公开(公告)号：US20130041114A1

公开(公告)日：2013-02-14

申请号：US13643863

申请日：2011-04-21

申请人： Robert E. Hefner, JR.

发明人： Robert E. Hefner, JR.

IPC分类号： C08F283/00

CPC分类号： C07C43/215 ,  C07C2603/68 ,  C07C2603/91 ,  C08G8/04 ,  C08G14/14

摘要： Embodiments include poly(allyl ether)s of polycyclopentadiene polyphenol that can be obtained by allylation of a polycyclopentadiene polyphenol, where the aromatic hydroxyl group(s) (—OH) are converted to HR1C═CR1—CH2—O— and/or H2R1C—CR1═HC—O—, where R1 is as described herein. Embodiments also include thermosettable compositions including the poly(allyl ether)s of polycyclopentadiene polyphenol and products obtained by curing the thermosettable compositions.

摘要翻译： 实施方案包括聚环戊二烯多酚的聚（烯丙基醚），其可通过将芳族羟基（-OH）转化为HR1C = CR1-CH2-O-和/或H2R1C-的聚环戊二烯多酚进行烯丙基化获得， CR1 = HC-O-，其中R 1如本文所述。 实施方案还包括可聚合的组合物，包括聚环戊二烯多酚的聚（烯丙基醚）和通过固化可热固组合物获得的产物。

公开(公告)号：US4568709A

公开(公告)日：1986-02-04

申请号：US712515

申请日：1985-03-18

申请人： Willibald Paar ,  Johann Gmoser ,  Helmut Honig ,  Wolfgang Daimer

发明人： Willibald Paar ,  Johann Gmoser ,  Helmut Honig ,  Wolfgang Daimer

IPC分类号： C08G14/14 ,  C09D5/44 ,  C08G18/80 ,  C08G59/14 ,  C09D3/58

CPC分类号： C09D5/4419 ,  C08G14/14 ,  Y10S524/901

摘要： Cathodically depositable electrodeposition paint binders comprising the reaction product of an epoxy resin with at least two epoxy groups with amines carrying primary amino groups and, optionally, with a carboxylic acid compound to provide an epoxy resin-amino adduct which is then reacted with a phenol and formaldehyde. The binders have excellent corrosion resistance and crosslink to provide coating films at relatively low stoving temperatures without splitting off of substances harmful to the environment.

摘要翻译： 阴极沉积的电沉积涂料粘合剂，其包含环氧树脂与至少两个环氧基团的反应产物和携带伯氨基的胺，以及任选地与羧酸化合物反应以提供环氧树脂 - 氨基加合物，然后与苯酚和 甲醛。 粘合剂具有优异的耐腐蚀性和交联性，以在相对低的烘烤温度下提供涂膜，而不会分解对环境有害的物质。

公开(公告)号：US4376849A

公开(公告)日：1983-03-15

申请号：US281891

申请日：1981-07-09

申请人： Fritz E. Kempter ,  Eberhard Schupp

发明人： Fritz E. Kempter ,  Eberhard Schupp

IPC分类号： C08C19/36 ,  C08G14/06 ,  C08G14/14 ,  C08G59/40 ,  C08G59/62 ,  C09D5/44 ,  C09D163/00 ,  C08G8/30 ,  C08L63/00 ,  C08L63/10

CPC分类号： C09D5/4488 ,  C08C19/36 ,  C08G14/06 ,  C08G14/14 ,  C08G59/4042 ,  C08G59/623 ,  C09D163/00 ,  C09D5/4403

摘要： A polyadduct/polycondensate which is water-dilutable when protonated with an acid, and which contains basic nitrogen groups, the groups being of the general formula (I) ##STR1## and/or of the general formula (II) ##STR2## as well as of the formula (III) ##STR3## where R.sup.1 and R.sup.2 are hydrogen or methyl, R.sup.3 and R.sup.4 are hydrogen, alkyl or a radical bonded to a phenol or phenolether, R.sup.5 and R.sup.6 are alkyl, hydroxyalkyl or alkoxyalkyl or are linked to one another to form a 5-membered or 6-membered ring, R.sup.7 is a polydienyl radical, n.sup.1 = from 0.5 to 3 and n.sup.2 = from 0.05 to 1.0, and its method of preparation.The polyadduct/polycondensate can be used, for example, as a surface-coating binder for the cathodic electrocoating of metal articles.

