Imino oxyphenyl acetic acid derivatives, methods and intermediates for
their preparation and use thereof
    133.
    发明授权
    Imino oxyphenyl acetic acid derivatives, methods and intermediates for their preparation and use thereof 失效
    亚氨基氧苯乙酸衍生物,其制备方法和中间体及其用途

    公开(公告)号:US5994359A

    公开(公告)日:1999-11-30

    申请号:US91921

    申请日:1998-06-25

    摘要: 2-Iminooxyphenylacetic acid derivatives ##STR1## where the substituents and the index have the following meanings: R.sup.1 is C(CO.sub.2 CH.sub.3).dbd.NOCH.sub.3 (Ia), C(CONHCH.sub.3).dbd.NOCH.sub.3 (Ib), C(CONH.sub.2).dbd.NOCH.sub.3 (Ic), C(CO.sub.2 CH.sub.3).dbd.CHOCH.sub.3 (Id) or C(CO.sub.2 CH.sub.3).dbd.CHCH.sub.3 (Ie);R.sup.2 is cyano, nitro, halogen, alkyl, haloalkyl or alkoxy;m is 0, 1 or 2;R.sup.3 is hydrogen, cyano, hydroxyl, halogen,alkyl, haloalkyl, alkoxyalkyl, alkoxy, haloalkoxy, alkylthio, cyclopropyl, alkenyl,unsubstituted or substituted aryloxyalkyl, benzyl or benzyloxy,R.sup.4 is hydrogen, cyano,unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl and hetaryl;unsubstituted or substituted alkoxy, alkenyloxy, alkynyloxy, cycloalkoxy, heterocyclyloxy, aryloxy and hetaryloxy;unsubstituted or substituted arylthio and hetarylthio;--Q--C(R.sup.5).dbd.N--Y.sup.1 --R.sup.6 or --Q--O--N.dbd.CR.sup.7 R.sup.8,R.sup.3 and R.sup.4 together with the carbon atom to which they are bonded are an unsubstituted or substituted four- to eight-membered ring which, besides carbon atoms, may contain one or two oxygen and/or sulfur atoms and/or NH and/or N(C.sub.1 -C.sub.4 -alkyl) groups;R.sup.3 and R.sup.4 not simultaneously being bonded to the carbon atom via hetero atoms;their salts, processes and intermediates for their preparation, and their use.

    摘要翻译: PCT No.PCT / EP96 / 05642 Sec。 371日期:1998年6月25日第 102(e)日期1998年6月25日PCT 1996年12月16日PCT PCT。 出版物WO97 / 24317 日期:1992年7月10日 - 亚氨基氧苯基乙酸衍生物,其中取代基和指数具有以下含义:R 1为C(CO 2 CH 3)= NOCH 3(Ia),C(CONHCH 3)= NOCH 3(Ib),C(CONH 2)= NOCH 3 Ic),C(CO 2 CH 3)= CHOCH 3(Id)或C(CO 2 CH 3)= CHCH 3(Ie); R2是氰基,硝基,卤素,烷基,卤代烷基或烷氧基; m为0,1或2; R3是氢,氰基,羟基,卤素,烷基,卤代烷基,烷氧基烷基,烷氧基,卤代烷氧基,烷硫基,环丙基,烯基,未取代或取代的芳氧基烷基,苄基或苄氧基,R4是氢,氰基,未取代或取代的烷基,烯基,炔基, 环烷基,杂环基,芳基和杂芳基; 未取代或取代的烷氧基,烯氧基,炔氧基,环烷氧基,杂环氧基,芳氧基和芳氧基; 未取代或取代的芳硫基和杂芳硫基; -QC(R5)= N-Y1-R6或-QON = CR7R8,R3和R4与它们所键合的碳原子一起是未取代或取代的四至八元环,除碳原子外, 一个或两个氧和/或硫原子和/或NH和/或N(C 1 -C 4 - 烷基)基团; R3和R4不同时通过杂原子键合到碳原子上; 它们的盐,其制备方法和中间体及其用途。

    Benzamidoxime derivatives, intermediates and processes for their preparation, and their use as fungicides
    137.
    发明授权
    Benzamidoxime derivatives, intermediates and processes for their preparation, and their use as fungicides 失效
    苯甲酰胺肟衍生物,中间体及其制备方法及其作为杀真菌剂的用途

    公开(公告)号:US06680402B2

    公开(公告)日:2004-01-20

    申请号:US10261122

    申请日:2002-10-01

    IPC分类号: C07C25549

    摘要: Benzamidoxime derivatives of the formula I: where R1 is difluoromethyl or trifluoromethyl R2 is hydrogen or fluorine R3 is C1-C4-alkyl which may be substituted by cyano, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkynyl, C3-C8-cycloalkyl-C1-C4-alkyl R4 is phenyl-C1-C6-alkyl which may carry one or more substitutents selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy on the phenyl ring, or is thienyl-C1-C4-alkyl which may carry one or more substituents selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy on the thienyl ring, or is pyrazolyl-C1-C4-alkyl which may carry one or more substituents selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy on the pyrazole ring, are prepared, and intermediates for their preparation and their use as fungicides are described.

    摘要翻译: 式I的苯甲酰胺肟衍生物:其中R 1是二氟甲基或三氟甲基R 2是氢或氟,R 3是可以被氰基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基 - C 1 -C 4 - 烷基,C 3 -C 6 - 烯基,C 3 -C 6 - 卤代烯基,C 3 -C 6 - 炔基,C 3 -C 8 - 环烷基-C 1 -C 4 - 烷基R 4是苯基-C 1 -C 6 - 或更多的选自苯基环上的卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基和C 1 -C 4 - 卤代烷氧基的取代基,可以携带的噻吩基-C 1 -C 4烷基 一个或多个选自噻吩基环上的卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基和C 1 -C 4 - 卤代烷氧基的取代基,其可以是吡唑基-C 1 -C 4烷基, 在吡唑环上携带一个或多个选自卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基和C 1 -C 4 - 卤代烷氧基的取代基,制备中间体和 描述了它们作为杀真菌剂的用途。