摘要:
Provided are a papermaking device having an excellent strength in which the unevenness in strength between its parts is suppressed, and a method for producing the papermaking device. Also provided is a papermaking device for use in papermaking machine, the papermaking device comprising at least one resin layer comprising a polyurethane resin, wherein the polyurethane resin comprises as a component a polyether polycarbonate diol comprising one or more unit(s) A expressed by the following formula (1).
摘要:
A papermaking device may have excellent strength and suppressed unevenness in strength between its parts. Such a papermaking device may be used in papermaking machine and may include at least one resin layer comprising polyurethane resin. The polyurethane resin may be obtained by reacting a urethane prepolymer having an isocyanate group with a curing agent having an active hydrogen group. The urethane prepolymer may be obtained by reacting a polyisocyanate compound including 2,4-tolylene-diisocyanate and/or 2,6-tolylene-diisocyanate with a polyol compound including one or more polyether polycarbonate diol(s).
摘要:
This invention relates to a composition for a preparation of polyurethane dispersion, comprising bio-based polyol as shown in structure (I) and polyhydroxy fatty acid compound as shown in structure (II): wherein, R represents a polyhydric alcohol unit that is selected from aliphatic polyhydric alcohol, alicyclic polyhydric alcohol, cyclic polyhydric alcohol, aromatic polyhydric alcohol, or optionally, cyclic polyhydroxyl having heteroatom; R\ represents a hydrocarbon unit obtained from a molecular chain of unsaturated fatty acid having 14-24 carbon atoms and having from 1-6 pairs of vicinal diol group per one molecular chain of such unsaturated fatty acid; n represents an integer from 2 to 8 of an ester group obtained from a reaction of polyhydric alcohol and unsaturated fatty acid; wherein said composition is prepared from a process comprising the steps of: i. mixing fatty acid comprising unsaturated fatty acid and polyhydric alcohol at a ratio of 1 mole equivalent or more of carboxylic group from unsaturated fatty acid per a hydroxy group from polyhydric alcohol; ii. adding organic acid and peroxide compound into the mixture from step i.; iii. adding nucleophilic substance into the mixture from step ii. under acidic condition.
摘要:
Coatings comprising an uncured branched polyester-urethane resin prepared by free radical polymerization of an unsaturated polyester prepolymer having a polyol segment, an unsaturated polycarboxylic acid and/or an anhydride and/or ester thereof, and a urethane segment, wherein the polymerization occurs primarily by reaction of the unsaturation are disclosed.
摘要:
The present invention discloses a thermoplastic polyurethane comprising substantially no plasticizers and having a Shore A hardness of 60 or less, which is prepared by a one-step polymerization of i) linear polyol, ii) organic diisocyanate and iii) glycol chain extender mainly comprising ethylene glycol and/or 1,3-propanediol; wherein the linear polyol (i) has a number average molecular weight within the range of from 1.5×103 g/mol to 5.0×103 g/mol. The thermoplastic polyurethane of the present invention can be easily produced by conventional production methods, and the thermoplastic polyurethane thus produced can be molded to articles in practicable processing cycles. Moreover, the thermoplastic polyurethane articles have low shrinkage, have good low-temperature properties and good mechanical properties, and do not harden substantially at low temperature.
摘要翻译:本发明公开了一种热塑性聚氨酯,其基本上不含增塑剂,其肖氏A硬度为60以下,其通过i)线性多元醇的一步聚合制备,ii)有机二异氰酸酯和iii)主要包含乙烯的乙二醇增链剂 乙二醇和/或1,3-丙二醇; 其中所述线性多元醇(i)的数均分子量在1.5×10 3 g / mol至5.0×10 3 g / mol的范围内。 本发明的热塑性聚氨酯可以通过常规的制造方法容易地制造,并且由此制造的热塑性聚氨酯可以在可行的加工循环中模塑成型。 此外,热塑性聚氨酯制品具有低收缩率,具有良好的低温性能和良好的机械性能,并且在低温下不会显着硬化。
摘要:
This invention relates to biocompatible, biodegradable thermoplastic polyurethane or polyurethane/ureas comprising isocyanate, polyol and a conventional chain extender and/or a chain extender having a hydrolysable linking group and their use in tissue engineering and repair applications, particularly as stents and stent coating.
摘要:
This invention relates to biocompatible, biodegradable thermoplastic polyurethane or polyurethane/ureas comprising isocyanate, polyol and a conventional chain extender and/or a chain extender having a hydrolysable linking group and their use in tissue engineering and repair applications, particularly as stents and stent coating.
摘要:
Blocked polyisocyanates, obtained by using a polyisocyanate derived from an aliphatic and/or an alicyclic diisocyanate monomer, as a precursor, and including both of a blocked isocyanate group blocked with a pyrazole compound and a cationic group neutralized with an anion, in one molecule thereof; methods for making and using such blocked polyisocyanates; and compositions of matter including such blocked polyisocyanates.
摘要:
The present invention is a polyol composition (A) for the production of polyurethane resins which comprises a compound (a1) having a vinyl-polymerizable functional group represented by general formula (I) and a strength improver (a2) represented by general formula (II). In general formula (I), R is hydrogen, C1-15 alkyl, or C6-21 aryl. In general formula (II), R1 is a residue derived from an active-hydrogen-containing compound by removing one active hydrogen atom; Y is a residue derived from an at least divalent aromatic polycarboxylic acid (f) by removing the carboxyl groups; a is an integer satisfying the relationship: 1≦a≦(the number of substituents on the aromatic ring−1); Z is a residue derived from an at least m-valent active-hydrogen-containing compound by removing the m active hydrogen atoms; and m is an integer of 1 to 10.
摘要:
A carbon fiber bundle has carbon fibers and a sizing agent, wherein the sizing agent comprises a water soluble polyurethane resin having an SP value of 11.2 to 13.3, and the sizing agent is deposited on the carbon fibers at a rate of 0.5 to 7% by mass. In another carbon fiber bundle, the sizing agent is composed of the component shown in (A) and the component shown in (B1) or (B2) below, and the sizing agent is deposited on the carbon fibers at a rate of 0.5 to 7% by mass: (A) 73 to 98% by mass of a polyoxyalkylene unit; (B1) 0.5 to 15% by mass of an aromatic ester unit, 1.5 to 10% by mass of an aromatic urethane unit; and (B2) 0.5 to 10% by mass of an aromatic ester unit, 1.5 to 11% by mass of an aliphatic urethane unit.