公开(公告)号：US20060210934A1

公开(公告)日：2006-09-21

申请号：US11375240

申请日：2006-03-15

Applicant: Yasuhiro Yoshioka

Inventor： Yasuhiro Yoshioka

IPC: G03C1/00

CPC classification number: G03C1/49827 ,  G03C1/0051 ,  G03C1/49818 ,  G03C1/49863 ,  G03C7/3225 ,  G03C7/346 ,  G03C2001/03558 ,  G03C2200/36

Abstract: A black and white photothermographic material including, on at least one side of a support, an image forming layer including at least a photosensitive silver halide, a silver salt of a fatty acid, a reducing agent for silver ions, and a binder, wherein the black and white photothermographic material includes a compound represented by the following formula (I) as the reducing agent and a compound represented by the following formula (BC-1) as a coupler: A black and white photothermographic material which exhibits low fog, high image density, excellent image tone, and excellent raw stock storability is provided.

Abstract translation: 一种黑色和白色光热敏成像材料，在至少一个支撑体的一侧包括至少包含感光卤化银，脂肪酸银盐，银离子还原剂和粘合剂的图像形成层，其中， 黑色和白色光热敏成像材料包括作为还原剂的下式（I）表示的化合物和作为成色剂的下式（BC-1）表示的化合物：具有低雾，高图像的黑白色光热敏成像材料 提供密度，优异的图像色调和优异的原始储存性。

公开(公告)号：US20060204907A1

公开(公告)日：2006-09-14

申请号：US11367785

申请日：2006-03-06

Applicant: Yasuhiro Yoshioka

Inventor： Yasuhiro Yoshioka

IPC: G03C1/00

CPC classification number: G03C1/49827 ,  G03C1/49818 ,  G03C1/49845 ,  G03C7/3225 ,  G03C7/34 ,  G03C7/36 ,  G03C7/38

Abstract: A color photothermographic material having, on at least one side of a support, an image forming layer including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, and a coupler which reacts with an oxidation product of the reducing agent to form a dye, wherein the photosensitive silver halide has an average silver iodide content of 40 mol % or higher, and the color photothermographic material contains a compound represented by the following formula (I) as the reducing agent. A color photothermographic material which exhibits low fog and excellent storage stability is provided.

Abstract translation: 一种彩色光热敏成像材料，其在载体的至少一侧具有至少包含感光卤化银，非感光性有机银盐，银离子还原剂和与氧化反应的成色剂的图像形成层 还原剂的产物形成染料，其中感光卤化银的平均碘化银含量为40摩尔％以上，彩色光热敏成像材料含有作为还原剂的下式（I）表示的化合物。 提供了具有低雾度和优异的储存稳定性的彩色光热敏成像材料。

公开(公告)号：US20060078835A1

公开(公告)日：2006-04-13

申请号：US11269595

申请日：2005-11-09

Applicant: Yasuhiro Yoshioka ,  Katsutoshi Yamane ,  Yasuhiko Goto

Inventor： Yasuhiro Yoshioka ,  Katsutoshi Yamane ,  Yasuhiko Goto

IPC: G03C1/00

CPC classification number: G03C1/49827 ,  G03C1/49818 ,  G03C1/49845 ,  G03C1/49881 ,  G03C7/30541 ,  G03C2001/03558 ,  G03C2200/39 ,  G03C2200/52 ,  G03C2200/60

Abstract: A photothermographic material including, on at least one surface of a support, at least a photosensitive silver halide containing a silver iodide at 40 mol % or more, a non-photosensitive organic silver salt, and a reducing agent, wherein the photothermographic material contains two or more kinds of the reducing agent at the mixing ratio to satisfy at least one of a), b), c) and d): a) a difference between a sensitivity or b) a difference between a maximum density is 0.10 or less, when developed at 120° C. for 10 sec and a sensitivity when developed at 120° C. for 14 sec; c) a difference between a sensitivity or d) a difference between a maximum density is 0.10 or less, when developed at 117° C. for 12 sec and a sensitivity when developed at 123° C. for 12 sec. An image forming method using the photothermographic material is also provided.

