公开(公告)号：US08545898B2

公开(公告)日：2013-10-01

申请号：US12527338

申请日：2008-02-15

申请人： Toshiaki Fukuda ,  Koji Abe ,  Takashi Shibata

发明人： Toshiaki Fukuda ,  Koji Abe ,  Takashi Shibata

IPC分类号： A01N59/08 ,  A61K33/14

CPC分类号： A61K9/0014 ,  A61K33/00 ,  A61K33/20 ,  A61K33/42 ,  A61K45/06 ,  A61K47/02 ,  A61K2300/00

摘要： A composition for a broad-spectrum antiviral agent with excellent preservation stability, which comprises a pure chlorine dioxide solution comprising a chlorine dioxide gas dissolved therein, a chlorite, and a pH adjuster.

摘要翻译： 一种具有优异保存稳定性的广谱抗病毒剂组合物，其包含溶解有二氧化氯气体的纯二氧化氯溶液，亚氯酸盐和pH调节剂。

公开(公告)号：US08530080B2

公开(公告)日：2013-09-10

申请号：US13618644

申请日：2012-09-14

申请人： Koji Abe ,  Takaaki Kuwata

发明人： Koji Abe ,  Takaaki Kuwata

IPC分类号： H01M6/14

CPC分类号： H01M10/0567 ,  H01M4/485 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0037

摘要： A nonaqueous electrolytic solution that provides a lithium secondary battery with excellent electrical capacity, cycling properties, storage properties and other battery characteristics and that maintains the battery characteristics for a long time; and a lithium secondary battery comprising it. A nonaqueous electrolytic solution comprising an electrolytic salt dissolved in a nonaqueous solvent, containing 0.1 to 10% by weight of an ethylene carbonate derivative represented by the general formula (I), and 0.01 to 10% by weight of (A) a triple bond-containing compound and/or (B) a pentafluorophenyloxy compound represented by the general formula (X), wherein formula (I) is: wherein R1 to R3 each independently represents a hydrogen atom, a halogen atom, an alkenyl group, an alkynyl group or an aryl group, provided that ethylene carbonate is excluded from the definition of the ethylene carbonate derivative; and wherein formula (X) is: wherein R15 represents an alkylcarbonyl group, an alkoxycarbonyl group, an aryloxycarbonyl group or an alkanesulfonyl group.

摘要翻译： 提供具有优异的电容，循环性能，储存性能和其他电池特性并且长时间保持电池特性的锂二次电池的非水电解液; 和包含该锂二次电池的锂二次电池。 包含溶解在非水溶剂中的电解质盐的非水电解液，含有0.1〜10重量％的由通式（I）表示的碳酸亚乙酯衍生物和0.01〜10重量％的（A）三键 - 含有化合物和/或（B）由通式（X）表示的五氟苯氧基化合物，其中式（I）为：其中R 1至R 3各自独立地表示氢原子，卤素原子，烯基，炔基或 芳基，条件是从碳酸亚乙酯衍生物的定义中排除碳酸亚乙酯; 并且其中式（X）为：其中R 15表示烷基羰基，烷氧基羰基，芳氧基羰基或链烷磺酰基。

公开(公告)号：US08404390B2

公开(公告)日：2013-03-26

申请号：US12596300

申请日：2008-04-15

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Yoshihiro Ushigoe ,  Manabu Takase ,  Kazuyuki Kawabe

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Yoshihiro Ushigoe ,  Manabu Takase ,  Kazuyuki Kawabe

IPC分类号： H01M6/16

CPC分类号： C07C317/08 ,  C07C317/18 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/4235 ,  Y02T10/7011

摘要： The present invention provides (1) a sulfone compounds having a propargyl group, (2) a nonaqueous electrolytic solution for lithium secondary batteries, which comprises an electrolyte salt dissolved in a nonaqueous solvent and contains a sulfone compound having a specific structure that has an SO2 group with a propargyl group or a vinyl group bonding thereto, in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution, and which can prevent gas generation and is excellent in battery characteristics such as cycle property and the like, and (3) a lithium secondary battery comprising a positive electrode, a negative electrode and a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, wherein the nonaqueous electrolytic solution contains a sulfone compound having a specific structure, in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution.

