Abstract:
The invention relates to a method of making fuel cell devices. Anode and cathode layers are applied on respective first and opposing second sides of a first portion of a first green ceramic layer, and a second green ceramic layer of thickness approximately equal to that of the anode and cathode layers is applied on a second portion of each of the first and second sides of the first green ceramic layer. A sacrificial layer is applied over each of the anode, cathode and second green ceramic layers, and a third green ceramic layer is applied over the sacrificial layers. The layered structure is heated to sinter all the layers and burn out the sacrificial layers. A pair of gas passages is thus formed with a thick sintered ceramic therebetween as a passive supporting portion and an anode, thin electrolyte and cathode therebetween as an active portion of the device.
Abstract:
The present invention relates to a method of making fuel cell devices. A stack structure is formed having plural ceramic layers, anode layers, cathode layers, and sacrificial layers, where the sacrificial layers are sized to provide internal gas passages. Removable structures are placed in contact with the sacrificial layers and extend to an edge. After laminating the stacked structure, the removable structures are pulled out to form bake-out paths that facilitate removal of the sacrificial material during a heating step, which paths are later sealed.
Abstract:
A fuel cell device is provided in which the gas input passages are separate from the exhaust gas passages to provide better flow of reactants through the pores of the electrodes. First and second porous electrodes are separated by an electrolyte layer that is monolithic with a solid ceramic support structure for the device. First and second input passages extend within the respective electrodes, within the electrolyte layer, and/or at the surfaces that form the interface between the respective electrodes and the electrolyte layer. First and second exhaust passages are spaced apart from the input passages, and extend within the respective electrodes and/or at a surface thereof opposite the interface surface with the electrolyte layer. Gases are adapted to flow through the respective input passages, then through the pores of the porous electrodes, and then through the respective exhaust passages.
Abstract:
A monolithic or essentially monolithic single layer capacitor with high structural strength and capacitance, a printed circuit board having the capacitor mounted thereon, and a method of making. Sheets of green-state ceramic dielectric material and glass/metal composite material are laminated together, diced into individual chips, and fired to sinter the glass and the ceramic together. The composite material contains an amount of metal sufficient to render the composite conductive whereby the composite may be used for one or both electrodes and for mounting the capacitor to the printed circuit board. Vertically-oriented surface mountable capacitors and hybrid capacitors are provided.
Abstract:
The invention provides solid oxide fuel cell devices and a fuel cell system incorporating a plurality of the fuel devices, each device including an elongate substrate having a reaction zone for heating to an operating reaction temperature, and at least one cold zone that remains at a low temperature below the operating reaction temperature when the reaction zone is heated. An electrolyte is disposed between anodes and cathodes in the reaction zone, and the anode and cathode each have an electrical pathway extending to an exterior surface in a cold zone for electrical connection at low temperature. In one embodiment, the device is a multi-layer anode-cathode structure, and in another embodiment, the device is an electrode-supported device. The system further includes the devices positioned with their reaction zones in a hot zone chamber and their cold zones extending outside the hot zone chamber. A heat source is coupled to the hot zone chamber to heat the reaction zones to the operating reaction temperature, and fuel and air supplies are coupled to the substrates in the cold zones.
Abstract:
A monolithic capacitor structure includes opposed and overlapping plates within a dielectric body, which are arranged to form a lower frequency, higher value capacitor. Other conductive structure is located either inside the dielectric body or on an external surface thereof and is effective to form a higher frequency, lower value capacitor in parallel with the lower frequency, higher value capacitor. The resulting array of combined series and parallel capacitors integral with the dielectric body provides effective wideband performance in an integrated, cost-effective structure.
Abstract:
A monolithic capacitor structure includes opposed and overlapping plates within a dielectric body, which are arranged to form a lower frequency, higher value capacitor. Other conductive structure is located either inside the dielectric body or on an external surface thereof and is effective to form a higher frequency, lower value capacitor in parallel with the lower frequency, higher value capacitor. The resulting array of combined series and parallel capacitors integral with the dielectric body provides effective wideband performance in an integrated, cost-effective structure.
Abstract:
A ceramic capacitor typically 10 mils to 340 mils square by typically 4-20 mils thickness with areas of metallization, or pads, to which electrical connections may be made on, typically, each of two opposite exterior surfaces, has embedded at least one, and normally two or more, metallization planes at close, typically 0.5 mil, separation. Each interior metallization plane connects through multiple redundant vias, as are preferably made by (ii) punching, (ii) drilling, (iii) laser drilling, or (iv) radiation patterning of a green ceramic sheet having a photosensitive binder, to an associated surface pad or trace. The vias are both numerous and redundant, typically being of 2 mil diameter on 10 mil centers in a pin grid array pattern over and through entire ceramic layers of the capacitor, permitting both (i) easy fabrication without exacting alignment or registration between layers, and (ii) low Equivalent Series Resistance (ESR) in the finished capacitor. The composite structure so created exhibits increased capacitance over that which would alternatively exist should no electrically-connected interior metallization planes be present.
Abstract:
A fuel cell device is provided having an active structure with an anode and cathode in opposing relation with an electrolyte therebetween, a fuel passage adjacent the anode for supplying fuel to the active structure, and an air passage adjacent the cathode for supplying air to the active structure. A porous ceramic layer is positioned between each of the anode and fuel passage and the cathode and air passage, the porous ceramic layers having a porosity configured to permit transport of fuel and air from the respective fuel and air passage to the respective anode and cathode. An inactive surrounding support structure is provided that is monolithic with the electrolyte and the porous ceramic layers, wherein the inactive surrounding support structure lacks the anode and cathode in opposing relation and the active structure resides within the inactive surrounding support structure.
Abstract:
A fuel cell device with a rectangular solid ceramic substrate extending in length between first and second end surfaces where thermal expansion occurs primarily along the length. An active structure internal to the exterior surface extends along only a first portion of the length and has an anode, cathode and electrolyte therebetween. The first portion is heated to generate a fuel cell reaction. A remaining portion of the length is a non-heated, non-active section lacking opposing anode and cathode where heat dissipates along the remaining portion away from the first portion. A second portion of the length in the remaining portion is distanced away from the first portion such that its exterior surface is at low temperature when the first portion is heated. The anode and cathode have electrical pathways extending from the internal active structure to the exterior surface in the second portion for electrical connection at low temperature.