摘要翻译： 当用酸质子化并且含有碱性氮基团时可水稀释的多元加聚物/缩聚物，通式（I）和/或通式（II）的基团

公开(公告)号：US3647919A

公开(公告)日：1972-03-07

申请号：US3647919D

申请日：1969-12-29

申请人： HOOKER CHEMICAL CORP

发明人： LEE SUNG KI

IPC分类号： C08G8/38 ,  C08G12/46 ,  C08G14/14 ,  C08G16/06 ,  C08G37/16

CPC分类号： C08G14/14 ,  C08G8/38 ,  C08G12/46 ,  C08G16/06

摘要： FLEXIBLE PHENOLIC RESINS USEFUL FOR INTERIOR CAN COATINGS, DRUM AND PAIL LININGS, WIRE COATINGS, LAMINATING RESINS, BAKING PRIMERS, ADHESIVE, PIPE COATINGS, PHENOLIC MOLDING RESINS, FOUNDRY RESINS AND THE LIKE ARE PRODUCED BY THE METHOD COMPRISING THE STEPS OF: (1) REACTING A POLYMER CONTAINING ALPHA BETA CARBONTO-CARBON UNSATURATED CARBONYL FUNCTION WITH A NUCLEOPHILIC COMPOUND HAVING AT LEAST TWO ACTIVE HYDROGENS TO FORM A POLYMER CONTAINING AN ACTIVE PENDENT NUCLEOPHILLIC GROUP CONTAINING AT LEAST 1 ACTIVE HYDROGEN, (2) REACTING THE RESULTANT NUCLEOPHILIC GROUP CONTAINING ACTIVE HYDROGEN ON THE SAID POLYMER WITH AN ALDEHYDE TO FORM A POLYMER CONTAINING AN ACTIVE PENDENT METHYLOL DERIVATIVE GROUP, (3) REACTING SAID PENDENT METHYLOL GROUP WITH AN AROMATIC COMPOUND CONTAINING AN ORTHO-PARA ACTIVATING GROUP TO FORM A MODIFIED POLYMER CONTAINING A PENDENT ARYLALKYLENE GROUP CONTAINING AT LEAST ONE NUCLEAR HYDROGEN CAPABLE OF FURTHER CONDENSATION WITH AN ALDEHYDE, (4) RECOVERING THE POLYMER SO PRODUCED.

公开(公告)号：US2330827A

公开(公告)日：1943-10-05

申请号：US33207340

申请日：1940-04-27

申请人： KOPPERS CO INC

发明人： KESTER ERNEST B

IPC分类号： C08G14/14

CPC分类号： C08G14/14

公开(公告)号：US09334409B2

公开(公告)日：2016-05-10

申请号：US14265731

申请日：2014-04-30

申请人： AIR PRODUCTS AND CHEMICALS, INC.

发明人： Frederick Herbert Walker ,  Michael Ian Cook ,  Gamini Ananda Vedage ,  Robert Marjo Theodoor Rasing

IPC分类号： C09K3/00 ,  C08L63/00 ,  C08G65/48 ,  C08G73/02 ,  C07C209/00 ,  C07C211/00 ,  C07C217/00 ,  C09D7/12 ,  C08G14/06 ,  C08G14/14 ,  C08G59/50 ,  C08G59/56 ,  C07C215/50

CPC分类号： C09D7/1233 ,  C07C215/50 ,  C08G14/06 ,  C08G14/14 ,  C08G59/504 ,  C08G59/56 ,  C08L63/00 ,  C09D7/63

摘要： The present invention provides Mannich base derivatives of N,N′-dimethyl secondary diamine polymers including Mannich base derivatives of methylamine-terminated poly-(N-methylazetidine) and Mannich base derivatives of methylamine-terminated poly-(N-methylazacycloheptane). Amine curing agent compositions and amine-epoxy compositions containing Mannich base derivatives of N,N′-dimethyl secondary diamine polymers are also disclosed.

摘要翻译： 本发明提供了N，N'-二甲基仲二胺聚合物的曼尼希碱衍生物，包括甲胺封端的聚（N-甲基氮杂环丁烷）的曼尼希碱衍生物和甲胺封端的聚-N-（N-甲基氮杂环庚烷）的曼尼希碱衍生物。 还公开了胺固化剂组合物和含有N，N'-二甲基仲二胺聚合物的曼尼希碱衍生物的胺 - 环氧组合物。

公开(公告)号：US5298538A

公开(公告)日：1994-03-29

申请号：US507927

申请日：1990-04-11

申请人： Klaus Cibura ,  Yali F. Hallock ,  John A. Gilbert ,  John D. McGee

发明人： Klaus Cibura ,  Yali F. Hallock ,  John A. Gilbert ,  John D. McGee

IPC分类号： C08G14/06 ,  C08G14/073 ,  C08G14/14 ,  C08G59/14 ,  C08L61/34 ,  C09D5/44 ,  C08K3/20

CPC分类号： C08L61/34 ,  C08G14/14

摘要： Plasticizing resins, aqueous dispersions of cationic resins, and methods of making the same for use in cathodic electrodeposition are disclosed. The resins are formed from reacting a polyoxyalkylenepolyamine, a phenol, and a formaldehyde. The reactants may further include a block building unit derived from a polyepoxide. When used in combination with other conventional electrodepositable resins, deposited films with improved mechanical properties and descreased tendency toward cratering are obtained.

