摘要:
Fertilizer materials, especially potassium dihydrogen phosphate, are produced by the reaction of phosphate rock or a solubilized form thereof, such as mono calcium phosphate, dicalcium phosphate, etc., concentrated sulfuric acid, potassium hydrogen sulfate and, optionally fresh or recycle phosphoric acid, the resulting mixture is filtered to remove the calcium sulfate precipitate and the potassium dihydrogen phosphate is recovered from the filtrate, either by concentration and filtration or by extraction with an organic solvent.
摘要:
Substantially fluoride-free phosphoric acid is produced by the acidulation of phosphate rock with sulfuric acid wherein the acidulation reaction is conducted in the presence of added potassium as K.sub.2 O bearing compounds, e.g. KHSO.sub.4, K.sub.2 SO.sub.4, KH.sub.2 PO.sub.4 or KOH, and additional silica, to precipitate fluorides and silica as potassium silicofluoride and then removed on separation of the gypsum formed. Optionally, additional silica may be added to the phosphoric acid solution recovered after precipitation and removal of the gypsum, to precipitate additional fluoride as potassium silicofluoride to further purify the phosphoric acid. In a further embodiment sufficient potassium may be added along with additional silica in the acidulation step to produce potassium dihydrogen phosphate and phosphoric acid as additional products. The phosphoric acid and potassium dihydrogen phosphate are recovered substantially free from fluoride contamination and the reaction is carried out in the substantial absence of fluorine evolution into the atmosphere. Also disclosed is a process for conducting a conventional phosphoric acid facility to produce phosphoric acid and gypsum wherein defluorination of the phosphoric acid recovered is achieved by silicon dioxide and K.sub.2 O addition and the fluorides are removed from the system, the process including steps for production of pure phosphoric acid and potassium dihydrogen phosphate.
摘要翻译:通过用硫酸酸化磷酸盐岩产生基本上不含氟化物的磷酸,其中酸化反应在加入的K 2存在下作为带有K2O的化合物,例如, KHSO 4,K 2 SO 4,KH 2 PO 4或KOH和另外的二氧化硅,以氟硅酸钠和二氧化硅的形式沉淀,然后在形成的石膏分离后除去。 任选地,可以在沉淀和除去石膏之后回收的磷酸溶液中加入另外的二氧化硅,以沉淀另外的氟化硅作为氟硅酸钾以进一步纯化磷酸。 在进一步的实施方案中,在酸化步骤中可以连同另外的二氧化硅一起加入足量的钾,以产生磷酸二氢钾和磷酸作为附加产物。 基本上没有氟化物污染物回收磷酸和磷酸二氢钾,并且基本上没有氟进入大气中进行反应。 还公开了一种用于进行常规磷酸设备以生产磷酸和石膏的方法,其中回收的磷酸的脱氟通过二氧化硅和K 2 O添加实现并且氟化物从系统中除去,该方法包括生产 纯磷酸和磷酸二氢钾。
摘要:
Potassium sulfate (K.sub.2 SO.sub.4) is prepared by contacting potassium chloride with an aqueous solution containing potassium bisulfate at a temperature of about 65.degree.-110.degree. C., cooling the solution and permitting the potassium sulfate to crystallize from solution.
摘要翻译:通过在约65-110℃的温度下使氯化钾与含有硫酸氢钾的水溶液接触来制备硫酸钾(K 2 SO 4),冷却溶液并允许硫酸钾从溶液中结晶。
摘要:
Method and apparatus are disclosed for converting seismic data obtained at known points to synthesized seismic traces obtainable at arbitrarily selected points. Two dimensional seismic data are converted to three dimensional data with the aid of a programmed computer to permit generation of arbitrary views of a particular geologic structure as well as a mathematical representation of the structure. In order to provide accurate interpolation from the known data, both apparent and true dip characteristics are obtained for the surveyed structure, and seismic trace data for a desired point are synthesized as a function of the dip of the surveyed structure. The dip characteristics are obtained from partial derivatives of the two dimensional data in specified coordinate directions. A three dimensional surface corresponding to the dip characteristics is obtained by a least squares fitting technique. The data obtained at the known points are weighted both by distance from the desired point and the semblance coefficients associated with dip for these points to synthesize the desired data.
摘要:
Gelled detergent compositions are contained in cleaning devices such as plastic mesh pads and sponges, which gelled detergent compositions comprise water, an alkali metal hydroxide, an alkali metal phosphate, a wetting agent, a fatty acid which reacts with the alkali metal hydroxide to form a soap, a chelating agent, a surfactant, and optionally colorant and odorant components.
摘要:
A novel tire sealant and inflator composition comprising a resin, a latex sealant, alkylene glycol, fibers, an alkanolamine, a foaming agent, and water. The composition is packaged in aerosol cans with a chlorofluorocarbon propellant/inflator and used to seal and inflate punctured tires. The composition is applied to the punctured tire through the valve stem, and acts to seal the puncture and inflate the tire sufficiently to support the weight of the car.
摘要:
Cuprous chloride is produced from the complex salt, 2KCl.CuCl, obtained as a by-product in the copper industry where chalcopyrite is decomposed in the presence of potassium chloride, by a series of steps involving reaction of an aqueous solution of the complex salt of potassium chloride and cuprous chloride with ammonia, separating the resulting solid potassium chloride from a solution containing cuprous chloride and ammonia, removing the ammonia from the solution to cause precipitation of the cuprous chloride and recovering solid cuprous chloride. Ammonia may then be recycled to the solution from which the cuprous chloride is removed and to which additional complex salt is added to repeat the cycle.
摘要:
A novel sulfur-based adduct formed by reacting sulfur with a diene-containing by-product hydrocarbon mixture available from petrochemical operations and/or from coal processing. The adduct is a reaction product of sulfur and each of the dienes contained in the by-product mixture. Also disclosed is a road surface composition containing this adduct as an asphalt extender or as a replacement for asphalt, and there are also disclosed other compositions containing this adduct such as sulfur cements, sulfur concretes, coatings, foams, structural materials and insulators.
摘要:
A method is disclosed for the acidulation of phosphate rock and the production of substantially pure alkali metal phosphates, calcium phosphates, and phosphoric acid which are essentially free of fluorides and recovery of the fluorine values from the starting phosphate rock in useful form. The steps of the method comprise initial acidulation of phosphate rock with a phosphoric acid solution containing sufficient alkali metal values to provide R.sub.2 O in the system, where R is alkali metal, to solubilize the phosphates and form an insoluble precipitate comprising a mixture of impurities, sand (SiO.sub.2) and the fluorides, from which the fluorides can be recovered in usable form. In preferred embodiments, after removal of the precipitate containing the fluorides, a portion of the solution of phosphoric acid and calcium phosphate is reacted with sulfuric acid and RHSO.sub.4 or R.sub.2 SO.sub.4 where R is alkali metal, to form a solution of RH.sub.2 PO.sub.4 and phosphoric acid and at least a portion of the RH.sub.2 PO.sub.4 and phosphoric acid solution is recycled to the initial acidulation to provide the R.sub.2 O and phosphoric acid makeup. The remainder of the solution of calcium phosphate and phosphoric acid may be further processed for recovery of useful products such as monocalcium phosphate and/or dicalcium phosphate, phosphoric acid, alkali metal phosphates, and calcium sulfate.
摘要:
Potassium polyphosphate polymers having ratios of P.sub.2 O.sub.5 to K.sub.2 O which make them suitable as fertilizer products are prepared by reacting potassium fluosilicate also known as potassium silicofluoride with phosphoric acid and sulfuric acid at temperatures of about 250-500.degree. C.