摘要翻译： 本发明提供（1）具有炔丙基的砜化合物，（2）锂二次电池用非水电解液，其包含溶解在非水溶剂中的电解质盐，并含有具有SO 2的特定结构的砜化合物 与非水电解液的重量比为0.01〜10重量％的炔丙基或与其结合的乙烯基，能够防止气体产生，并且电池特性如循环特性等优异， （3）一种锂二次电池，其包含正极，负极和溶解在非水溶剂中的电解质盐的非水电解液，其中所述非水电解液含有特定结构的砜化合物，其量为0.01 至10重量％的非水电解液。

公开(公告)号：US08394541B2

公开(公告)日：2013-03-12

申请号：US13164826

申请日：2011-06-21

申请人： Toshikazu Hamamoto ,  Akira Ueki ,  Koji Abe ,  Kazuhiro Miyoshi

发明人： Toshikazu Hamamoto ,  Akira Ueki ,  Koji Abe ,  Kazuhiro Miyoshi

IPC分类号： H01M6/16 ,  H01M4/58

CPC分类号： H01M10/0567 ,  H01M4/382 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0564 ,  H01M10/4235 ,  H01M10/44 ,  H01M2300/004 ,  H01M2300/0042

摘要： The sudden generation of heat being frequently caused in the case of the overcharge of a lithium secondary cell which have a positive electrode comprising a composite metal oxide of lithium and cobalt or a composite metal oxide of lithium and nickel, a negative electrode comprising metallic lithium, a lithium alloy or a material capable of occluding and releasing lithium, and a nonaqueous electrolyte solution comprising a nonaqueous solvent and an electrolyte dissolved therein can be efficiently prevented by the addition, to the nonaqueous electrolyte solution, of an organic compound which, when the lithium secondary cell is overcharged, decomposes into a decomposition product capable of dissolving out the cobalt or nickel contained in the positive electrode and depositing it ion the negative electrode (for example, a tert-alkylbenzene derivative).

摘要翻译： 在具有包含锂和钴的复合金属氧化物或锂或镍的复合金属氧化物的正极的锂二次电池的过充电的情况下，常常引起热的突然产生，包含金属锂的负极， 可以通过向非水电解液中添加有机化合物来有效地防止锂离子或能够吸留和释放锂的材料，以及非水溶剂和电解质溶解在其中的非水电解质溶液， 二次电池过充电，分解成能够溶解正极中所含的钴或镍的分解产物，并将其沉积在负极（例如，叔烷基苯衍生物）上。

公开(公告)号：US20120301797A1

公开(公告)日：2012-11-29

申请号：US13576182

申请日：2011-02-02

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

IPC分类号： H01M10/056 ,  C07C309/70 ,  C07C309/68 ,  C07C309/67

CPC分类号： H01M10/0567 ,  C07C309/67 ,  C07F9/113 ,  C07F9/327 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it.The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2  (I) (In the formula, X1 represents a group —C(═O)—, a group —C(═O)—C(═O)—, a group —S(═O)2—, a group —P(═O) (—R3)—, or a group —X2—S(═O)2O—. R1 represents an alkenyl group, a formyl group, an alkyl group, an acyl group, an arylcarbonyl, an alkanesulfonyl group, an alkynyloxysulfonyl group, an arylsulfonyl group, a dialkylphosphoryl group, an alkyl(alkoxy)phosphoryl group, or a dialkoxyphosphoryl group; R2 represents an alkynyl group or an alkynyloxy group; R3 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, or an aryloxy group; n indicates 0 or 1.

