Process for the preparation of aromatic dicarboxylic acids and aromatic
hydrocarbons
    121.
    发明授权
    Process for the preparation of aromatic dicarboxylic acids and aromatic hydrocarbons 失效
    制备芳族二羧酸和芳香烃的方法

    公开(公告)号:US5183926A

    公开(公告)日:1993-02-02

    申请号:US759794

    申请日:1991-09-13

    摘要: Aromatic dicarboxylic acids of the formula ##STR1## in which R.sup.1, R.sup.2, m, n, and X have the meaning mentioned in the description,can be prepared from the bisphenols, on which they are based, of the formula ##STR2## if the bisphenols are first reacted to give the bissulphonates, the sulphonate groups are removed catalytically with H.sub.2 and the hydrocarbons obtained in this way are doubly acylated in a known manner and the acyl groups are oxidized to the carboxyl groups.Many of the aromatic dicarboxylic acids which can be prepared in this way are new.

    摘要翻译: 其中R 1,R 2,m,n和X具有说明书中提到的含义的式(I)的芳族二羧酸可由其所基于的双酚制备,具有下式:IMAGE 如果双酚首先反应得到双磺酸盐,用H2催化除去磺酸盐基团,以这种方式得到的烃以已知的方式进行双重酰化,酰基被氧化成羧基。 可以以这种方式制备的许多芳族二羧酸是新的。

    Condensation products of thioalkylene oxides of polythio-alkylene oxides
with polyalkylene oxides, their preparation and their use as breakers
for water-in-oil emulsions
    124.
    发明授权
    Condensation products of thioalkylene oxides of polythio-alkylene oxides with polyalkylene oxides, their preparation and their use as breakers for water-in-oil emulsions 失效
    聚硫化烯氧化物的硫代环氧烷与聚环氧烷的缩合产物,它们的制备及其作为油包水乳液的破乳剂的用途

    公开(公告)号:US4745175A

    公开(公告)日:1988-05-17

    申请号:US821568

    申请日:1986-01-22

    CPC分类号: C10G33/04 C08G65/34 C08G81/00

    摘要: New sulphur-containing polyethers based on optionally polymeric thioalkylene oxides and polyalkylene oxides, method for their preparation and their use as breakers for water-in-oil emulsions, in particular, as breakers for crude oil emulsions. The polyethers are of the formula ##STR1## in which R.sub.1 and R.sub.2, independently of each other, represent hydrogen and/or a straight-chain or branched C.sub.1 to C.sub.20 alkyl group,R.sub.3 and R.sub.4, independently of each other and independently of adjacent ##STR2## groups, represent in each case hydrogen, a straight-chain or branched C.sub.1 to C.sub.20 alkyl group and/or for --A--O--B, whereA denotes a straight-chain or branched C.sub.1 to C.sub.20 alkylene group andB denotes a straight-chain or branched C.sub.1 to C.sub.20 alkylene-OH group or a ##STR3## group with R.sub.1 and R.sub.2 as defined above, n represents an integer from 1 to 100 andm represents an integer from 10 to 2,500.

    摘要翻译: 基于任选的聚合硫代亚烷基氧化物和聚环氧烷的新型含硫聚醚,其制备方法及其作为油包水乳液的破乳剂,特别是作为原油乳液的破碎剂。 聚醚具有式(I)的化合物,其中R 1和R 2彼此独立地表示氢和/或直链或支链C 1至C 20烷基,R 3和R 4彼此独立地且独立地 相邻的“IMAGE”基团表示氢,直链或支链C1至C20烷基和/或-AOB,其中A表示直链或支链C1至C20亚烷基,B表示直链 链或支链C1至C20亚烷基-OH基团或具有如上定义的R1和R2的基团,n表示1至100的整数,m表示10至2,500的整数。