摘要:
The invention provides a fuel cell comprising an anode in an anode region of the cell and a cathode in a cathode region of the cell, the anode being separated from the cathode by an ion selective polymer electrolyte membrane, the anode region of the cell being supplied in use thereof with an alcoholic fuel, the cathode region of the cell being supplied in use thereof with an oxidant, the cell being provided with means for generating an electrical circuit between the anode and the cathode and with a non-volatile redox couple in solution in flowing fluid communication with the cathode in the cathode region of the cell, the redox couple being at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with the oxidant after such reduction at the cathode, the redox couple and/or the concentration of the redox couple in the catholyte solution being selected so that the current density generated by the cell in operation is substantially unaffected by the crossover of the alcoholic fuel from the anode region of the cell to the cathode region of the cell across the polymer electrolyte membrane.
摘要:
An electrochemical device includes at least one electrochemical cell having an anode electrode and a cathode electrode, a reservoir configured to store an electrolyte and a mass distribution measuring device. The mass distribution measuring device includes at least one of a scale, a first pressure sensor located in a lower portion of the reservoir and a second pressure sensor located in an upper portion of the reservoir, or at least one strain gauge or load cell configured to measure a change a weight of the at least one electrochemical cell.
摘要:
An apparatus includes a cathode chamber configured to store a gel cathode and an anode chamber configured to store a gel anode. A cathode dispensing channel is in fluid communication with the cathode chamber and allows at least a portion of the gel cathode to be dispensed. An anode dispensing channel is in fluid communication with the anode chamber and allows at least a portion of the gel anode to be dispensed. A portion of the gel cathode and a portion of the gel anode come into contact upon being dispensed to form an active battery that can be used to generate an electrical current.
摘要:
A redox flow battery charged and discharged by supply of a positive electrode electrolyte stored in a positive electrode tank and a negative electrode electrolyte stored in a negative electrode tank to a battery element, in which the positive electrode electrolyte contains a Mn ion as a positive electrode active material, and the positive electrode tank includes a positive electrode charging pipe opening to a position close to a liquid level of the positive electrode electrolyte in the positive electrode tank, and a positive electrode discharging pipe opening to a position close to the bottom of the positive electrode tank. This redox flow battery can include a stirring mechanism for stirring the electrolytes in the tanks, and can include a connection pipe connecting the positive electrode tank to the negative electrode tank.
摘要:
Disclosed herein is an efficient and high capacity electrical energy storage device consisting of diaphragm-less anode and cathode cells charging and discharging an electrolyte containing suitable ions that store electrical energy during the charging cycle and release the electrical energy during the discharge cycle. The charge-discharge reactions are reversible so that the efficiency does not reduce with the number of cycles and efficiency is maintained until the last of the charged electrolyte passes through the cells.
摘要:
A direct Fuel Cell is based on organic liquid hydrogen storage materials, and includes a fuel cell unit connected to load through AC/DC convert circuit. The outlet and inlet of hydrogen storage materials on the fuel cell unit is connected to hydrogen storage tank through hydrogen storage output pipe and hydrogen storage input pipe, respectively. There is a pump for hydrogenated hydrogen storage materials on the hydrogenated hydrogen storage materials input pipe; the second outlet for water and gas on the fuel cell unit is connected to water tank through the second water output pipe. The water and gas inlet on the fuel cell unit is connected with oxygen input pipe; there is a gas outlet on the top of the water tank; the hydrogen storage materials tank contains hydrogen storage materials. The mentioned hydrogen storage materials are a multi-component mixture of liquid unsaturated heterocyclic aromatics.
摘要:
Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficicency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S2− and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.
摘要:
A method of operating a redox flow battery includes a step of observing a difference in relative volume between the anolyte fluid volume and the catholyte fluid volume. The ionic molality of anolyte fluid is increased if the relative volume of the anolyte fluid decreases. A redox flow battery having balanced anolyte and catholyte initial ionic molalities is also provided.
摘要:
This invention is directed to aqueous redox flow batteries comprising ionically charged redox active materials and ionomer membranes, wherein the charge of the redox active materials is of the same sign as that of the ionomer, so as to confer specific improvements.