公开(公告)号：US4725283A

公开(公告)日：1988-02-16

申请号：US872387

申请日：1986-06-10

Applicant: Jean Cotteret ,  Alex Junino ,  Gerard Lang

Inventor： Jean Cotteret ,  Alex Junino ,  Gerard Lang

IPC: A61K8/00 ,  A61K20060101 ,  A61K8/34 ,  A61K8/35 ,  A61K8/40 ,  A61K8/41 ,  A61K8/42 ,  A61K8/49 ,  A61K8/73 ,  A61Q5/06 ,  A61Q5/10 ,  C09B20060101 ,  C09B51/00 ,  D06P3/04 ,  A61K7/13

CPC classification number: A61K8/418 ,  A61Q5/065

Abstract: The invention relates to dyeing compositions for direct dyeing of keratinic fibres, containing, in a cosmetically acceptable medium:(a) at least one yellow or green-yellow dye corresponding to the formula (I): ##STR1## in which X=Cl, Br, F, and R.sub.1 and R.sub.2 denote, independently of each other, hydrogen, alkyl, hydroxyalkyl, or alkylaminoalkyl in which the aminoalkyl group may be mono- or disubstituted provided that R.sub.1 and R.sub.2 do not simultaneously denote a hydrogen atom, and(b) at least one blue or violet dye corresponding to the formula: ##STR2## in which R.sub.3 denotes a hydrogen atom or an alkyl, monohydroxyalkyl, polyhydroxyalkyl or alkoxyalkyl radical and R.sub.4 and R.sub.5 have separately the same meanings as R.sub.3 but cannot denote a hydrogen atom.

Abstract translation: 本发明涉及用于直接染色角蛋白纤维的染色组合物，其包含在化妆品可接受的介质中：（a）至少一种对应于式（I）的黄色或绿黄色染料：其中X = Cl，Br，F和R 1和R 2彼此独立地表示氢，烷基，羟基烷基或烷基氨基烷基，其中氨基烷基可以被单或二取代，条件是R 1和R 2不同时表示氢原子， 和（b）对应于下式的至少一种蓝色或紫色染料：其中R 3表示氢原子或烷基，单羟基烷基，多羟基烷基或烷氧基烷基，R 4和R 5分别具有与R 3 但不能表示氢原子。

公开(公告)号：US4692166A

公开(公告)日：1987-09-08

申请号：US841813

申请日：1986-03-20

Applicant: Alex Junino ,  Gerard Lang ,  Herve Andrean ,  Jean Cotteret

Inventor： Alex Junino ,  Gerard Lang ,  Herve Andrean ,  Jean Cotteret

IPC: A61K8/00 ,  A61K8/33 ,  A61K8/34 ,  A61K8/40 ,  A61K8/41 ,  A61K8/46 ,  A61K8/49 ,  A61K8/73 ,  A61Q5/10 ,  C07D317/48 ,  C07D317/52 ,  C07D317/54 ,  D06P1/32 ,  D06P1/64 ,  D06P3/08 ,  A61K7/13

CPC classification number: A61Q5/10 ,  A61K8/4973

Abstract: Use for dyeing keratinous fibres, and especially human hair, on a compound corresponding to the formula: ##STR1## in which X denotes a bromine or chlorine atom.

Abstract translation: 用于将角质纤维特别是人发染色在对应于下式的化合物：其中X表示溴或氯原子。

公开(公告)号：US4663088A

公开(公告)日：1987-05-05

申请号：US825933

申请日：1986-02-04

Applicant: Gerard Lang ,  Madeleine Leduc ,  Alain Malaval

Inventor： Gerard Lang ,  Madeleine Leduc ,  Alain Malaval

IPC: A61K8/35 ,  A61K8/46 ,  A61Q17/04 ,  C07C45/68 ,  C07C45/74 ,  C07C49/683 ,  C07C49/697 ,  C07C49/753 ,  C07C59/86 ,  C07C309/03 ,  C07C309/25 ,  C07C143/52

CPC classification number: A61K8/35 ,  A61K8/466 ,  A61Q17/04 ,  C07C255/00 ,  C07C309/00 ,  C07C45/68 ,  C07C45/74 ,  C07C49/683 ,  C07C49/697 ,  C07C49/753 ,  C07C59/86

Abstract: The invention relates to new 3-benzylidene-camphor derivatives of the formula: ##STR1## in which R.sub.1 denotes H or SO.sub.3.sup..crclbar. M.sup..sym., with M=H, an alkali metal or N.sup..sym. (R.sub.3).sub.4, with R.sub.3 =H or C.sub.1 -C.sub.4 alkyl or hydroxyalkyl; R.sub.2 denotes C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and n=0-4; and Z denotes ##STR2## in which R.sub.4 has the same meaning as R.sub.1 and can be identical or different, or alternatively ##STR3## in which R.sub.5 denotes H, optionally substituted aryl, C.sub.1 -C.sub.4 alkyl, --CN, --COOR7 or ##STR4## and R.sub.6 denotes --COOR.sub.8 or ##STR5## in which R.sub.7 and R.sub.8, which are identical or different, denote alkyl, alkenyl, cycloalkyl or aralkyl and R.sub.9 and R.sub.10, which are identical or different, denote H, alkyl, alkenyl or cycloalkyl; if R.sub.5 =H, alkyl or aryl, R.sub.6 can represent --COO.sup..crclbar. M.sup..sym. ; the methylidene-camphor radical, on the one hand, and the radical Z, on the other hand, are in the meta or para position. These derivatives act as sun filters.

