05

Applicant: ASPEN AEROGELS,INC.

Inventor： Owen R Evans ,  Wenting Dong ,  Kiranmayi Deshpande

IPC: C08J9/28 ,  C08J9/00 ,  C08K5/548

CPC classification number: C08J9/28 ,  B01J13/0065 ,  B01J13/0091 ,  C08C19/25 ,  C08J9/0085 ,  C08J2347/00 ,  C08K5/548 ,  C08K7/02

Abstract: Methods and materials are described for preparing organic-inorganic hybrid gel compositions where a sulfur-containing cross-linking agent covalently links the organic and inorganic components. The gel compositions are further dried to provide porous gel compositions and aerogels. The mechanical and thermal properties of the dried gel compositions are also disclosed.

Abstract translation: 描述了制备有机 - 无机杂化凝胶组合物的方法和材料，其中含硫交联剂共价连接有机和无机组分。 将凝胶组合物进一步干燥以提供多孔凝胶组合物和气凝胶。 还公开了干燥的凝胶组合物的机械和热性质。

公开(公告)号：US09085893B2

公开(公告)日：2015-07-21

申请号：US14508740

申请日：2014-10-07

Applicant: ASPEN AEROGELS, INC.

Inventor： Wenting Dong ,  Wendell E Rhine ,  Decio Coutinho

IPC: C08G73/10 ,  C08L83/02 ,  E04B1/78 ,  B01J13/00 ,  C08G77/54 ,  C08K3/20 ,  F16L59/02

CPC classification number: C08J9/286 ,  B01J13/0091 ,  C08G73/106 ,  C08G77/54 ,  C08G2220/00 ,  C08J9/0066 ,  C08J9/0085 ,  C08J2201/0502 ,  C08J2205/026 ,  C08J2379/08 ,  C08K3/20 ,  E04B1/78 ,  F16L59/028

Abstract: Disclosed and claimed herein are hybrid aerogels which are compositions of tetraalkoxysilanes and bis-(trialkoxysilyl)imides that exhibit low thermal conductivities and high compressive strengths. Methods for their preparation are also provided.

Abstract translation: 本文公开和要求保护的是混合气凝胶，其是表现出低导热性和高抗压强度的四烷氧基硅烷和双 - （三烷氧基甲硅烷基）酰亚胺的组合物。 还提供了其制备方法。

公开(公告)号：US20150065590A1

公开(公告)日：2015-03-05

申请号：US14536735

申请日：2014-11-10

Applicant: ASPEN AEROGELS,INC.

Inventor： Wendell E Rhine ,  Decio Coutinho ,  Kiranmayi Deshpande

IPC: C08J9/28

CPC classification number: F16L59/028 ,  C01B33/145 ,  C01B33/155 ,  C01B33/1585 ,  C08J9/286 ,  C08J2201/0504 ,  C08J2383/04

Abstract: Disclosed and claimed herein are hybrid silica aerogels containing non-polymeric, functional organic materials covalently bonded at one or both ends to the silica network of the aerogels through a C—Si bond between a carbon atom of the organic material and a silicon atom of the aerogel network. Methods of their preparation are also disclosed.

Abstract translation: 本文公开和要求保护的是混合二氧化硅气凝胶，其含有在一端或两端通过有机材料的碳原子与有机材料的硅原子之间的C-Si键在气凝胶的二氧化硅网络上共价结合的非聚合功能有机材料 气凝胶网络 还公开了它们的制备方法。

公开(公告)号：US20150021509A1

公开(公告)日：2015-01-22

申请号：US14508740

申请日：2014-10-07

Applicant: ASPEN AEROGELS,INC.

Inventor： Wenting Dong ,  Wendell E. Rhine ,  Decio Coutinho

IPC: F16L59/02 ,  C08K3/20 ,  C08G77/54

CPC classification number: C08J9/286 ,  B01J13/0091 ,  C08G73/106 ,  C08G77/54 ,  C08G2220/00 ,  C08J9/0066 ,  C08J9/0085 ,  C08J2201/0502 ,  C08J2205/026 ,  C08J2379/08 ,  C08K3/20 ,  E04B1/78 ,  F16L59/028

Abstract: Disclosed and claimed herein are hybrid aerogels which are compositions of tetraalkoxysilanes and bis-(trialkoxysilyl) imides that exhibit low thermal conductivities and high compressive strengths. Methods for their preparation are also provided.