Abstract translation: 一种光热成像材料，其在载体的至少一个表面上至少包含含有40摩尔％以上的碘化银的光敏卤化银，非光敏有机银盐和还原剂，其中光热敏成像材料包含两个 或更多种还原剂，以满足a），b），c）和d）中的至少一个：a）灵敏度之间的差异或b）最大密度之间的差为0.10以下， 当在120℃显影10秒时，在120℃显影14秒时的灵敏度; c）灵敏度之差或d）当在117℃显影12秒时，最大密度之间的差为0.10以下，当在123℃显影12秒时的灵敏度。 还提供了使用光热敏成像材料的成像方法。

公开(公告)号：US07008760B1

公开(公告)日：2006-03-07

申请号：US09573333

申请日：2000-05-18

Applicant: Hiroyuki Yoneyama ,  Yasuaki Deguchi ,  Yasuhiro Yoshioka ,  Hidekazu Sakai ,  Katsuyuki Takada ,  Yoshiro Ochiai ,  Shin Soejima ,  Kentaro Okazaki

Inventor： Hiroyuki Yoneyama ,  Yasuaki Deguchi ,  Yasuhiro Yoshioka ,  Hidekazu Sakai ,  Katsuyuki Takada ,  Yoshiro Ochiai ,  Shin Soejima ,  Kentaro Okazaki

IPC: G03C1/795 ,  G03C1/93 ,  G03C7/38 ,  G03C7/30 ,  G03C1/035

CPC classification number: G03C1/79 ,  G03C1/0051 ,  G03C1/30 ,  G03C1/32 ,  G03C1/7954 ,  G03C5/04 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/383 ,  G03C7/3835 ,  G03C7/407 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/7635 ,  G03C2200/01 ,  G03C2200/03 ,  G03C2200/36 ,  G03C2200/52 ,  Y10S430/164

Abstract: Disclosed is a silver halide color photographic light-sensitive material having at least three silver halide emulsion layers different in color sensitivity from each other on a reflective support, wherein said reflective support is one selected from the group consisting of the following (a), (b) and (c):(a) the reflective support is a water-resistant resin-coated support, and at least one layer of the water-resistant resin layers between the support and the silver halide emulsion layers is a biaxially oriented polyolefin layer having micropores, (b) the reflective support is a water-resistant resin-coated support, and at least one layer of the water-resistant resin layers between the support and the silver halide emulsion layers is a biaxially oriented polyolefin layer having micropores, and between the polyolefin layer and the silver halide emulsion layers, a polyolefin layer having no micropore is provided, and (c) the reflective support is one prepared by coating onto at least the side of the emulsion-coated surface of the support with a composition having a white pigment mixed and dispersed in a resin containing at least 50 wt % of a polyester synthesized by polycondensation of a dicarboxylic acid with a diol, and wherein the silver halide emulsions in the silver halide emulsion layers each comprise silver halide emulsion grains with a silver chloride content of 95 mol % or more. Further, a method of forming a color image by the use of this silver halide color photographic light-sensitive material is also disclosed.

Abstract translation: 公开了一种卤化银彩色照相感光材料，其在反射性支持体上具有彼此颜色灵敏度不同的至少三种卤化银乳剂层，其中所述反射性支持体选自下列（a），（ b）和（c）：（a）反射性载体是防水树脂涂覆的载体，载体和卤化银乳剂层之间的至少一层耐水树脂层是双轴取向聚烯烃层 具有微孔，（b）反射性支持体是耐水性树脂涂布载体，载体和卤化银乳剂层之间的至少一层耐水性树脂层是具有微孔的双轴取向聚烯烃层， 在聚烯烃层和卤化银乳剂层之间提供没有微孔的聚烯烃层，（c）反射载体是通过将至少 将具有混合并分散在含有至少50重量％的通过二羧酸与二醇的缩聚合成的聚酯的树脂的树脂中的白色颜料的组合物的所述载体的乳液涂覆表面的一侧，并且其中所述卤化银乳剂在 卤化银乳剂层各自包含卤化银乳剂颗粒，氯化银含量为95摩尔％以上。 此外，还公开了通过使用该卤化银彩色照相感光材料形成彩色图像的方法。

公开(公告)号：US20050214700A1

公开(公告)日：2005-09-29

申请号：US11072513

申请日：2005-03-07

Applicant: Seiichi Yamamoto ,  Masahiko Taniguchi ,  Yasuhiro Yoshioka ,  Takanori Hioki ,  Hideo Hanawa

Inventor： Seiichi Yamamoto ,  Masahiko Taniguchi ,  Yasuhiro Yoshioka ,  Takanori Hioki ,  Hideo Hanawa

IPC: G03C1/498 ,  G03C1/83 ,  G03C1/00

CPC classification number: G03C1/833 ,  G03C1/49854

Abstract: The present invention provides a silver halide photosensitive material and a photothermographic material having, on at least one side of a support, at least a photosensitive silver halide, a non-photosensitive organic silver salt, and a reducing agent for the organic silver salt, wherein the silver halide photosensitive material and the photothermographic material contain a phthalocyanine compound represented by the following formula (PC-1): wherein, M represents a hydrogen atom or a metal atom; R1, R4, R5, R8, R9, R12, R13, and R16 each independently represent a hydrogen atom or a substituent; at least one of R1, R4, R5, R8, R9, R12, R13, and R16 represents an electron-attracting group; and R2, R3, R6, R7, R10, R11, R14, and R15 each independently represent a hydrogen atom or a substituent.

