公开(公告)号：US4585540A

公开(公告)日：1986-04-29

申请号：US689134

申请日：1985-01-07

申请人： Henri B. Beer ,  Frans A. M. Van den Keybus ,  Jeries I. Bishara ,  William A. Kovatch ,  Jean M. Hinden

发明人： Henri B. Beer ,  Frans A. M. Van den Keybus ,  Jeries I. Bishara ,  William A. Kovatch ,  Jean M. Hinden

IPC分类号： C25B11/04 ,  C25B11/10 ,  C25B11/00 ,  H01M4/88

CPC分类号： C25B11/0484

摘要： A porous high surface area composite electroconductive catalytic material, particularly as electrocatalyst for electrolysis electrodes, comprises a porous pre-formed matrix which is a catalytic mixed crystal material of at least one platinum group metal oxide and at least one valve metal oxide throughout which a subsequently-added additional catalyst preferably consisting of at least one platinum group metal and/or oxide is dispersed by chemideposition in an oxidizing or reducing atmosphere preferably followed by an annealing post heat treatment. The porous matrix may be ruthenium-titanium oxide and the additional catalyst advantageously comprises at least two oxides of ruthenium, rhodium, palladium and iridium, other combinations being possible.

摘要翻译： 多孔高表面积复合导电催化材料，特别是作为电解电极的电催化剂，包括多孔预形成基体，其是至少一种铂族金属氧化物和至少一种阀金属氧化物的催化混合晶体材料，其中随后 优选由至少一种铂族金属和/或氧化物组成的附加催化剂通过化学沉积分散在氧化或还原气氛中，优选随后进行热处理退火。 多孔基质可以是钌 - 氧化钛，另外的催化剂有利地包括钌，铑，钯和铱的至少两种氧化物，其它组合也是可能的。

公开(公告)号：US4568441A

公开(公告)日：1986-02-04

申请号：US647194

申请日：1984-09-04

申请人： Michael J. Covitch ,  Donald L. DeRespiris ,  Leo L. Benezra ,  Elvin M. Vauss, Jr.

发明人： Michael J. Covitch ,  Donald L. DeRespiris ,  Leo L. Benezra ,  Elvin M. Vauss, Jr.

IPC分类号： C25B9/10 ,  C25B13/00 ,  C25B11/03

CPC分类号： C25B9/10 ,  C25B13/00 ,  Y10T156/10

摘要： A solid polymer electrolyte (SPE), solid polymer electrolyte electrode, and method for forming from cationic exchange perfluorocarbon copolymer. Disclosed are solution techniques for forming SPE's and SPE electrodes using fluorocarbon vinyl ether copolymers.

摘要翻译： 固体聚合物电解质（SPE），固体聚合物电解质电极和由阳离子交换全氟化碳共聚物形成的方法。 公开了使用氟碳乙烯基醚共聚物形成SPE和SPE电极的溶液技术。

公开(公告)号：US4560446A

公开(公告)日：1985-12-24

申请号：US683006

申请日：1984-12-18

申请人： Thinh Nguyen ,  Jean-Pol Wiaux ,  Christopher J. Vance

发明人： Thinh Nguyen ,  Jean-Pol Wiaux ,  Christopher J. Vance

IPC分类号： C25B11/06 ,  C25D3/54 ,  C25D3/56 ,  C25D3/44

CPC分类号： C25D3/54 ,  C25D3/56 ,  Y10T428/12736 ,  Y10T428/12743 ,  Y10T428/1275 ,  Y10T428/12757 ,  Y10T428/12806 ,  Y10T428/12812 ,  Y10T428/12819 ,  Y10T428/12826

摘要： Transition metals of the groups IVB, VB and VIB or alloys thereof with Al are electrodeposited in a system of an electrolyte based on an aromatic hydrocarbon. The electrolyte is originally prepared by dissolving 0.02 to 0.2 moles of an inexpensive high oxidation state transition metal halide and 0.2 to 0.5 moles AlBr.sub.3 in 1.00 mole of the aromatic hydrocarbon. Additions of transition metal powders or Mg or Al particles lead to the pre-reduction of the high oxidation state transition metal ions to lower oxidation states. Alkali metal or Mg halides may be used to establish favorable bath conditions. The electrolysis is carried out with dissolvable metal anodes, to maintain the bath composition. The plating current density, bath composition and method of preparation are chosen to obtain the desired composition of the coatings.

摘要翻译： 将基团IVB，VB和VIB或其与Al的合金的过渡金属电沉积在基于芳族烃的电解质体系中。 电解质最初通过在1.00摩尔芳烃中溶解0.02至0.2摩尔便宜的高氧化态过渡金属卤化物和0.2至0.5摩尔AlBr 3来制备。 添加过渡金属粉末或Mg或Al颗粒导致高度氧化态过渡金属离子的预还原以降低氧化态。 可以使用碱金属或卤化镁来建立有利的浴条件。 电解是用可溶解的金属阳极进行的，以保持浴组成。 选择电镀电流密度，浴组成和制备方法以获得所需的涂层组成。

公开(公告)号：US4543348A

公开(公告)日：1985-09-24

申请号：US467157

申请日：1983-02-16

申请人： Henri B. Beer ,  Jean M. Hinden ,  Mark R. Honard ,  Jeries I. Bishara ,  Joseph K. Walker, Jr.

发明人： Henri B. Beer ,  Jean M. Hinden ,  Mark R. Honard ,  Jeries I. Bishara ,  Joseph K. Walker, Jr.