摘要翻译： 本发明提供一种能够提高高温充电保存后的低温高温循环性能和负载特性的优异的非水电解液，使用它的电化学元件和用于其的炔基化合物。 本发明的非水电解液在非水电解液中含有0.01〜10质量％的由通式（I）表示的至少一种炔基化合物。 R 1（O）n -X 1 -R 2（I）（式中，X1表示-C（= O） - 基，-C（= O）-C（= O） - 基，-S（ = O）2-，基团-P（= O）（-R 3） - 或基团-X 2 -S（= O）2 O-，R 1表示链烯基，甲酰基，烷基，酰基 基团，芳基羰基，烷磺酰基，炔氧基磺酰基，芳基磺酰基，二烷基磷酰基，烷基（烷氧基）磷酰基或二烷氧基磷酰基; R2表示炔基或炔氧基; R3表示烷基， 烯基，炔基，芳基，烷氧基，烯氧基，炔氧基或芳氧基; n表示0或1。

公开(公告)号：US08283508B2

公开(公告)日：2012-10-09

申请号：US12671858

申请日：2008-08-01

申请人： Koji Abe ,  Yoshihiro Ushigoe ,  Yuichi Kotou ,  Ken Ikuno ,  Takashi Hosomi ,  Toyoaki Ihara

发明人： Koji Abe ,  Yoshihiro Ushigoe ,  Yuichi Kotou ,  Ken Ikuno ,  Takashi Hosomi ,  Toyoaki Ihara

IPC分类号： C07C1/32

CPC分类号： B01J31/04 ,  B01J21/18 ,  B01J23/42 ,  B01J23/44 ,  B01J2231/64 ,  C07C1/322 ,  C07C2523/44 ,  C07C2531/04 ,  C07C15/02

摘要： The present invention is a method for producing an aromatic compound by substituting the sulfonic acid group in a sulfonic acid aromatic-ester with a hydrogen atom in the presence of a platinum group metal catalyst, wherein an alkali metal carboxylate and/or an ammonium formate are made to coexist in the system. According to the present invention, an aromatic compound where the sulfonic acid group in a sulfonic acid aromatic-ester is substituted with a hydrogen atom, can be produced efficiently with good operability without using metal magnesium.

摘要翻译： 本发明是通过在铂族金属催化剂的存在下用氢原子取代磺酸芳族酯中的磺酸基而制备芳族化合物的方法，其中碱金属羧酸盐和/或甲酸铵是 在系统中共存。 根据本发明，可以在不使用金属镁的情况下，以良好的可操作性有效地制备磺酸芳族酯中的磺酸基被氢原子取代的芳族化合物。

公开(公告)号：US08247147B2

公开(公告)日：2012-08-21

申请号：US11767640

申请日：2007-06-25

申请人： Koji Abe ,  Shinya Yachi ,  Satoshi Handa ,  Kazumi Yoshizaki ,  Emi Tosaka ,  Yasuhiro Hashimoto ,  Nobuhisa Abe ,  Yushi Mikuriya

发明人： Koji Abe ,  Shinya Yachi ,  Satoshi Handa ,  Kazumi Yoshizaki ,  Emi Tosaka ,  Yasuhiro Hashimoto ,  Nobuhisa Abe ,  Yushi Mikuriya

IPC分类号： G03G9/087

CPC分类号： G03G9/08797 ,  G03G9/0806 ,  G03G9/0821 ,  G03G9/0823 ,  G03G9/0827 ,  G03G9/08708 ,  G03G9/08711 ,  G03G9/08755 ,  G03G9/08793 ,  G03G9/08795

摘要： A toner including toner particles containing at least a binder resin and a colorant. The binder resin is a vinyl-based resin. The toner contains a THF insoluble matter in a quantity of 0.0 mass % or more to less than 16.0 mass %. The toner has a main peak in a molecular weight domain Dr1 ranging from 5,000 to 80,000 in measurement of THF soluble matter of the toner with a gel permeation chromatogram (GPC)-differential refractive index detector (RI), and the toner has a main peak in a molecular weight domain Dm1 ranging from 10,000 to 120,000 and at least one peak in a molecular weight domain Dm2 ranging from 300,000 to 7,000,000 in the GPC-RI measurement in measurement with a GPC-multi-angle laser light scattering detector (MALLS).