Abstract translation: 本发明涉及下式的新的3-亚苄基 - 樟脑衍生物：其中R 1表示H或SO 3（ - ）M（+），其中M = H，碱金属或N（+）（ R3）4，其中R3 = H或C1-C4烷基或羟烷基; R2表示C1-C4烷基或C1-C4烷氧基，n = 0-4; 并且Z表示其中R 4具有与R 1相同的含义并且可以相同或不同，或者其中R 5表示H，任选取代的芳基，C 1 -C 4烷基，-CN，-COOR 7或

公开(公告)号：US4153065A

公开(公告)日：1979-05-08

申请号：US806817

申请日：1977-06-15

Applicant: Gerard Lang

Inventor： Gerard Lang

IPC: A61K8/41 ,  A61K8/49 ,  A61Q5/06 ,  A61Q5/10 ,  C09B29/00 ,  D06P3/00 ,  A45D7/00

CPC classification number: C09B29/0048 ,  A61K8/413 ,  A61K8/4926 ,  A61Q5/065 ,  A61Q5/10

Abstract: Compositions for dyeing human hair contain in an aqueous or hydroalcoholic solution an azo derivative of pyridine N-oxide as a hair dye present in amounts of 0.001-1 weight percent of said composition which has a pH ranging from 3-9.5. Certain of said azo derivatives of pyridine N-oxide are new compounds.

Abstract translation: 用于染色人头发的组合物在水溶液或水醇溶液中含有作为染发剂的吡啶N-氧化物的偶氮衍生物，其存在量为所述组合物的0.001-1重量％，其pH为3-9.5。 吡啶N-氧化物的某些所述偶氮衍生物是新的化合物。

公开(公告)号：US4151162A

公开(公告)日：1979-04-24

申请号：US707769

申请日：1976-07-22

Applicant: Gerard Lang ,  Andree Bugaut

Inventor： Gerard Lang ,  Andree Bugaut

IPC: A61K8/41 ,  A61K8/49 ,  A61Q5/10 ,  C09B23/16 ,  A61K7/13 ,  C09B29/06 ,  C09B29/08

CPC classification number: C09B23/166 ,  A61K8/413 ,  A61K8/4926 ,  A61K8/494 ,  A61K8/4946 ,  A61Q5/10

Abstract: Dyes for application to hair to impart rich color nuances thereto, include diazamerocyanines, the mesomeric forms thereof and the salts thereof, of the formulaA.dbd.N--N.dbd.B",wherein A is ##STR1## and wherein B" is ##STR2##

Abstract translation: 用于赋予毛发以赋予其丰富色彩细微差别的染料包括式A = NN = B“的二氮杂吖啶，其中间体形式及其盐，其中A为”IMA“，其中B”为“ （I）（II）（III）（IV）（V）

公开(公告)号：US4150115A

公开(公告)日：1979-04-17

申请号：US742118

申请日：1976-11-15

Applicant: Bernard Jacquet ,  Gerard Lang

Inventor： Bernard Jacquet ,  Gerard Lang

IPC: C08G73/00 ,  A61K8/00 ,  A61K8/72 ,  A61K8/73 ,  A61K8/81 ,  A61K8/84 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/10 ,  A61Q7/00 ,  C08G73/02 ,  C11D3/37 ,  A61K7/06 ,  A61K7/09 ,  A61K7/11 ,  A61K31/74

CPC classification number: A61Q5/10 ,  A61K8/731 ,  A61K8/817 ,  A61K8/8182 ,  A61K8/84 ,  A61K2800/5426 ,  Y10S424/01 ,  Y10S424/02 ,  Y10S424/03 ,  Y10S424/04

Abstract: Quaternized polyamine polymers are employed in cosmetic compositions for application to the hair or skin. The polymer has recurring units of the formula: ##STR1## WHEREIN A is polymethylene having 2-10 carbon atoms, B is selected from polymethylene having 3-10 carbon atoms, xylylidenyl group --CH.sub.2 --C.sub.6 H.sub.4 --CH.sub.2 -- ortho, meta or para, --(CH.sub.2).sub.x --O--(CH.sub.2).sub.x -- wherein x is 2 or 3, or --CH.sub.2 --CHOH--CH.sub.2 --; R.sub.1 and R.sub.3 represent an aliphatic radical having 1-12 carbon atoms; R.sub.2 and R.sub.4 represent an aliphatic radical having 1-20 carbon atoms; R.sub.5 is hydrogen or an aliphatic, alicyclic, aryl or arylaliphatic radical containing 1-20 carbon atoms; R.sub.6 is an aliphatic or arylaliphatic radical containing 1-20 carbon atoms; X is a halide anion; Y is selected from a halide anion, SO.sub.4 H.sup..crclbar. or CH.sub.3 SO.sub.4.sup..crclbar. ; and n and p are whole numbers with p being able to be 0, such that the ratio p/n+p ranges from 0 to 0.95.

