Coating compositions curable by radiation and their use for preparing
coated substrates
    121.
    发明授权
    Coating compositions curable by radiation and their use for preparing coated substrates 失效
    通过辐射固化的涂料组合物及其用于制备涂布的基材

    公开(公告)号:US5744248A

    公开(公告)日:1998-04-28

    申请号:US789047

    申请日:1997-01-28

    摘要: The present invention relates to coating compositions, which are curable by radiation and contain I) 0 to 95 parts by weight of at least one binder curable by radiation and containing maleate, fumarate and/or acryloyl groups other than those of component II), II) 5 to 100 parts by weight of a mixture of A) 20 to 80 parts by weight of at least one polyester resin prepared from fatty acids, provided that at least 20 wt. % of component A) is a fatty acid having a number average molecular weight of 112 to 400 and B) 20 to 80 parts by weight of compounds containing (meth)acryloyl groups, having a viscosity at 23.degree. C. of 10 to 1,000 mPa.s and having a number average molecular weight of 170 to 1,000, wherein the sum of the parts by weight of components I) and II) adds up to 100, based on the weight of components I) and II), and the sum of the parts by weight of components A) and B) adds up to 100, based on the weight of components A) and B).

    摘要翻译: 本发明涉及涂料组合物,其可通过辐射固化并含有I)0至95重量份的至少一种可通过辐射固化并可含有除组分II),II之外的马来酸酯,富马酸酯和/或丙烯酰基的粘合剂 )5至100重量份的A)20至80重量份的由脂肪酸制备的至少一种聚酯树脂的混合物,条件是至少20重量份 组分A)的%是数均分子量为112〜400的脂肪酸,B)20〜80重量份含有(甲基)丙烯酰基的化合物,在23℃下的粘度为10〜1000mPa 并且其数均分子量为170至1,000,其中基于组分I)和II)的重量,组分I)和II)的重量份的总和相加至100,并且 组分A)和B)的重量份数基于组分A)和B)的重量加起来高达100。

    Continuous preparation of polymers
    122.
    发明授权
    Continuous preparation of polymers 失效
    连续制备聚合物

    公开(公告)号:US5739219A

    公开(公告)日:1998-04-14

    申请号:US673966

    申请日:1996-07-01

    摘要: In a process and an apparatus for the continuous preparation of polymers from reaction components, in particular of copolymers of styrene and acrylonitrile, by bulk or solution polymerization, the reaction components are passed through a recycle reactor which has at least one tube bundle reactor whose tubes are in thermal contact with a liquid heat-transfer medium and which is connected to at least one static mixing element.

    摘要翻译: 在通过本体或溶液聚合从反应组分,特别是苯乙烯和丙烯腈的共聚物中连续制备聚合物的方法和装置中,将反应组分通过具有至少一个管束反应器的再循环反应器,其管 与液体传热介质热接触并且连接到至少一个静态混合元件。

    Molding composition having a matt surface
    125.
    发明授权
    Molding composition having a matt surface 失效
    具有无光泽表面的成型组合物

    公开(公告)号:US5475053A

    公开(公告)日:1995-12-12

    申请号:US259165

    申请日:1994-06-13

    摘要: A molding composition based on an impact-modified thermoplastic A selected from ABS, ASA, impact-resistant polystyrene (HIPS) impact resistant polymethyl methacrylate, impact resistant PVC, polycarbonate, polyester carbonate, polyester, polyamide, polyphenylene ether, polyether ketone, polyether sulfone, polysulfone, polyoxyalkylene, polyarylene sulfide and also mixtures thereof containing a matting agent B composed of 30 to 80% by weight of an elastomeric grafting base B1 of 75 to 99.8% by weight of an alkyl acrylate having 1 to 8 carbon atoms in the alkyl radical (B11), 0.1 to 5% by weight of a polyfunctional, crosslinking monomer (B12) and 0.1 to 20% by weight of a monomer containing one or more acidic groups, or 49.9 to 99.9% by weight of one or more dienes (B111), up to 50% by weight of a further ethylenically unsaturated monomer (B112) and 0.1 to 20% by weight of a monomer containing one or more acidic groups (B113), and 20 to 70% by weight of a graft sheath B2 composed of 40 to 99.9% by weight of an aromatic vinyl monomer (B21), up to 49.9% by weight of a polar, copolymerizable, ethylenically unsaturated monomer (B22) and 0.1 to 20% by weight of a monomer containing one or more basic groups (B23), and also a molding composition whose constituents B13 and B113 and B23 are interchanged.