IPC分类号： C25B11/04 ,  C25C7/02 ,  H01M4/88 ,  C25B11/00

CPC分类号： C25B11/04 ,  C25C7/02

摘要： An electrode having a lead base and a catalyst is manufactured by (a) compressing titanium sponge particles so as to consolidate them to a coherent porous layer, (b) applying the catalyst to the titanium sponge particles, and (c) fixing the layer of consolidated sponge particles to the lead base. The catalyst is formed on the titanium sponge particles before or after their consolidation to a coherent layer. This layer may be produced and fixed to the base in a single compressing and fixing step combining (a) and (c). Oxygen is anodically evolved at a reduced, stable potential by means of this electrode, so that it can be usefully applied as an anode in processes for electrowinning metals from acid electrolytes.

摘要翻译： 通过以下方法制造具有铅基和催化剂的电极：（a）压缩钛海绵颗粒以将其固结在粘着多孔层上，（b）将该催化剂施加到钛海绵颗粒上，和（c）将 固结海绵颗粒到铅基。 催化剂在固化到相干层之前或之后在钛海绵颗粒上形成。 可以在组合（a）和（c）的单个压缩和固定步骤中生产并固定该层。 氧气通过该电极在降低的稳定电位下阳极放电，使得其可以有用地用作阳极，用于从酸性电解质中电解提取金属。

公开(公告)号：US4524702A

公开(公告)日：1985-06-25

申请号：US635441

申请日：1984-07-30

申请人： Thomas M. Miller ,  Raymond J. Schraff ,  Nicholas Labas

发明人： Thomas M. Miller ,  Raymond J. Schraff ,  Nicholas Labas

IPC分类号： F27D1/00 ,  F27D1/14 ,  F27D1/18 ,  E04B1/80 ,  C04B43/02 ,  F23M7/00

CPC分类号： F27D1/0013 ,  F27D1/1808

摘要： A lightweight cover provides heat insulation for a heated vessel such as a soaking pit. The cover can be readily assembled in a manner providing for ease of repair plus simplicity of maintenance. The cover has a pair of opposing frame members with ceramic fiber insulation positioned therebetween. The insulation is secured in movable engagement such as a draped and swinging engagement. In this mode, compression can be exerted against the insulation to most desirably reduce heat loss otherwise caused by heat induced ceramic fiber shrinkage. Moreover, with this structure a ceramic fiber heat seal can be achieved around edges of the soaking pit.

摘要翻译： 轻质的盖子为诸如浸泡坑的加热容器提供隔热。 盖子可以容易地组装，方便维修和简单的维护。 盖具有一对相对的框架构件，陶瓷纤维绝缘件位于它们之间。 绝缘体以可动接合方式固定，例如悬垂和摆动接合。 在这种模式中，可以对绝缘体施加压缩，最希望地减少由热诱导的陶瓷纤维收缩引起的热损失。 此外，通过这种结构，可以在均热槽的边缘周围实现陶瓷纤维热封。

公开(公告)号：US4515672A

公开(公告)日：1985-05-07

申请号：US516867

申请日：1983-07-25

申请人： Gary F. Platek ,  Geoffrey P. Krug

发明人： Gary F. Platek ,  Geoffrey P. Krug

IPC分类号： C25C7/02 ,  C25C7/00 ,  C25B11/03 ,  C25B11/12

CPC分类号： C25C7/02 ,  Y10S204/13 ,  Y10S588/90

摘要： A reticulate cathode, for use in an electrolytic cell for scavenging a metal from a solution containing ions of the metal, comprising an open cell electrically conductive foam which has been coated with conductive carbon particles. A cathode assembly comprises an electrically conductive support member to which the conductive foam is secured, the support also serving as the current conductor. The resistivity of the foam is less than 3000 ohm-cm, preferably in the range from about 40-1000 ohm-cm, and it has a pore size in the range from about 10 pores per inch (ppi) to about 100 ppi, and a void fraction in the range from about 0.5 to about 0.98. In its most preferred embodiment, the cathode is preplated with copper in an amount from about 0.5-20 g/ft.sup.2 of active area, sufficient to impart rigidity to the cathde and avoid using a support member.

摘要翻译： 一种网状阴极，用于电解池中，用于从含有金属离子的溶液中清除金属，包括已经涂覆有导电碳颗粒的开孔电导体泡沫。 阴极组件包括导电支撑构件，导电泡沫固定到该支撑构件上，支撑体也用作电流导体。 泡沫的电阻率小于3000欧姆 - 厘米，优选在约40-1000欧姆 - 厘米的范围内，并且其孔径在约10个孔/英寸（ppi）至约100ppi的范围内，以及 空隙率在约0.5至约0.98的范围内。 在其最优选的实施方案中，阴极以约0.5-20g / ft 2的有效面积的量预先镀铜，足以赋予导电体刚性并避免使用支撑构件。

公开(公告)号：US4501824A

公开(公告)日：1985-02-26

申请号：US457013

申请日：1983-01-10

申请人： Kenneth L. Hardee ,  Arnold Z. Gordon ,  Charles B. Pyle ,  Rajat K. Sen

发明人： Kenneth L. Hardee ,  Arnold Z. Gordon ,  Charles B. Pyle ,  Rajat K. Sen

IPC分类号： C01B11/02 ,  B01J21/06 ,  B01J23/64

CPC分类号： C01B11/025

摘要： A heterogeneous catalyst and method for making chlorine dioxide from an acid and a metal chlorate solution. The catalyst comprises coformed mixed oxides of platinum group metals with at least one valve metal oxide.

摘要翻译： 一种由酸和金属氯酸盐溶液制备二氧化氯的非均相催化剂和方法。 催化剂包括铂族金属与至少一种阀金属氧化物的共成型混合氧化物。