Abstract translation: 季铵化聚胺聚合物用于化妆品组合物中以用于头发或皮肤。 该聚合物具有下式的重复单元：A是具有2-10个碳原子的多亚甲基，B选自具有3-10个碳原子的多亚甲基，亚二甲苯基-CH 2 -C 6 H 4 -CH 2 - 邻，间位或对位， - （CH 2）x O-（CH 2）x - ，其中x为2或3，或-CH 2 -CHOH -CH 2 - ; R1和R3表示具有1-12个碳原子的脂族基团; R2和R4表示具有1-20个碳原子的脂族基团; R5是氢或含有1-20个碳原子的脂族，脂环族，芳基或芳基脂族基; R6是含有1-20个碳原子的脂族或芳基脂族基; X是卤素阴离子; Y选自卤化物阴离子，SO 4 H（ - ）或CH 3 SO 4（ - ）; 并且n和p是整数，其中p可以为0，使得p / n + p的比率在0至0.95的范围内。

公开(公告)号：US4025301A

公开(公告)日：1977-05-24

申请号：US617159

申请日：1975-09-26

Applicant: Gerard Lang

Inventor： Gerard Lang

IPC: C07D213/76 ,  C07D213/77 ,  C07D213/89 ,  C09B29/00 ,  C09B29/033 ,  C09B29/06 ,  C09B44/12 ,  A61K7/13

CPC classification number: C07D213/77 ,  A61K8/413 ,  A61K8/4926 ,  A61Q5/065 ,  A61Q5/10 ,  C07D213/89 ,  C09B29/0048 ,  C09B29/06 ,  C09B44/126 ,  Y10S424/01 ,  Y10S424/02

Abstract: A composition for dyeing hair comprises in a cosmetic vehicle at least one dye compound of the formula ##STR1## wherein B is selected from the group consisting of ##STR2## and ##STR3## wherein R is lower alkyl containing 1-4 carbon atoms, R.sub.1 is selected from the group consisting of hydrogen, lower alkyl containing 1-4 carbon atoms, lower alkoxy containing 1-4 carbon atoms and chlorine,R.sub.2 is selected from the group consisting of hydrogen, methyl and methoxy,R.sub.4 is selected from the group consisting of hydrogen, methyl, chlorine, nitro, amino and acetylamino,R.sub.3 is hydrogen or together with R.sub.4 forms an unsaturated 6 membered ring carrying a hydroxy substituent chelated with one of the nitrogen atoms of the azo link, and ##STR4## where R.sub.5 is selected from the group consisting of hydrogen, -CH.sub.3, -C.sub.2 H.sub.5 and .beta.-hydroxyethyl, and R.sub.6 is selected from the group consisting of hydrogen, --CH.sub.3, --C.sub.2 H.sub.5, .beta.-hydroxyethyl, phenyl and -CH.sub.2 SO.sub.3 N.sub.a,With the proviso that when B is ##STR5## the anion X.sup.- associated with the quaternized nitrogen atom is the anion residue of a member selected from the group consisting of organic acid and mineral acid, said composition having a pH ranging from 3 to 11 and said compound being present in an amount ranging from 0.001 to 1 percent by weight of said composition.

Abstract translation: 用于染发的组合物在化妆品载体中包含至少一种式IMA图像的染料化合物，其中B选自由下列组成的组：其中R是含有1-4个碳原子的低级烷基，R 1 选自氢，含1-4个碳原子的低级烷基，含有1-4个碳原子的低级烷氧基和氯，R2选自氢，甲基和甲氧基，R4选自 的氢，甲基，氯，硝基，氨基和乙酰氨基，R 3是氢或与R 4一起形成携带与偶氮连接的氮原子之一螯合的羟基取代基的不饱和6元环，并且其中选择R5的 来自由氢，-CH 3，-C 2 H 5和β-羟乙基组成的组，R 6选自氢，-CH 3，-C 2 H 5，β-羟乙基，苯基和-CH 2 SO 3 N a，当B为 阴离子X < - >为 与季铵化氮原子缔合的是选自有机酸和无机酸的成员的阴离子残基，所述组合物的pH为3至11，所述化合物的存在量为0.001至1％，通过 所述组合物的重量。