Abstract translation: 本发明提供一种卤化银感光材料和光热敏成像材料，其至少在载体的一侧至少含有感光卤化银，非感光性有机银盐和有机银盐的还原剂，其中 卤化银感光材料和光热敏成像材料含有由下式（PC-1）表示的酞菁化合物：其中，M表示氢原子或金属原子; R 1，R 4，R 5，R 8，R 9， R 12，R 13和R 16各自独立地表示氢原子或取代基; R 1，R 4，R 5，R 8，R 9，R 9， R 12，R 12，R 16和R 16表示吸电子基团; 和R 2，R 3，R 6，R 7，R 10， R 11，R 14和R 15各自独立地表示氢原子或取代基。

公开(公告)号：US20050202355A1

公开(公告)日：2005-09-15

申请号：US11071436

申请日：2005-03-04

Applicant: Yasuhiro Yoshioka

Inventor： Yasuhiro Yoshioka

IPC: G03C1/498 ,  G03C1/00

CPC classification number: G03C1/46 ,  G03C1/49827 ,  G03C2001/0055 ,  G03C2001/03558 ,  G03C2001/7425

Abstract: A photothermographic material, which includes: a support; and image forming layers containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, a polyhalogen compound, and a binder, on the support, wherein the number of the image forming layers provided is at least 2, at least one layer of the image forming layers contains a reducing agent represented by the following formula (I), and at least one layer of the other image forming layers contains a reducing agent represented by the following formula (II):

Abstract translation: 光热成像材料，其包括：支撑体; 以及在载体上含有感光卤化银，非感光性有机银盐，还原剂，多卤素化合物和粘合剂的图像形成层，其中提供的图像形成层的数量至少为2，至少 一层图像形成层含有由下式（I）表示的还原剂，并且至少一层其它图像形成层含有由下式（II）表示的还原剂：

公开(公告)号：US20050106515A1

公开(公告)日：2005-05-19

申请号：US10939855

申请日：2004-09-14

Applicant: Yasuhiro Yoshioka

Inventor： Yasuhiro Yoshioka

IPC: G03C1/498 ,  G03C1/76 ,  G03C5/16

CPC classification number: G03C1/49845 ,  G03C1/49809 ,  G03C1/49818 ,  G03C1/49881 ,  G03C2007/3025

Abstract: The present invention provides a photothermographic material including at least a photosensitive silver halide, a non-photosensitive silver-supplying compound, a reducing agent and a binder on at least one surface of a support. The photothermographic material further includes at least one kind of halogen releasing compound having a water-solubilizing group and at least one kind of halogen releasing compound having no water-solubilizing group, and a gradation of a characteristic curve is 2.5 to 4.0. The photothermographic material of the invention is excellent in storability, and particularly excellent in storability of high quality images used for image recording for medical diagnosis.

Abstract translation: 本发明提供一种在支撑体的至少一个表面上至少包含光敏卤化银，非感光性银供给化合物，还原剂和粘合剂的光热敏成像材料。 光热敏成像材料还包括至少一种具有水溶性基团的卤素释放化合物和至少一种不具有水溶性基团的卤素释放化合物，特性曲线的等级为2.5至4.0。 本发明的光热敏成像材料的保存性优异，对于用于医疗诊断的图像记录用的高质量图像的保存性特别优异。

公开(公告)号：US06762016B2

公开(公告)日：2004-07-13

申请号：US09960328

申请日：2001-09-24

Applicant: Itsuo Fujiwara ,  Yoshihisa Tsukada ,  Yasuhiro Yoshioka ,  Hajime Nakagawa

Inventor： Itsuo Fujiwara ,  Yoshihisa Tsukada ,  Yasuhiro Yoshioka ,  Hajime Nakagawa

IPC: G03C1498

CPC classification number: G03C1/49845

Abstract: A photothermographic material is described, which comprises a support having provided on at least one side thereof a photosensitive silver halide, a photo-insensitive organic silver salt, a reducing agent for silver ion and a binder, wherein at least one layer constituting the photothermographic material comprises an oxazoline compound, by which sufficiently high image density is developed within practically feasible reaction time and temperature, and sufficiently suppressed background coloration is exhibited when stored for a prolonged period after development processing.

