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公开(公告)号：US4298480A
公开(公告)日：1981-11-03
申请号：US96370
申请日：1979-11-21
申请人： Harold E. Wixon
发明人： Harold E. Wixon
IPC分类号： C11D1/14 , C11D1/62 , C11D1/72 , C11D3/00 , C11D3/22 , C11D10/04 , C11D1/86 , C11D17/06 , D06M13/46
摘要： Heavy duty detergent compositions, particularly for imparting improved softness and detersive effects to fabrics laundered therewith, said composition including in addition to conventional builder and principally anionic surfactant components, fatty acid soap, and cationic softener of the di-lower-di-higher alkyl quaternary ammonium and/or heterocyclic imide type, e.g., imidazolinium, the weight ratio of soap to softener being about 8:1 to 1:3 preferably 5:1 to 1:2, more preferably 3:2:2:3, e.g. about unity. The soap in the form of a spaghetti, flake, or other shape and is present in the product composition as substantially homogeneously dispersed, discrete particles.
摘要翻译： 重垢洗涤剂组合物，特别是用于赋予对其洗涤的织物提高的柔软度和去污效果，所述组合物除了常规助洗剂和主要是阴离子表面活性剂组分，脂肪酸皂和二低级二高级烷基季铵盐的阳离子软化剂之外 铵和/或杂环酰亚胺类型，例如咪唑啉，皂与软化剂的重量比为约8:1至1:3，优选5:1至1:2，更优选3:2:2:3，例如 关于团结 以意大利面，薄片状或其他形状形式的肥皂，在产品组合物中作为基本上均匀分散的离散颗粒存在。
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公开(公告)号：US4971706A
公开(公告)日：1990-11-20
申请号：US324960
申请日：1989-03-20
申请人： Harold E. Wixon
发明人： Harold E. Wixon
IPC分类号： C11D3/00 , C11D9/00 , D06M13/192
CPC分类号： D06M13/192 , C11D3/0015 , C11D3/2079 , C11D9/002
摘要： A liquid fabric softening composition comprising a predispersed finely-divided divalent and/or trivalent metal soap homogeneously suspended in an aqueous dispersing medium; the process of preparing said liquid fabric softener; and a method of softening fabrics therewith.
摘要翻译： 一种液体织物软化组合物，其包含均匀悬浮在水分散介质中的预分散的细分二价和/或三价金属皂; 制备所述液体织物柔软剂的过程; 以及使织物软化的方法。
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公开(公告)号：US4664950A
公开(公告)日：1987-05-12
申请号：US475294
申请日：1983-03-14
申请人： Harold E. Wixon
发明人： Harold E. Wixon
CPC分类号： C11D17/065 , C11D1/66 , C11D3/062 , C11D3/1246
摘要： A free flowing particulate heavy duty laundry detergent containing no more than 8.7% of phosphorus (from phosphate) is comprised of sodium tripolyphosphate particles having nonionic detergent in the interior and on the surface thereof, which adheres a coating of smaller particles of ion-exchanging zeolite to the phosphate. Also within the invention is a method of making such a product by pre-mixing spray dried sodium tripolyphosphate particles and smaller zeolite particles and admixing with them, as by spraying, in liquid form, onto moving particles, a normally liquid or pasty nonionic detergent, such as a higher fatty alcohol polyethylene oxide condensation product, which penetrates the sodium tripolyphosphate particles and adheres zeolite particles to the surfaces thereof.
摘要翻译： 含有不超过8.7％的磷（来自磷酸盐）的自由流动的颗粒重型洗衣洗涤剂由其内部和表面上具有非离子洗涤剂的三聚磷酸钠颗粒组成，其粘附较小颗粒的离子交换沸石 到磷酸盐。 本发明还有一种通过将喷雾干燥的三聚磷酸钠颗粒和较小的沸石颗粒预先混合并与其混合的方法，通过以液体形式喷洒到移动的颗粒，常规液体或糊状非离子洗涤剂上， 例如高级脂肪醇聚氧乙烯缩合产物，其渗透三聚磷酸钠颗粒并将沸石颗粒粘附到其表面。
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14.发明授权High bulk density carbonate-zeolite built heavy duty nonionic laundry detergent 失效高堆积密度碳酸盐 - 沸石制造重型非离子型洗衣粉
公开(公告)号：US4457854A
公开(公告)日：1984-07-03
申请号：US430976
申请日：1982-09-30
摘要： A free flowing phosphate-free high bulk density particulate heavy duty nonionic laundry detergent is comprised of particles of spray dried base beads containing ion exchanging zeolite and sodium carbonate with which is mixed a particulate water soluble sodium silicate and into which is absorbed a nonionic detergent. The product is made by spray drying an aqueous mixture or slurry of the zeolite and carbonate, mixing with the beads produced a water soluble silicate powder such as hydrous sodium silicate of Na.sub.2 O:SiO.sub.2 ratio of about 1:2 and mixing nonionic detergent in liquid form with the mixture of spray dried base beads and silicate powder and absorbing the nonionic detergent into said mixture.