摘要翻译： 公开了增塑树脂，阳离子树脂的水分散体及其制备方法用于阴极电沉积。 树脂由聚氧亚烷基多胺，苯酚和甲醛反应形成。 反应物还可以包括衍生自聚环氧化物的嵌段结构单元。 当与其它常规的可电沉积树脂组合使用时，获得具有改善的机械性能和下降趋势的沉积膜。

公开(公告)号：US4444956A

公开(公告)日：1984-04-24

申请号：US439863

申请日：1982-11-08

申请人： John G. Schaffhausen ,  Adel B. Abdul-Malek

发明人： John G. Schaffhausen ,  Adel B. Abdul-Malek

IPC分类号： C08F8/34 ,  C08G12/46 ,  C08G14/14 ,  C10M159/16 ,  C08G12/06

CPC分类号： C10M159/16 ,  C08F8/32 ,  C08F8/50 ,  C08G12/46 ,  C08G14/14 ,  C10M2219/044

摘要： A process for the preparation of oil-soluble Mannich condensation products wherein an amine is prereacted with a sulfonic acid or ammonium sulfonate, and the prereaction product is reacted with an aldehyde and an oxidized olefin polymer.

摘要翻译： 一种制备油溶性曼尼期缩合产物的方法，其中胺与磺酸或磺酸铵预反应，并将预反应产物与醛和氧化烯烃聚合物反应。

公开(公告)号：US4396732A

公开(公告)日：1983-08-02

申请号：US282512

申请日：1981-07-13

申请人： Kazys Sekmakas ,  Raj Shah

发明人： Kazys Sekmakas ,  Raj Shah

IPC分类号： C08G14/06 ,  C08G14/14 ,  C08G59/62 ,  C09D5/44 ,  C08G59/02 ,  C08G59/14 ,  C08G59/50

CPC分类号： C09D5/4419 ,  C08G14/06 ,  C08G14/14 ,  C08G59/623

摘要： An amine resin soluble in water with the aid of an acid is produced by reacting a dihydric phenolic compound, such as a bisphenol, with a stoichiometric deficiency of preferably aromatic diepoxide, and then reacting the product containing less than -0.3 part of unreacted dihydric phenolic compound per part of reaction product with at least about 3.25 mol of formaldehyde per mol of said reaction product and with monosecondary amine to produce a Mannich base. This Mannich base is then reacted with additional diepoxide in an amount of from 0.5 to 2 epoxy equivalents per epoxy equivalent in the initially used diepoxide.

摘要翻译： 通过使二羟基酚类化合物（如双酚）与化学计量不足的优选芳族二环氧化物反应，然后使含有少于-0.3份未反应的二羟基酚类的产物 每一份反应产物与每摩尔所述反应产物至少约3.25摩尔甲醛的化合物和与单仲胺反应生成曼尼希碱。 然后，在最初使用的二环氧化物中，该曼尼希碱与额外的二环氧化物反应，其量为每环氧当量0.5至2环氧当量。

公开(公告)号：US4226971A

公开(公告)日：1980-10-07

申请号：US005125

申请日：1979-01-22

申请人： Harold G. Waddill ,  Howard P. Klein

发明人： Harold G. Waddill ,  Howard P. Klein

IPC分类号： C08G14/06 ,  C08G14/14 ,  C08G59/62 ,  C08G65/322 ,  C08G65/333 ,  C08L63/00

CPC分类号： C08G65/33365 ,  C08G14/06 ,  C08G14/14 ,  C08G59/623 ,  C08G65/322 ,  C08L63/00

摘要： A process for the accelerated cure of an epoxy resin is disclosed. The resulting epoxy resin may be used in protective coatings, adhesives, seamless and terrazo flooring and caulking and sealing compositions. The resulting resin system is also useful, for example, in casting, potting, in escapulating, grouting and patching. The process involves mixing an epoxy resin of the polyhydric phenol, polyglycidyl ether type with a novel accelerator-hardener which is a condensation product of phenol, formaldehyde and an aminoalkylene derivative of a polyoxyalkylenepolyamine.

摘要翻译： 公开了一种加速固化环氧树脂的方法。 所得到的环氧树脂可用于保护涂料，粘合剂，无缝和地层和填缝和密封组合物中。 所得的树脂体系也可用于例如浇铸，灌封，脱水，灌浆和修补。 该方法包括将多元酚的环氧树脂，聚缩水甘油醚型与作为苯酚，甲醛和聚氧亚烷基多胺的氨基亚烷基衍生物的缩合产物的新型促进剂 - 硬化剂混合。