Polymerisable Resin Film
    1.
    发明公开

    公开(公告)号:US20240318055A1

    公开(公告)日:2024-09-26

    申请号:US18580212

    申请日:2022-08-02

    申请人: Gurit (UK) Ltd.

    摘要: A resin film with at least 50 wt % of at least one polymerisable vinyl ester prepolymer having at least two carbon-carbon unsaturated functional groups and a curing system, the prepolymer in a concentration of at least 10 wt %, based on the weight of the polymerisable resin, and has the structure R1n-R2-R1′m, wherein R1 and R1′ are the same or different, n and m are each at least one and may be the same or different, and each of R1 and R1′ includes a carbon-carbon unsaturation at a free end thereof remote from R2, and includes a residue of an epoxy resin, and wherein R2 is a polyfunctional chain extending linker between R1 and R1′, and is derived from a polyfunctional carboxylic acid having the structure R-Fnx, where Fn is a carboxylic acid functional group, x is at least 2, and R comprises an organic moiety having aliphatic, araliphatic, cycloaliphatic, heterocyclic and/or aromatic groups, containing any type and/or combination of saturated, unsaturated and/or aromatic carbon bonds, and wherein R may be unsubstituted or substituted by functional groups and/or heteroatoms.

    ESTER PRE-EXTENDED EPOXY-TERMINATED VISCOSIFIERS AND METHOD FOR PRODUCING THE SAME
    4.
    发明申请
    ESTER PRE-EXTENDED EPOXY-TERMINATED VISCOSIFIERS AND METHOD FOR PRODUCING THE SAME 失效
    ESTER预扩展的环氧封端的粘合剂及其生产方法

    公开(公告)号:US20100048828A1

    公开(公告)日:2010-02-25

    申请号:US12448483

    申请日:2007-12-21

    摘要: Viscosifiers, especially terminated polymers that have functional terminal groups, the polymers being pre-extended by polyols and being reacted to give polymers that are terminated by other functional groups, are produced. The viscosifiers have a low content in educts or educt descendants that deteriorate the properties of compositions. The formation of high-molecular addition products is considerably reduced or even excluded so that the products obtained have low viscosity and good storage stability. The epoxy-terminated polymer of formula (I) is especially preferred.

    摘要翻译: 粘度计,特别是具有官能端基的封端聚合物,聚合物被多元醇预扩展并且被反应以产生被其它官能团封端的聚合物。 增粘剂在离子渗透剂或脱水后代中的含量低,会降低组合物的性能。 高分子加成产物的形成显着减少甚至排除,使得所得产品具有低粘度和良好的储存稳定性。 式(I)的环氧封端的聚合物是特别优选的。

    Epoxy resin pre-advanced with carboxyl-containing polyester and advanced
with bisphenol
    6.
    发明授权
    Epoxy resin pre-advanced with carboxyl-containing polyester and advanced with bisphenol 失效
    环氧树脂预先用含羧基的聚酯和先进的双酚

    公开(公告)号:US6103825A

    公开(公告)日:2000-08-15

    申请号:US70662

    申请日:1998-04-30

    摘要: Epoxy resins which are obtainable by a process in which, first of all(a) by reacting(A1) at least one substance selected from the substances of the formula (I) and of the formula (II): ##STR1## in which Alc is the radical of a diol which has been freed fromI ts hydroxyl groups and comprises 2 to 20 carbon atoms,Ac is the radical of a dicarboxylic acid which has been freed from its carboxyl groups and comprises 2 to 20 carbon atoms,[Ph] is the radical of a difunctional phenolic compound which has been freed from its phenolic hydroxyl groups and has 6 to 20 carbon atoms, andc is a number greater than 1 but not more than 2, with(A2) at least one liquid diglycidyl ether based on a first bisphenol compound in an amount chosen so that there are more than two equivalents of glycidyl groups of component (A2) for a total of one equivalent of carboxyl and phenolic hydroxyl groups of component (A1),a pre-advanced diglycidyl ether resin is formed in dispersion in the liquid diglycidyl ether of which there is at least one, and subsequently(b) the resin dispersion obtained in accordance with (a) is reacted with a phenol component comprising at least one bisphenol compound which is identical to or different from the first bisphenol compound, the amount of the phenol component being chosen so that in the mixture of the resin dispersion and the phenol component the glycidyl groups prior to the reaction are in a stoichiometric excess over the phenolic hydroxyl groups.

    摘要翻译: 环氧树脂可以通过以下方法获得:首先(a)通过(A1)选自式(I)和式(II)的物质中的至少一种物质:其中Alc是基团 的二醇,其已经脱离了羟基并且包含2至20个碳原子,Ac是已经脱离其羧基并且包含2至20个碳原子的二羧酸的基团,[Ph]是基团 的二官能酚类化合物,其已经脱离其酚羟基并且具有6至20个碳原子,c是大于1但不大于2的数,其中(A2)基于第一个(A2)的至少一种液体二缩水甘油醚 双酚化合物的量选择为使得组分(A2)的总共1当量的羧基和酚羟基具有多于2当量的缩水甘油基,组分(A1)的羧基和酚羟基的总数,预先的二缩水甘油醚树脂形成在 分散在液体中的二缩水甘油醚 h中至少有一个,随后(b)将根据(a)获得的树脂分散体与包含至少一种与第一双酚化合物相同或不同的双酚化合物的酚组分反应, 苯酚组分的选择使得在树脂分散体和酚组分的混合物中,反应前的缩水甘油基的化学计量过量超过酚羟基。

    Expoxide flexibilizers based on polylactone adducts
    10.
    发明授权
    Expoxide flexibilizers based on polylactone adducts 失效
    基于聚对苯二甲酸乙二醇酯的增塑剂

    公开(公告)号:US5132374A

    公开(公告)日:1992-07-21

    申请号:US676410

    申请日:1991-03-28

    CPC分类号: C08G59/12

    摘要: Adducts of the formula I ##STR1## are described in which R.sup.1 is an e-valent aliphatic radical after the removal of the functional groups, X is --O--or --NH--, R.sup.2 is a d+l-valent carbocyclic-aromatic radical, R.sup.3 is hydrogen or methyl, R.sup.4 is an aliphatic, aromatic, or araliphatic c+l-valent radical, Y is --O--, --S--or --NR.sup.5 --, R.sup.5 is hydrogen or ##STR2## b is an integer from 2 to 15, b is an integer from 1 to 25, c is 1, 2 or 3, d is 1, 2 or 3 and e is 2, 3 or 4.The adducts can be combined with latent curing agents and, if appropriate, other epoxy resins to give adhesives having good stability on storage and high flexibility.

    摘要翻译: 描述式I的加合物(I)其中R1是除去官能团之后的e价的脂族基团,X是-O - 或-NH-,R 2是d + 1 R 3是氢或甲基,R 4是脂族,芳族或芳脂族c + 1价基团,Y是-O-,-S-或-NR 5 - ,R 5是氢或者 b为2至15的整数,b为1至25的整数,c为1,2或3,d为1,2或3,e为2,3或4.加合物可与潜在固化 代理商和适当的情况下,其他环氧树脂,以提供具有良好的储存稳定性和高柔性的粘合剂。