公开(公告)号：US4324937A

公开(公告)日：1982-04-13

申请号：US220546

申请日：1980-12-29

申请人： Bipin V. Vora

发明人： Bipin V. Vora

IPC分类号： C07C5/27 ,  C07C9/16 ,  C10L1/06 ,  C07C2/58

CPC分类号： C10L1/06 ,  C07C5/2791 ,  C07C9/16

摘要： A hydrocarbon conversion process for the production of motor fuel blending stocks from propane and butane is disclosed. Preferably a charge stream comprising a mixture of C.sub.3 -C.sub.4 saturated hydrocarbons is split into a C.sub.3 stream passed into a dehydrogenation zone and a C.sub.4 stream passed into an isostripper column. Normal butanes are removed from the isostripper and passed into an isomerization zone, with product isobutane being concentrated by fractionation in the isostripper. Isobutane and propylene from the dehydrogenation zone are then reacted in an alkylation zone which produces C.sub.5 -plus product hydrocarbons. The effluent of the alkylation zone enters the isostripper. The product stream and a propane-containing stream are withdrawn from the isostripper, with the propane-containing stream being passed into a second separation zone. Alternative butane fractionation systems are disclosed.

摘要翻译： 公开了一种用于从丙烷和丁烷生产汽油燃料混合原料的烃转化方法。 优选地，将包含C 3 -C 4饱和烃的混合物的电荷流分裂成进入脱氢区的C 3流，并且将C4流通入等分管柱。 将正丁烷从等离子体捕集器中取出并进入异构化区，产物异丁烷通过分馏在分离器中进行浓缩。 然后将脱氢区的异丁烷和丙烯在产生C5加产物烃的烷基化区中反应。 烷基化区的流出物进入等离子体。 将产物流和含丙烷的物流从等速吸管中取出，含丙烷的物流进入第二分离区。 公开了替代丁烷分馏系统。

公开(公告)号：US4293722A

公开(公告)日：1981-10-06

申请号：US121353

申请日：1980-02-14

申请人： Dennis J. Ward ,  Bipin V. Vora

发明人： Dennis J. Ward ,  Bipin V. Vora

IPC分类号： C07C11/02 ,  C07C11/107 ,  C10G49/22 ,  C10L1/06 ,  C07C2/08 ,  C07C5/32

CPC分类号： C10L1/06 ,  C07C11/02 ,  C07C11/107 ,  C10G2400/02 ,  Y02P20/582

摘要： A multi-step hydrocarbon conversion process for producing gasoline from propane is disclosed. Propane is passed into a dehydrogenation zone and the entire dehydrogenation zone effluent is then passed into a catalytic condensation zone wherein propylene is converted into C.sub.6 and C.sub.9 hydrocarbons. The condensation zone effluent, a stripper overhead stream and an absorber bottoms stream are commingled and then separated into vapor and liquid portions. The liquid is passed into the stripper, and the vapor portion is contacted with stripper bottoms liquid in an absorber. The absorber overhead stream is contacted with liquid propane in a second absorber to remove C.sub.6 hydrocarbons and is then recycled to the dehydrogenation zone. Depropanizing a portion of the stripper bottoms yields the liquid propane and a gasoline product.

摘要翻译： 公开了一种用于从丙烷生产汽油的多步烃转化方法。 丙烷通入脱氢区，然后将全部脱氢区流出物送入催化冷凝区，其中丙烯转化为C6和C9烃。 冷凝区流出物，汽提器顶部物流和吸收塔底物流混合，然后分离成蒸汽和液体部分。 将液体通入汽提器中，蒸气部分与吸收器中的汽提塔底部液体接触。 吸收塔顶流与第二吸收器中的液态丙烷接触以除去C6烃，然后再循环到脱氢区。 脱胶一部分汽提塔底部产生液体丙烷和汽油产品。

公开(公告)号：US4024200A

公开(公告)日：1977-05-17

申请号：US683354

申请日：1976-05-05

申请人： Bipin V. Vora

发明人： Bipin V. Vora

IPC分类号： B01J19/24 ,  C07C2/54 ,  C07C2/62 ,  C07C3/54

CPC分类号： B01J19/2425 ,  C07C2/54 ,  C07C2/62 ,  B01J2219/00081 ,  B01J2219/00159 ,  C07C2527/1206 ,  Y02P20/582 ,  Y10S585/90

摘要： An alkylatable reactant is alkylated with an olefin-acting reactant, utilizing a fluid HF catalyst in a countercurrent flow reaction chamber wherein reactants are flowing upward and the fluid catalyst is flowing downward. The fluid catalyst enters the reaction chamber at the top and is withdrawn at the bottom. Reaction chamber effluent passes into a settling chamber wherein it is separated into a catalyst phase and a hydrocarbon phase, the latter passing through a second reaction chamber in which it contacts a countercurrent flow of higher concentration fluid HF catalyst, and into a final settling chamber, wherein a hydrocarbon reaction product phase is separated from a catalyst phase and withdrawn. Also disclosed is a novel unitary alkylation vessel comprising, in combination, a countercurrent reaction chamber, a settling chamber, a second reaction chamber, and a final settling chamber.

摘要翻译： 在反向流动反应室中利用流体HF催化剂将烷基化反应物用烯烃作用反应物烷基化，其中反应物向上流动并且流体催化剂向下流动。 流体催化剂在顶部进入反应室，并在底部排出。 反应室流出物进入沉降室，其中分离成催化剂相和烃相，后者通过第二反应室，其中其接触高浓度流体HF催化剂的逆流，并进入最终沉降室， 其中将烃反应产物相与催化剂相分离并萃取。 还公开了一种新颖的单一烷基化容器，其组合包括逆流反应室，沉降室，第二反应室和最终沉降室。

公开(公告)号：US3985823A

公开(公告)日：1976-10-12

申请号：US643570

申请日：1975-12-22

申请人： Jay E. Sobel ,  Bipin V. Vora

发明人： Jay E. Sobel ,  Bipin V. Vora

IPC分类号： C07C2/62 ,  C07C2/86 ,  C07C5/27 ,  C07C9/16 ,  C07C3/54

CPC分类号： C07C9/16 ,  C07C2/62 ,  C07C2/861 ,  C07C5/2786 ,  C07C2527/1206

摘要： A process for producing hydrocarbon alkylate from an isoparaffin and an olefin-acting agent. The isoparaffin, the olefin and a first, relatively low strength hydrogen fluoride catalyst are contacted in an alkylation reaction to form a reaction mixture, the reaction mixture is settled to separate a first hydrocarbon phase from the low strength catalyst phase, the first hydrocarbon phase is admixed with a second, relatively higher strength hydrogen fluoride catalyst phase in an alkylation soaker, the effluent from the soaker is settled to separate a second hydrocarbon phase from the high strength catalyst phase, and the hydrocarbon alkylate is recovered from the second hydrocarbon phase.

摘要翻译： 从异链烷烃和烯烃作用剂制备烷基化烃的方法。 异烷烃，烯烃和第一相对低强度的氟化氢催化剂在烷基化反应中接触以形成反应混合物，将反应混合物沉淀以将第一烃相与低强度催化剂相分离，第一烃相为 与第二个相对较高强度的氟化氢催化剂相在烷基化浸泡剂中混合，来自沉淀器的流出物被沉降以将第二烃相与高强度催化剂相分离，并从第二烃相回收烃烷基化物。