    摘要翻译: 基于抗冲击改性热塑性塑料A的成型组合物,其选自ABS,ASA,耐冲击聚苯乙烯(HIPS)耐冲击聚甲基丙烯酸甲酯,耐冲击PVC,聚碳酸酯,聚酯碳酸酯,聚酯,聚酰胺,聚苯醚,聚醚酮,聚醚砜 ,聚砜,聚氧化烯,聚芳硫醚以及它们的混合物,其含有消光剂B,其由30至80重量%的弹性体接枝基料B1为75至99.8重量%的烷基中具有1至8个碳原子的丙烯酸烷基酯 (B11),0.1〜5重量%的多官能交联单体(B12)和0.1〜20重量%的含有一个或多个酸性基团的单体,或49.9-99.9重量%的一种或多种二烯( B111),至多50重量%的另外的烯属不饱和单体(B112)和0.1〜20重量%的含有一个或多个酸性基团(B113)的单体和20〜70重量%的接枝鞘B2 由40组成 99.9重量%的芳族乙烯基单体(B21),最多49.9重量%的极性,可共聚的烯属不饱和单体(B22)和0.1-20重量%的含有一个或多个碱性基团(B23)的单体, ,以及其组分B13和B113和B23互换的成型组合物。

    ATM signal processors
    127.
    发明授权
    ATM signal processors 失效
    ATM信号处理器

    公开(公告)号:US5404354A

    公开(公告)日:1995-04-04

    申请号:US118224

    申请日:1993-09-09

    IPC分类号: H04L12/56 H04Q11/04 H04J3/24

    摘要: An ATM signal processor system for processing ATM data cells which in combination define a data package wherein the last cell of a package is characterized by an identifying code. The cells of different data packages are multiplexed to provide a serial data stream. A server and a buffer store via which the server is fed with the serial data stream are provided. The buffer store has a threshold capacity beyond which cells are discarded. A discarded cell identifier/rejecter serves to identify and store the identity of a data package with which a discarded cell is associated so as to be set thereafter to reject subsequently received cells with the same data package identity until being reset upon receipt of the last cell of the package as indicated by its characteristic identifying code.

    摘要翻译: 一种用于处理ATM数据单元的ATM信号处理器系统,其组合地定义数据包,其中包的最后一个单元的特征在于识别码。 不同数据包的单元被复用以提供串行数据流。 提供服务器和通过其提供串行数据流的服务器的缓冲存储器。 缓冲存储器具有超过其阈值容量的单元格被丢弃。 丢弃的小区标识符/拒绝用户用于识别和存储与被丢弃的小区相关联的数据包的身份,以便随后设置以拒绝具有相同数据包标识的随后接收的小区,直到在接收到最后一个小区时被重置 的包装,如其特征识别代码所示。

    Multi-ply textile fabric especially for protection suits and the like
    128.
    发明授权
    Multi-ply textile fabric especially for protection suits and the like 失效
    多层纺织面料,特别适用于防护服等

    公开(公告)号:US5399418A

    公开(公告)日:1995-03-21

    申请号:US156000

    申请日:1993-11-22

    IPC分类号: B64G6/00 D03D11/00 B32B7/02

    摘要: A multi-ply three-dimensionally bonded textile fabric is provided, to be used especially in making protective space suits, protective space shielding and other protective garments or shields. The fabric is a three-dimensionally woven, knitted, netted, braided or otherwise interlocked structure of threads including organic fibers such as aramid, polyethylene and/or polytetrafluoroethylene fibers and preferably also metallic fibers such as copper, aluminum and/or stainless steel fibers. These fibers are chosen to provide protection against adverse thermal, chemical, electrical and mechanical environmental effects that may be hazardous to an astronaut, for example. The fibers are arranged substantially in respective plies, and each ply is bonded or interlocked only to respective adjacent plies over substantially the entire ply area to provide a flexible multi-ply fabric. The threads are arranged to provide a gradient or variation in characteristics or properties from an outer surface to an inner surface. For example, different types, numbers or densities of threads, or different fabric densities may be used in different plies to achieve a gradient. Such a gradient allows a single, three-dimensionally bonded multi-ply fabric to provide several different protective properties. An outside surface coating of silicone or polymers such as polytetrafluroethylene or ethylene-tetrafluoroethylene may be applied on an outer surface of the fabric to further improve its protective properties.

    摘要翻译: 提供多层三维粘合纺织品,特别用于制作保护性衣服,保护性空间屏蔽和其他防护服或防护罩。 该织物是三维织造的,针织的,网状的,编织的或其它互锁的螺纹结构,包括有机纤维如芳族聚酰胺,聚乙烯和/或聚四氟乙烯纤维,并且优选还包括金属纤维如铜,铝和/或不锈钢纤维。 这些纤维被选择以提供防止例如可能对宇航员有害的不利的热,化学,电学和机械环境影响。 纤维基本上布置在相应的层中,并且每个帘布层仅在基本上整个帘布层区域上结合或互锁到相应的相邻帘布层以提供柔性多层织物。 螺纹被布置成提供从外表面到内表面的特性或性质的梯度或变化。 例如,螺纹的不同类型,数量或密度或不同的织物密度可以用于不同层中以实现梯度。 这种梯度允许单个三维粘合的多层织物提供几种不同的保护性能。 硅树脂或聚四氟乙烯或乙烯 - 四氟乙烯等聚合物的外表面涂层可以施加到织物的外表面上,以进一步提高其保护性能。