Abstract translation: 描述了一种光热成像材料，其包括在至少一侧上提供感光卤化银，不光敏有机银盐，银离子还原剂和粘合剂的载体，其中至少一层构成光热照相材料 包括恶唑啉化合物，其在实际可行的反应时间和温度下产生足够高的图像浓度，并且在显影处理后长时间储存​​时，表现出充分抑制的背景着色。

公开(公告)号：US06696237B1

公开(公告)日：2004-02-24

申请号：US09695864

申请日：2000-10-26

Applicant: Yasuhiro Yoshioka ,  Makoto Suzuki

Inventor： Yasuhiro Yoshioka ,  Makoto Suzuki

IPC: G03C1498

CPC classification number: G03C1/49827 ,  G03C1/49863

Abstract: Disclosed is a photothermographic material comprising, on one side of a support, a photosensitive silver halide, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions and a binder, which is characterized by containing one or more phenol compounds as the reducing agent and one or more compounds satisfying at least one of the following requirements A and B in combination: A: the hydrogen bond formation rate constant Kf is 20-4000, B: the chemical structure is represented by the following formula (II), (III), (IV) or (V) (R21 and others represent an alkyl group etc.), or has a phosphoryl group. According to the present invention, there is provided a photothermographicmaterial that can provide sufficient image density at practical reaction temperatures (specifically 100-140° C.) with practical reaction times (specifically 1-30 seconds), and can sufficiently suppress coloration of blank portions during storage in the dark after development.

Abstract translation: 公开了一种光热敏成像材料，其在载体的一面上包含感光卤化银，有机酸的非感光银盐，银离子还原剂和粘合剂，其特征在于含有一种或多种酚化合物 作为还原剂和一种或多种满足以下要求A和B中的至少一种组合的化合物：A：氢键形成速率常数Kf为20-4000，B：化学结构由下式（II ），（III），（IV）或（V）（R 21等）代表烷基等），或具有磷酰基。 根据本发明，提供一种能够在实际的反应时间（具体为1-30秒）的实际反应温度（特别是100-140℃）下提供足够的图像密度的光热敏成像材料，并且可以充分抑制毛坯部分的着色 在黑暗中储存后开发。

公开(公告)号：US06495313B2

公开(公告)日：2002-12-17

申请号：US09110271

申请日：1998-07-06

Applicant: Yasuhiro Yoshioka ,  Shin Soejima ,  Osamu Takahashi ,  Naoki Saito ,  Hisashi Mikoshiba ,  Masakazu Morigaki

Inventor： Yasuhiro Yoshioka ,  Shin Soejima ,  Osamu Takahashi ,  Naoki Saito ,  Hisashi Mikoshiba ,  Masakazu Morigaki

IPC: G03C730

CPC classification number: G03C7/301 ,  G03C7/3029 ,  G03C7/39252 ,  G03C2200/35

Abstract: A silver halide color photographic light-sensitive material comprising a support having provided thereon: at least one yellow-color-forming light-sensitive silver halide emulsion layer; at least one magenta-color-forming light-sensitive silver halide emulsion layer; at least one cyan-color-forming light-sensitive silver halide emulsion layer; and at least one light-insensitive non-color-forming hydrophilic colloid layer, wherein at least one layer of said at least one cyan-color-forming light-sensitive silver halide emulsion layer contains at least one cyan-dye-forming coupler having a pKa of not more than 8.7, and wherein said at least one light-insensitive non-color-forming hydrophilic colloid layer contains at least one compound represented by the following formula (I): wherein R1, R2, R3 and R4, which may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group; and R5 represents an aryl group; provided that the total number of carbon atoms included in R1, R2, R3, R4 and R5 is not less than 14.

Abstract translation: 一种卤化银彩色照相感光材料，包括其上提供的载体：至少一种黄色形成感光卤化银乳剂层; 至少一种品红色形成感光卤化银乳剂层; 至少一种青色成色感光卤化银乳剂层; 和至少一种不透光的不着色的亲水胶体层，其中至少一层所述至少一种青色成色感光卤化银乳剂层含有至少一种形成青色染料的成色剂，其具有 pKa不大于8.7，并且其中所述至少一种不透光的非成色性亲水胶体层含有至少一种由下式（I）表示的化合物：其中R1，R2，R3和R4可以是 相同或不同，各自表示氢原子，烷基或芳基; R5代表芳基; 条件是包括在R1，R2，R3，R4和R5中的碳原子总数不小于14。