Abstract:
Filler which is surface-modified with a compound of the formula [(PG)—R1—Z]n—SP—[Y—R2—(AG)]m, in which AG is —COOH, —P(═O)(OH)2, —O—P(═O)(OH)2, —SO2OH, —SiR3R4X, or a chelating group; R1 is a C1-C3 alkylene group or cyclopropylene group or is absent; R2 is a C1-C10 alkylene group or is absent; R3 is a C1-C8 alkyl group, chlorine or OR5; R4 is a C1-C8 alkyl group, phenyl, chlorine or OR5; R5 is a C1-C6 alkyl group; X is OR5 or chlorine; Y is O, S, CO—NH, O—CO—NH, NH—CO—NH or is absent, Y being absent if R2 is absent; Z is O, S, CO—NR6, O—CO—NH, NH—CO—NH or is absent, R6 being H or C1-C6 alkyl; PG is a radically polymerizable group of the formula in which R9 is H, C1-C3 alkyl, C1-C3 hydroxyalkyl or COOR10; R10 is H, C1-C10 alkyl, 1,6-dimethylphenyl or mesityl; R11 is H or phenyl; m is 1 or 2; n is 1, 2, 3 or 4; SP is absent or is an (n+m)-valent linear or branched aliphatic C1-C30 radical, in which the carbon chain can be interrupted by O, S, CO—NH, O—CO—NH or NH—CO—NH, an (n+m)-valent aromatic C6-C18 radical, an (n+m)-valent cycloaliphatic C3-C18 radical or an (n+m)-valent heterocyclic C3-C18 radical, where the radicals can be substituted or unsubstituted; in which, if AG is a silyl radical of the formula —SiR3R4X and PG is a vinyl group of the formula H2C═CH—, R1 and Z are not absent simultaneously.
Abstract:
The invention relates to a method for removing water from a mixture containing at least one compound having at least one group reactive towards isocyanate and containing water, the mixture being applied to the surface of a rotating body A, the mixture flowing over the surface of the rotating body A to an outer region of the surface of the rotating body A and water evaporating from the mixture. In particular, this method is suitable for removing water from alcohols and amines.
Abstract:
The invention relates to a process for preparing multimetal cyanide compounds by reacting the aqueous solution of a metal salt a) with the aqueous solution of a hexacyanometalate compound b), wherein the mixture of the solutions a) and b) flows over the surface of a rotating body A to an outer region of the surface of the rotating body A and is flung off from there.
Abstract:
The proposed spinning disc reactor comprises substantially a horizontally rotatable, disc-like and thermostatable support element which has an outer reaction surface, feed means for feeding at least one reactant onto the reaction surface and internal structures for thermostating the reaction surface. In addition, it contains at least one separation apparatus for collecting and removing the reaction product from the reaction surface. The support element is characterized in particular in that it consists of two components a) and b) arranged horizontally one on top of the other and having substantially identical surface measures. These two components are connected to one another in an interlocking manner and tightly during the operating time and the lower component a) has, on its top facing the inner region of the support element, at least one substantially uninterrupted groove milled in over an extensive area and intended for receiving, conducting and discharging a heat-transfer fluid. In addition, it has at least two bores for feeding and discharging the heat-transfer fluid, at least one profiled seal encircling the outer surface region being arranged between the component a) and the component b). The two components a) and b) as a whole are reversibly connected to one another. As a result of such specific features, a simply designed reactor which is advantageous with respect to maintenance, is versatile and permits targeted control of the chemical reaction on its rotating surface is present.
Abstract:
Polymerizable materials which contain (1) 1 to 80 wt.-% of at least one polysiloxane, (2) 0.1 to 5 wt.-% of one or more initiators for radical polymerization, (3) 0 to 60 wt.-% of radically polymerizable monomer and (4) 1 to 50 wt.-% of one or more radically polymerizable monomers which carry at least phosphonic acid group, sulphonic acid group and/or mono- or dihydrogen phosphoric acid ester group, the polysiloxane (1), the monomer (3) or both being substituted by fluorine. The materials are suitable in particular for the coating of natural or artificial teeth.
Abstract:
The invention relates to a composition comprising (A) at least 5% by weight of en organic prepolymer P having at least two water-crossilnkable organosilicon end groups, (B) 0.01% to 3.0% by weight of boric acid and/or bone ester, and (C) 0.01% to 3.0% by weight of an amine component. Additionally disclosed is a method for the curing of these compositions and also the use of boric acid and/or boric esters and an amine component a condensation catalyst.
Abstract:
A filler which is surface-modified with a compound of the formula [(PG)-R1—Z]n—SP—[Y—R2-(AG)]m is particularly suitable for use in dental materials, for the preparation of adhesives, coatings and composites.
Abstract:
Filler based on glass particles which contain a homo- or copolymer of vinyl chloride on the surface, process for its preparation and its use as a dental material.
Abstract:
The present invention relates to a curable dental material having adjustable translucence and high opalescence containing I. at least one monomer or one monomer mixture having a refractive index of