    Polyurethanes containing acryloyl groups, a process for their
preparation and their use as binders for coating compositions
    129.
    发明授权
    Polyurethanes containing acryloyl groups, a process for their preparation and their use as binders for coating compositions 失效
    含有丙烯酰基的聚氨酯,其制备方法及其作为涂料组合物的粘合剂的用途

    公开(公告)号:US5300615A

    公开(公告)日:1994-04-05

    申请号:US123630

    申请日:1993-09-20

    摘要: The present invention relates to polyurethanes which contain acryloyl groups, have a viscosity at 23.degree. C. of 800 to 100,000 mPa.s, and are prepared by reacting at an NCO/OH equivalent ratio of 0.7:1 to 1:1,I) an organic isocyanate component containinga) 20 to 50 mole % of one or more organic diisocyanates, other than hexamethylene diisocyanate, which have aliphatically and/or cycloaliphatically bound isocyanate groups and a molecular weight of less than 300 andb) 50 to 80 mole % of hexamethylene diisocyanate withII) a hydroxyl component containingc) 43 to 93 hydroxyl equivalent % of an alcohol component which has an average hydroxyl functionality of 0.8 to 1.5 and contains one or more alcohols having acryloyl groups and a molecular weight of 116 to 1000, provided that at least 50 mole % of component c) is made up of ether group-containing esterification products of acrylic acid with ether group-containing alcohols which are at least trihydric, wherein the esterification products have an average molecular weight of 300 to 1000 and an average hydroxyl functionality of 0.8 to 1.5,d) 7 to 50 hydroxyl equivalent % of one or more monohydric or dihydric branched alcohols having a molecular weight of 130 to 300 ande) 0 to 50 hydroxyl equivalent % of one or more monohydric or polyhydric alcohols having a molecular weight of less than 130.The present invention also relates to a method of preparing these polyurethanes and to their use as binders for coating compositions, particularly for those which can be hardened by high-energy radiation.

    摘要翻译: 本发明涉及包含丙烯酰基的聚氨酯,其在23℃下的粘度为800至100,000mPa.s,并且通过以0.7:1至1:1的NCO / OH当量比反应制备,I) 有机异氰酸酯组分,其含有20-50摩尔%的一种或多种除六亚甲基二异氰酸酯以外的有机二异氰酸酯,它们具有脂族和/或环烯键合的异氰酸酯基,分子量小于300,b)50-80摩尔% 的六亚甲基二异氰酸酯与II)含羟基的羟基组分c)43至93羟基当量%的醇组分的平均羟基官能度为0.8至1.5,并含有一种或多种具有丙烯酰基的醇和分子量为116至1000的醇, 条件是至少50摩尔%的组分c)由丙烯酸与至少三元的含醚基的醇的含醚基的酯化产物组成,其中酯化产物 的平均分子量为300〜1000,平均羟基官能度为0.8〜1.5,d)分子量为130〜300的一种或多种一元或二元支链醇的7〜50羟基当量%,e)0〜 一种或多种分子量小于130的一元醇或多元醇的羟基当量的50%羟基当量%。本发明还涉及一种制备这些聚氨酯的方法及其作为涂料组合物的粘合剂的用途,特别是可硬化的那些 通过高能辐射。

    Aliphatic polyurethanes containing acryloyl groups and a process for
their preparation
    130.
    发明授权
    Aliphatic polyurethanes containing acryloyl groups and a process for their preparation 失效
    含有丙烯酸酯的聚氨酯和其制备方法

    公开(公告)号:US5128432A

    公开(公告)日:1992-07-07

    申请号:US749235

    申请日:1991-08-23

    摘要: The present invention relates to aliphatic polyurethanes which contain acryloyl groups and are based on the reaction product (at an NCO/OH equivalent ratio of 0.5:1 to 1:1) ofa) 1.0 mole of a diisocyanate component containing at least 50 equivalent percent, based on NCO equivalents, of hexamethylene diisocyanate withb) 0.5 to 0.85 moles of at least one monohydric alcohol having a molecular weight of 116 to 144 and containing acryloyl groups.c) 0.15 to 0.5 moles of a monohydric alcohol having a molecular weight of 154 to 2000 and containing ester groups or a mixture of alcohols having an average molecular weight of 154 to 2000 and an average hydroxyl functionality of 0.8 to 1.5 and containing ester groups andd) 0.3 to 0.5 moles of at least one polyhydric alcohol having a molecular weight of 62 to 2000.The present invention also relates to a process for the preparation of these polyurethanes.

    摘要翻译: 本发明涉及含有丙烯酰基并基于反应产物(以NCO / OH当量比为0.5:1至1:1)的a)1.0摩尔含至少50当量%的二异氰酸酯组分的脂族聚氨酯 基于NCO当量,六亚甲基二异氰酸酯与b)0.5至0.85摩尔的至少一种分子量为116至144的一元醇并含有丙烯酰基。 c)0.15至0.5摩尔分子量为154至2000的一元醇,并且含有酯基或平均分子量为154至2000的醇和0.8至1.5的平均羟基官能度的混合物,并且含有酯基和 d)0.3至0.5摩尔的至少一种分子量为62至2000的多元醇。本发明还涉及制备这些聚氨酯的方法。