Abstract translation: 本文公开和要求保护的是混合气凝胶，其是表现出低导热性和高抗压强度的四烷氧基硅烷和双 - （三烷氧基甲硅烷基）酰亚胺的组合物。 还提供了其制备方法。

公开(公告)号：US08921436B2

公开(公告)日：2014-12-30

申请号：US13896156

申请日：2013-05-16

Applicant: Aspen Aerogels, Inc.

Inventor： Je Kyun Lee ,  George L Gould

IPC: C08J9/28 ,  C08J9/00 ,  C08F36/00 ,  C08F36/02 ,  C08F36/20 ,  C08G61/08 ,  C08F34/00

CPC classification number: C08F34/00 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418 ,  C08J9/28 ,  C08J2201/0502 ,  C08J2203/08 ,  C08J2205/026

Abstract: Microporous polyolefin and microporous polydicyclopentadiene (polyDCPD) based aerogels and methods for preparing and using the same are provided. The aerogels are produced by forming a polymer gel structure within a solvent from a olefin or dicyclopentadiene monomer 5 via Ring Opening Metathesis Polymerization (ROMP) reactions, followed by supercritical drying to remove the solvent from the aerogel. Other aerogels are prepared by sequentially (1) mixing at least one dicyclopentadiene monomer, at least one solvent at least one catalyst and at least one inorganic and/or organic reinforcing material, (2) gelling the mixture, (3) aging, and (4) supercritical drying. Aerogels provided herein are inexpensive to prepare, possess desirable 10 thermal, mechanical, acoustic, chemical, and physical properties and are hydrophobic. The aerogels provided herein are suitable for use in various applications, including but not limited to thermal and acoustic insulation, radiation shielding, and vibrational damping applications.

Abstract translation: 提供微孔聚烯烃和微孔聚二环戊二烯（polyDCPD）为基础的气凝胶及其制备和使用方法。 气凝胶是通过经由开环复分解聚合（ROMP）反应从烯烃或二环戊二烯单体5在溶剂中形成聚合物凝胶结构，然后通过超临界干燥从气凝胶中除去溶剂而制备的。 其它气凝胶通过顺序地（1）混合至少一种二环戊二烯单体，至少一种溶剂至少一种催化剂和至少一种无机和/或有机增强材料，（2）胶凝该混合物，（3）老化和（ 4）超临界干燥。 本文提供的气凝胶制备成本低廉，具有期望的10种热，机械，声学，化学和物理性质并且是疏水性的。 本文提供的气凝胶适用于各种应用，包括但不限于热和隔音，辐射屏蔽和振动阻尼应用。

公开(公告)号：US20040132845A1

公开(公告)日：2004-07-08

申请号：US10625501

申请日：2003-07-22

Applicant: Aspen Aerogels, Inc.

Inventor： Wendell Rhine ,  Jing Wang ,  Redouane Begag

IPC: C08J009/00

CPC classification number: C08J9/28 ,  B01J13/0091 ,  C08G73/10 ,  C08G73/1028 ,  C08G73/106 ,  C08J2201/0502 ,  C08J2203/08 ,  C08J2205/026 ,  C08J2379/08 ,  Y10T428/31721

Abstract: A preparation process of polyimide aerogels that composed of aromatic dianhydrides and aromatic diamines or a combined aromatic and aliphatic diamines is described. Also descried is a process to produce carbon aerogels derived from polyimide aerogel composed of a rigid aromatic diamine and an aromatic dianhydride. Finally, the processes to produce carbon aerogels or xerogel-aerogel hybrid, both of which impregnated with highly dispersed transition metal clusters, and metal carbide aerogels, deriving from the polyimide aerogels composed of a rigid aromatic diamine and an aromatic dianhydride, are described. The polyimide aerogels and the polyimide aerogel derivatives consist of interconnecting mesopores with average pore size at 10 to 30 nm and a mono-dispersed pore size distribution. The gel density could be as low as 0.008 g/cc and accessible surface area as high as 1300 m2/g.

