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129 条记录 (耗时 0.032 秒)

    Process for producing organic sulfur acids or salts thereof
    6.
    发明授权
    Process for producing organic sulfur acids or salts thereof 有权
    生产有机硫酸或其盐的方法

    公开(公告)号：US06143924A

    公开(公告)日：2000-11-07

    申请号：US522140

    申请日：2000-03-09

    申请人： Yasutaka Ishii ,  Tatsuya Nakano

    发明人： Yasutaka Ishii ,  Tatsuya Nakano

    IPC分类号： B01J31/02 ,  B01J31/20 ,  C07B61/00 ,  C07C303/02 ,  C07C303/14 ,  C07C303/32 ,  C07C307/00 ,  C07C309/25 ,  C07C309/00

    CPC分类号： C07C303/14 ,  C07C2103/74

    摘要： In the presence of an imide compound of the following formula (1), a sulfur oxide is reacted with an organic substrate to yield a corresponding sulfur acid or its salt. This process can efficiently produce an organic sulfur acid or its salt under relatively mild conditions. ##STR1## wherein each of R.sup.1 and R.sup.2 is, identical to or different from each other, a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group, a hydroxyl group, an alkoxy group, a carboxyl group, an alkoxycarbonyl group, or an acyl group, where R.sup.1 and R.sup.2 may be combined to form a double bond or an aromatic or non-aromatic ring; X is an oxygen atom or a hydroxyl group, where one or two N-substituted cyclic imido groups indicated in the formula (1) may be further bonded to the aforementioned R.sup.1, R.sup.2 or to the double bond or aromatic or non-aromatic ring formed together by R.sup.1 and R.sup.2.

    摘要翻译： 在下式（1）的酰亚胺化合物存在下，使硫氧化物与有机底物反应，得到相应的硫酸或其盐。 该方法可以在相对温和的条件下有效地产生有机硫酸或其盐。 其中R 1和R 2各自相同或不同，为氢原子，卤素原子，烷基，芳基，环烷基，羟基，烷氧基，羧基，烷氧基羰基 基团或酰基，其中R 1和R 2可以结合形成双键或芳族或非芳族环; X是氧原子或羟基，其中式（1）中所示的一个或两个N-取代的环亚胺基可以进一步键合到上述R 1，R 2或形成双键或芳族或非芳族环 由R1和R2组合。

    3-benzylidene-camphors, process for their preparation and their use in protection against UV rays
    10.
    发明授权
    3-benzylidene-camphors, process for their preparation and their use in protection against UV rays 失效
    3-亚苄基 - 樟脑，其制备方法及其在防紫外线中的应用

    公开(公告)号：US4654434A

    公开(公告)日：1987-03-31

    申请号：US825932

    申请日：1986-02-04

    申请人： Gerard Lang ,  Madeleine Leduc ,  Alain Malaval

    发明人： Gerard Lang ,  Madeleine Leduc ,  Alain Malaval

    IPC分类号： A61K8/35 ,  A61K8/46 ,  A61Q17/04 ,  C07C45/68 ,  C07C45/74 ,  C07C49/683 ,  C07C49/697 ,  C07C49/753 ,  C07C59/86 ,  C07C309/25 ,  C07C69/76 ,  C07C143/52

    CPC分类号： A61K8/466 ,  A61K8/35 ,  A61Q17/04 ,  C07C255/00 ,  C07C309/00 ,  C07C45/68 ,  C07C45/74 ,  C07C49/683 ,  C07C49/697 ,  C07C49/753 ,  C07C59/86

    摘要： The invention relates to new 3-benzylidene-camphor derivatives of the formula: ##STR1## in which R.sub.1 denotes H or SO.sub.3.sup..crclbar. M.sup..sym., with M=H, an alkali metal or N.sup..sym. (R.sub.3).sub.4, with R.sub.3 =H or C.sub.1 -C.sub.4 alkyl or hydroxyalkyl; R.sub.2 denotes C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and n=0-4; and Z denotes ##STR2## in which R.sub.4 has the same meaning as R.sub.1 and can be identical or different, or alternatively ##STR3## in which R.sub.5 denotes H, optionally substituted aryl, C.sub.1 -C.sub.4 alkyl, --CN, --C00R7 or ##STR4## and R.sub.6 denotes --COOR.sub.8 or ##STR5## in which R.sub.7 and R.sub.8, which are identical or different, denote alkyl, alkenyl, cycloalkyl or aralkyl and R.sub.9 and R.sub.10, which are identical or different, denote H, alkyl, alkenyl or cycloalkyl; if R.sub.5 =H, alkyl or aryl, R.sub.6 can represent --COO.sup..crclbar. M.sup..sym. ; the methylidene-camphor radical, on the one hand, and the radical Z, on the other hand, are in the meta or para position. These derivatives act as sun filters.

    摘要翻译： 本发明涉及下式的新的3-亚苄基 - 樟脑衍生物：其中R 1表示H或SO 3（ - ）M（+），其中M = H，碱金属或N（+）（ R3）4，其中R3 = H或C1-C4烷基或羟烷基; R2表示C1-C4烷基或C1-C4烷氧基，n = 0-4; 并且Z表示其中R 4具有与R 1相同的含义并且可以相同或不同，或者其中R 5表示H，任选取代的芳基，C 1 -C 4烷基，-CN，-COOR 7或