摘要翻译： 自由流动的无磷酸盐的高堆积密度颗粒重垢型非离子洗衣洗涤剂由含有离子交换沸石和碳酸钠的喷雾干燥的基础颗粒的颗粒组成，与颗粒状水溶性硅酸钠混合并吸收其中的非离子洗涤剂。 该产品通过喷雾干燥沸石和碳酸盐的水性混合物或浆料制成，与珠粒混合产生水溶性硅酸盐粉末，例如Na 2 O:SiO 2比例为约1:2的含水硅酸钠，并混合液体形式的非离子洗涤剂 与喷雾干燥的基础珠和硅酸盐粉末的混合物，并将非离子洗涤剂吸收到所述混合物中。
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公开(公告)号：US4450085A
公开(公告)日：1984-05-22
申请号：US370850
申请日：1982-04-22
申请人： Harold E. Wixon
发明人： Harold E. Wixon
IPC分类号： C11D1/14 , C11D1/62 , C11D1/72 , C11D3/00 , C11D3/22 , C11D10/04 , C11D9/10 , C11D13/18 , D06M13/48
摘要： The present invention provides heavy duty detergent compositions, particularly for imparting improved softness and detersive effects to fabrics laundered therewith, said composition including in addition to conventional builder and principally anionic surfactant components, cationic softener of the di-lower-di-higher alkyl quaternary ammonium and/or heterocyclic imide type, e.g. imidazolinium, and a mixture of fatty acid soap, nonionic organic surfactant, and magnesium sulfate, the weight ratio of soap to softener being about 8:1 to 1:3 preferably 5:1 to 1:2, more preferably 3:2:2:3, e.g., about unity. The soap-nonionic surfactant magnesium sulfate mixture is in the form of a spaghetti, flake, or other shape and is present in the product composition as substantially homogeneously dispersed, discrete particles. A process of laundering fabrics using the above-mentioned composition is also disclosed.
摘要翻译： 本发明提供重垢洗涤剂组合物，特别是用于赋予对其洗涤的织物提高的柔软度和去污效果，所述组合物除了常规助洗剂和主要是阴离子表面活性剂组分外，还包括二低级二高级烷基季铵盐的阳离子软化剂 和/或杂环酰亚胺类型，例如 咪唑啉鎓和脂肪酸皂，非离子有机表面活性剂和硫酸镁的混合物，皂与软化剂的重量比为约8:1至1:3，优选5:1至1:2，更优选3:2:2 ：3，例如关于团结。 皂 - 非离子表面活性剂硫酸镁混合物是意大利面，薄片或其他形状的形式，并且作为基本上均匀分散的离散颗粒存在于产品组合物中。 还公开了使用上述组合物洗涤织物的方法。
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公开(公告)号：US4411803A
公开(公告)日：1983-10-25
申请号：US360642
申请日：1982-03-22
申请人： Harold E. Wixon
发明人： Harold E. Wixon
IPC分类号： C11D1/14 , C11D1/62 , C11D1/72 , C11D3/00 , C11D3/22 , C11D10/04 , C11D1/86 , C11D17/06 , D06M13/48
摘要： The present invention provides heavy duty detergent compositions, particularly for imparting improved softness and detersive effects to fabrics laundered therewith, said composition including in addition to conventional builder and principally anionic surfactant components, cationic softener of the di-lower-di-higher alkyl quaternary ammonium and/or heterocyclic imide type, e.g., imidazolinium, and a mixture of fatty acid soap and nonionic organic surfactant, the weight ratio of soap to softener being about 8:1 to 1:3 preferably 5:1 to 1:2, more preferably 3:2:2:3, e.g., about unity. The soap nonionic surfactant mixture is in the form of a spaghetti, flake, or other shape and is present in the product composition as substantially homogeneously dispersed, discrete particles. A process of laundering fabrics using the above-mentioned composition is also disclosed.
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17.发明授权High bulk density carbonate-zeolite built heavy duty nonionic laundry detergent 失效高堆积密度碳酸盐 - 沸石制造重型非离子型洗衣粉
公开(公告)号：US4406808A
公开(公告)日：1983-09-27
申请号：US384994
申请日：1982-06-04
CPC分类号： C11D3/128 , C11D1/72 , C11D17/065 , C11D3/10
摘要： A free flowing, phosphate free high bulk density particulate heavy duty laundry detergent is prepared by spray-drying an aqueous slurry of ion-exchanging detergent building zeolite particles, sodium carbonate and sodium silicate which has been sheared to reduce the viscosity thereof, followed by mixing nonionic detergent in liquid form with the spray-dried base beads to absorb the detergent into the beads.