Abstract translation: 描述了由芳族二酸酐和芳族二胺或组合的芳族和脂族二胺组成的聚酰亚胺气凝胶的制备方法。 还描述了生产由由刚性芳族二胺和芳族二酐组成的聚酰亚胺气凝胶衍生的碳气凝胶的方法。 最后，描述了从由刚性芳族二胺和芳族二酐组成的聚酰亚胺气凝胶产生的碳气凝胶或干凝胶 - 气凝胶混合物的方法，两者均浸渍有高度分散的过渡金属簇和金属碳化物气凝胶。 聚酰亚胺气凝胶和聚酰亚胺气凝胶衍生物由平均孔径为10至30nm的互连介孔和单分散孔径分布组成。 凝胶密度可以低至0.008g / cc，可达到的表面积高达1300m 2 / g。

公开(公告)号：US12272814B2

公开(公告)日：2025-04-08

申请号：US17750190

申请日：2022-05-20

Applicant: Aspen Aerogels, Inc.

Inventor： Nicholas A. Zafiropoulos ,  George L. Gould

IPC: H01M4/38 ,  H01M4/04 ,  H01M4/139 ,  H01M4/66 ,  H01M4/80 ,  H01M10/052 ,  H01M4/02

Abstract: Nanoporous carbon-based scaffolds or structures, and specifically carbon aerogels and their manufacture and use thereof. Embodiments include a sulfur-doped cathode material within a lithium-sulfur battery, where the cathode is collector-less and is formed of a binder-free, monolithic, polyimide-derived carbon aerogel. The carbon aerogel includes pores that surround elemental sulfur and accommodate expansion of the sulfur during conversion to lithium sulfide. The cathode and underlying carbon aerogel provide optimal properties for use within the lithium-sulfur battery.

公开(公告)号：US20250091884A1

公开(公告)日：2025-03-20

申请号：US18698323

申请日：2023-06-09

Applicant: Aspen Aerogels, Inc.

Inventor： Sean Depner ,  Owen Evans ,  lrene Melnikova ,  Roxana Trifu ,  Wendell Rhine ,  George Gould

IPC: C01B33/26 ,  H01M10/658

Abstract: Methods and compositions herein relate to producing an aluminosilicate aerogel. The method may include receiving a silica precursor in solvent, hydrolyzing the silica precursor to produce colloidal silica, introducing an aluminum compound to the colloidal silica to produce a colloidal aluminosilicate suspension, converting the aluminosilicate suspension to an aluminosilicate gel composition, and forming the aluminosilicate aerogel by extracting fluid.

公开(公告)号：US20250059052A1

公开(公告)日：2025-02-20

申请号：US18935226

申请日：2024-11-01

Applicant: Aspen Aerogels, Inc.

Inventor： Owen Evans ,  George Gould ,  John Williams ,  David Mihalcik ,  Kathryn deKrafft ,  Wenting Dong

IPC: C01B33/158

Abstract: This disclosure relates generally to acrogel technology. The disclosure relates more particularly, in various embodiments, to improved methods for producing acrogels and improved acrogel composites having a low compression set.

公开(公告)号：US20250011562A1

公开(公告)日：2025-01-09

申请号：US18883579

申请日：2024-09-12

Applicant: Aspen Aerogels, Inc.

Inventor： Nicholas Leventis ,  Redouane Begag ,  Rushi Soni ,  Joshua Bartels ,  Hooman Yaghoobnejad Asl

IPC: C08J9/28 ,  C08G73/10 ,  C08J3/075 ,  C08K3/04

Abstract: The present disclosure is directed to methods of forming polyamic acid, polyamic acid metal salt, and polyimide gels under aqueous conditions, the methods utilizing water-soluble carbonate or bicarbonate salts. These gels may be converted to aerogels or xerogels, which may further be converted to carbon aerogels or xerogels. Such carbon aerogels or xerogels have the same physical properties as carbon aerogels or xerogels prepared from polyimide aerogels obtained according to conventional methods, i.e., organic solvent-based methods.