Chiral smectic liquid crystal device having fluorine-containing
polymeric alignment film with predetermined refractive index anisotropy
after rubbing
    15.
    发明授权
    Chiral smectic liquid crystal device having fluorine-containing polymeric alignment film with predetermined refractive index anisotropy after rubbing 失效
    具有摩擦后具有预定折射率各向异性的含氟聚合物取向膜的手性近晶液晶装置

    公开(公告)号:US5576864A

    公开(公告)日:1996-11-19

    申请号:US429017

    申请日:1995-04-26

    IPC分类号: G02F1/1337 G02F1/141

    摘要: A liquid crystal device is constituted by a pair of substrates, and a liquid crystal disposed between the substrates. At least one of the substrates has thereon an alignment film. The alignment film is characterized in that (1) it has a surface energy of at most 35 dyne/cm before rubbing and has been rubbed to have a refractive index anisotropy of at least 0.02, or (2) it has been rubbed to have a surface energy difference .DELTA.E of at least 9 dyne/cm and a difference .DELTA..delta. in dispersion term of the surface energy of at least 6 dyne/cm between before and after the rubbing. The alignment film is effective in providing a high contrast and decreasing a delay in optical response causing after-image.

    摘要翻译: 液晶装置由一对基板和设置在基板之间的液晶构成。 至少一个基板上具有取向膜。 取向膜的特征在于,(1)在摩擦前具有至多35达因/厘米的表面能,并且已经被摩擦以具有至少0.02的折射率各向异性,或(2)已被摩擦以具有 至少9达因/厘米的表面能差ΔTA和摩擦前后至少6达因/厘米的表面能的色散项的差ΔTA。 取向膜有效地提供高对比度并减少导致后图像的光学响应的​​延迟。

    Liquid crystal device
    17.
    发明授权
    Liquid crystal device 失效
    液晶装置

    公开(公告)号:US5510159A

    公开(公告)日:1996-04-23

    申请号:US214428

    申请日:1994-03-18

    IPC分类号: C08G73/10 G02F1/1337

    摘要: A liquid crystal device is constituted by a pair of substrates each provided with a transparent electrode, and a liquid crystal disposed between the substrates; at least one of said pair of substrates having thereon an alignment film comprising (i) a polyimide including principally a recurring unit of the following structural formula (I): ##STR1## wherein R.sub.11 denotes a tetravalent organic group, and R.sub.12 and R.sub.13 denote the same or different alkyl or perfluoroalkyl groups having 1-10 carbon atoms, and also at most 20 mol. % of a recurring monoamine unit of the following structural formula (II): ##STR2## wherein R.sub.21 and R.sub.22 denote the same or different alkyl or perfluoroalkyl groups having 1-10 carbon atoms, and X denotes an aromatic group, a heterocyclic group or a derivative group thereof; or (ii) a polyimide obtained through a reaction of at least two species of tetracarboxylic anhydrides of the following formula (III): ##STR3## wherein R.sub.31 denotes a tetravalent organic group, and a diamine of the following formula (IV): ##STR4## wherein R.sub.41 and R.sub.42 denote the same or different alkyl or perfluoroalkyl groups having 1-10 carbon atoms.

    摘要翻译: 液晶装置由分别设置有透明电极的一对基板和设置在基板之间的液晶构成, 所述一对衬底中的至少一个具有取向膜,所述取向膜包含(i)主要包含以下结构式(I)的重复单元的聚酰亚胺:其中R 11表示四价有机基团,R 12和 R13表示相同或不同的具有1-10个碳原子,最多20mol的烷基或全氟烷基。 %结构式(II)的重复单胺单元:其中R 21和R 22表示具有1-10个碳原子的相同或不同的烷基或全氟烷基,X表示芳族基团,杂环基 基团或其衍生基团; 或(ii)通过至少两种下列通式(III)的四羧酸酐的有机基团反应获得的聚酰亚胺和下式(Ⅳ)的二胺:其中R41和 R42表示具有1-10个碳原子的相同或不同的烷基或全氟烷基。