摘要翻译： 通过喷雾干燥已经剪切以降低其粘度的离子交换洗涤剂建筑沸石颗粒，碳酸钠和硅酸钠的水性浆料，然后混合，制备自由流动的，无磷酸盐的高堆积密度颗粒重垢洗衣洗涤剂 液体形式的非离子洗涤剂与喷雾干燥的基础珠子一起将洗涤剂吸收到珠粒中。
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公开(公告)号：US4339335A
公开(公告)日：1982-07-13
申请号：US134558
申请日：1980-03-27
申请人： Harold E. Wixon
发明人： Harold E. Wixon
CPC分类号： C11D1/72 , C11D17/0039 , C11D17/065 , C11D3/001 , C11D3/128
摘要： A free flowing, particulate detergent-softener of high bulk density is comprised of nucleus particles of builder salt, preferably a mixture of sodium carbonate and sodium bicarbonate, having nonionic detergent in the interior and on the surface thereof, to which is adhered a coating of smaller particles of ion exchanging zeolite, and quaternary ammonium halide fabric softening compound. In a preferred embodiment of the invention the quaternary ammonium halide is "insulated" from immediate contact with laundry when the detergent-softener is added to the wash water by being added to the nucleus particles with the nonionic detergent, after which the resulting particles are coated with the zeolite powder. In another embodiment of the invention the product described is further coated with nonionic detergent and zeolite.
摘要翻译： 自由流动的高堆积密度的微粒洗涤剂 - 软化剂由助洗剂盐的核颗粒，优选碳酸钠和碳酸氢钠的混合物组成，在其内部和表面上具有非离子洗涤剂，其中附着有 较小的离子交换沸石颗粒和季铵卤化物织物柔软化合物。 在本发明的一个优选实施方案中，当洗涤剂 - 软化剂通过用非离子型洗涤剂加入到核颗粒中而将洗涤剂 - 软化剂加入洗涤水中时，季铵卤化物“与绝缘”与衣物立即接触，然后将所得颗粒涂布 与沸石粉末。 在本发明的另一个实施方案中，所描述的产品进一步用非离子洗涤剂和沸石涂覆。
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公开(公告)号：US4329237A
公开(公告)日：1982-05-11
申请号：US201168
申请日：1980-10-27
申请人： Harold E. Wixon
发明人： Harold E. Wixon
IPC分类号： C11D1/14 , C11D1/62 , C11D1/72 , C11D3/00 , C11D3/22 , C11D10/04 , C11D1/86 , C11D17/06 , D06M13/48
摘要： The present invention provides heavy duty detergent compositions, particularly for imparting improved softness and detersive effects to fabrics laundered therewith, said composition including in addition to conventional builder and principally anionic surfactant components, cationic softener of the di-lower-di-higher alkyl quaternary ammonium and/or heterocyclic imide type, e.g., imidazolinium, and a mixture of fatty acid soap and nonionic organic surfactant, the weight ratio of soap to softener being about 8:1 to 1:3 preferably 5:1 to 1:2, more preferably 3:2:2:3, e.g., about unity. The soap nonionic surfactant mixture is in the form of a spaghetti, flake, or other shape and is present in the product composition as substantially homogeneously dispersed, discrete particles. A process of laundering fabrics using the above-mentioned composition is also disclosed.
摘要翻译： 本发明提供重垢洗涤剂组合物，特别是用于赋予对其洗涤的织物提高的柔软度和去污效果，所述组合物除了常规助洗剂和主要是阴离子表面活性剂组分外，还包括二低级二高级烷基季铵盐的阳离子软化剂 和/或杂环酰亚胺类型，例如咪唑啉，以及脂肪酸皂和非离子有机表面活性剂的混合物，皂与软化剂的重量比为约8:1至1:3，优选5:1至1:2，更优选 3：2：2：3，例如关于统一。 皂非离子表面活性剂混合物是意大利面，薄片或其他形状的形式，并且作为基本上均匀分散的离散颗粒存在于产品组合物中。 还公开了使用上述组合物洗涤织物的方法。
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公开(公告)号：US4183815A
公开(公告)日：1980-01-15
申请号：US905622
申请日：1978-05-15
摘要： Laundry detergent compositions containing halloysite, kyanite or mixtures of these with each other or with metakaolin or bentonite. Compositions preferably contain a quaternary ammonium fabric softener.
摘要翻译： 含有多水高岭土，蓝晶石或它们彼此的混合物或与偏高岭土或膨润土混合的洗衣洗涤剂组合物。 组合物优选含有季铵织物柔软剂。
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