摘要翻译： 包含至少含有粘合剂树脂和着色剂的调色剂颗粒的调色剂。 粘合剂树脂是乙烯基类树脂。 调色剂含有0.0质量％以上至小于16.0质量％的THF不溶性物质。 调色剂在具有凝胶渗透色谱（GPC） - 差示折射率检测器（RI）的调色剂的THF可溶物质的测量中，在分子量范围Dr1中具有5,000至80,000的主峰，并且调色剂具有主峰 在使用GPC-多角度激光散射检测器（MALLS）测量的GPC-RI测量中，在10,000至120,000的分子量结构域Dm1和分子量域Dm2中至少一个峰范围为30万至700,000的峰。

公开(公告)号：US08192907B2

公开(公告)日：2012-06-05

申请号：US11767640

申请日：2007-06-25

申请人： Koji Abe ,  Shinya Yachi ,  Satoshi Handa ,  Kazumi Yoshizaki ,  Emi Tosaka ,  Yasuhiro Hashimoto ,  Nobuhisa Abe ,  Yushi Mikuriya

发明人： Koji Abe ,  Shinya Yachi ,  Satoshi Handa ,  Kazumi Yoshizaki ,  Emi Tosaka ,  Yasuhiro Hashimoto ,  Nobuhisa Abe ,  Yushi Mikuriya

IPC分类号： G03G9/087

摘要： A toner including toner particles containing at least a binder resin and a colorant. The binder resin is a vinyl-based resin. The toner contains a THF insoluble matter in a quantity of 0.0 mass % or more to less than 16.0 mass %. The toner has a main peak in a molecular weight domain Dr1 ranging from 5,000 to 80,000 in measurement of THF soluble matter of the toner with a gel permeation chromatogram (GPC)-differential refractive index detector (RI), and the toner has a main peak in a molecular weight domain Dm1 ranging from 10,000 to 120,000 and at least one peak in a molecular weight domain Dm2 ranging from 300,000 to 7,000,000 in the GPC-RI measurement in measurement with a GPC-multi-angle laser light scattering detector (MALLS).

公开(公告)号：US20120134939A1

公开(公告)日：2012-05-31

申请号：US13146418

申请日：2010-01-27

申请人： Hideto Ueda ,  Koji Abe ,  Akio Nasu

发明人： Hideto Ueda ,  Koji Abe ,  Akio Nasu

IPC分类号： A61K8/73 ,  A61Q17/04

CPC分类号： A61Q17/04 ,  A61K8/03 ,  A61K8/06 ,  A61K8/064 ,  A61K8/73 ,  A61K8/99 ,  A61K2800/882

摘要： To provide a low-viscosity water-in-oil emulsion sunscreen cosmetic composition which is extremely excellent in UV protective enhancing effect (as the protective boosting effect of the UV absorption capability thereof) over a broad UV radiation region and has superior feeling in use (smooth feeling, dry feeling, and non-sticky feeling, etc.). A water-in-oil emulsion sunscreen cosmetic composition comprising (a) from 0.01 to 10% by mass of a water-soluble polymer and (b) from 0.01 to 30% by mass of a UV absorbent, and having a viscosity of at most 10,000 mPa·s (as measured with a B-type viscometer at 30° C.), wherein the aqueous phase accounts for at most 45% by mass.

摘要翻译： 提供一种在广泛的紫外线辐射区域上具有非常优异的UV保护增强效果（作为其UV吸收能力的保护性增强效果）的低粘度油包水乳剂防晒化妆品组合物，并且具有优异的使用感（ 平滑的感觉，干燥的感觉和不粘的感觉等）。 一种油包水型乳化防晒化妆品组合物，其含有（a）0.01〜10质量％的水溶性聚合物和（b）0.01〜30质量％的紫外线吸收剂，粘度至多为 10,000mPa·s（用B型粘度计在30℃下测定），其中，水相为45质量％以下。

公开(公告)号：US08163427B2

公开(公告)日：2012-04-24

申请号：US10564852

申请日：2004-07-16

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC分类号： H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M4/661 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2300/0025 ,  H01M2300/0091

摘要： A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.

摘要翻译： 非水电解液有利地用于制备循环特性优异的锂二次电池。 在锂二次电池用非水电解液中，将电解质盐溶解在非水溶剂中。 非水电解液还含有碳酸亚乙烯酯化合物，其量为0.01〜10重量％。 ％，炔化合物的量为0.01〜10重量％。 ％。