摘要:
A process for removing carbonaceous deposits on surfaces of catalysts and plant parts by treating the deposits with a superheated stream of steam admixed at least temporarily with an oxygenous gas is provided, which involves, in each case monitoring the offgas CO2 content after condensation of the steam, at a temperature of at least 300° C.: (a) treating the carbonaceous deposits with superheated steam at a temperature of at least 300° C. until the CO2 content of the offgas has exceeded a maximum; (b) then, with further supply of superheated steam, commencing oxygen supply, the amount of oxygen supplied being adjusted such that the CO2 content in the offgas decreases further until it has fallen to a value of
摘要:
A process for the hydrolysis of polymers comprising vinylcarboxamide units by heating polymers comprising vinylcarboxamide units in an aqueous medium in the presence of acids or bases, wherein an aqueous solution or dispersion of a polymer comprising vinylcarboxamide units and an aqueous solution or a base or acid are fed continuously to a tubular reactor at elevated pressure, from 0.05 to less than one equivalent of a base or acid being used per vinylcarboxamide equivalent and the mixture being passed through the tubular reactor at a temperature of >100° C. to 250° C., depressurized and cooled.
摘要:
Cationic 2,2,6,6-tetraalkylpiperidinyl alkoxyamines of, for example, formula (1a) and (1b) are useful as polymerization initiators/regulators in a controlled stable free radical polymerization process to produce intercalated and/or exfoliated nanoparticles from natural or synthetic clays. Compositions comprising improved nanocomposites produced by this process are useful as, for example, coatings, sealants, caulks, adhesives and plastic additives wherein Q1 is a direct bond or a —CH2— group T1, T2, T3 and T4 are independently methyl or ethyl with the proviso that at least one is ethyl; T7 and T8 are hydrogen or methyl; T5 and T6 are hydrogen or T5 and T6 together are a group ═O, ═NOH, ═NO-T9 or T5 is hydrogen and T6 is —O-T9 or —NR9-T9 T9 is hydrogen, R9 or —C(O)—R9; R9 is hydrogen, C1-C18alkyl, C3-C18alkenyl, C3-C18alkynyl, phenyl or C7-C9phenylalkyl unsubstituted or substituted by hydroxy, halogen or C1-C4alkoxy; K1 and K2 are hydrogen, C1-C18alkyl, C5-C12cycloalkyl, phenyl or C7-C9phenylalkyl and K3 is a group containing selected amine containing salts.
摘要:
Embodiments relate to viscosifiers that are terminated polymers that have functional terminal groups. The polymers being pre-extended by polyepoxides and being reacted to give polymers that are terminated by other functional groups. The viscosifiers have a low content in educts or educt descendants that deteriorate the properties of compositions and considerably reduce or even exclude the formation of high-molecular addition products so that the products obtained have low viscosity and good storage stability.
摘要:
Viscosifiers, especially terminated polymers that have functional terminal groups, the polymers being pre-extended by polyols and being reacted to give polymers that are terminated by other functional groups, are produced. The viscosifiers have a low content in educts or educt descendants that deteriorate the properties of compositions. The formation of high-molecular addition products is considerably reduced or even excluded so that the products obtained have low viscosity and good storage stability. The epoxy-terminated polymer of formula (I) is especially preferred.
摘要:
The instant invention relates to a process for the preparation of star and block-copolymers, which are prepared by controlled free radical polymerization using epoxy-functionalized alkoxyamines and multifunctional compounds capable of reacting with the epoxy group.
摘要:
In a spray gun (1) for atomizing fluids, that can be actuated using a lever (15) mounted in a pivoting arrangement on a sleeve (11) which accommodates an atomizer nozzle (12) and in which the air flow can be generated by an air turbine (5) that is assigned to the spray gun (1), the air turbine (5) and its electric drive motor (4) are arranged substantially coaxially to the sleeve (11) on the opposite side of a handle (21) and the air flow is supplied from the air turbine (5) in a substantially straight line through the sleeve (11) of the atomizer nozzle (12). The air turbine (5) is provided with a muffler (6). Loud operating noise of the air turbine (5) does not have a disruptive effect and practically no flow noise is generated due to deflections of the air flow. The components of the spray gun (1) are arranged in such a way that no more than slight tilting torques are generated, permitting work over long periods without leading to fatigue.
摘要:
The present invention provides a process for preparing propargyl alcohol by converting an aqueous formaldehyde solution comprising acetylene over a catalyst comprising copper acetylide at an operating pressure of from 1 to 15 bar and from 70 to 120° C. without forming a continuous gas phase, in which the aqueous formaldehyde solution comprises an organic solvent for acetylene and the catalyst is arranged in a fluidized bed.
摘要:
A color photographic material which contains on a support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, together with customary non-light-sensitive layers, characterized in that at least one layer contains a compound of formula (I) or (II) wherein the R1-radicals and R2-radicals are preferably methyl; and wherein the compounds of formula (II) are preferably (III) R3 is a radical —CH(CH3)—X—D, wherein X is phenylene. D is a group (IV) or a group —C(O)—C1–C18alkyl or a group —O—CH2—CH(OH)—CH2—NR12R13, with R12 and R13 being C1–C18alkyl or together form a 4 to 8 membered ring as defined in claim 1, or D is a group —O—CH2—CH(OH)—CH2—N(R12)—CH2—CHOH—CH2—O—or —O—CH2—CH(OH)—CH2—W—CH2—CHOH—CH2—O— with W being a divalent amino group (—N(C1–C18alkyl)−), a polyamine residue, a polyethyleneimine residue or a polyoxyalkyleneamine residue; Z and Z′ are for example C1–C12alkyl, C3–C12alkenyl, C3–C12alkenyl, C5–C8cycloalkyl, or Z and Z′ together bivalent groups such as —CH2—CH2— or —CH2—C(R18)(R19)—CH(R20)—