Surface-modified cyanide-based transition metal compounds
    3.
    发明授权
    Surface-modified cyanide-based transition metal compounds 有权
    表面改性氰化物基过渡金属化合物

    公开(公告)号:US09359219B1

    公开(公告)日:2016-06-07

    申请号:US14880010

    申请日:2015-10-09

    IPC分类号: C01C3/11 C01C3/12

    摘要: A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition. The composition, compound, device, and uses thereof according to AxMn(y-k)Mjk[Mnm(CN)(6-p-q)(NC)p(Che)rq]z. (Che)rw(Vac)(1-z).nH2O (wherein Vac is a Mn(CN)(6-p-q)(NC)p(Che)rq vacancy); wherein Che is an acid chelating agent; wherein: A=Na, K, Li; and M=Mg, Al, Ca, Sc, Ti, V, Cr, Fe, Co, Ni, Cu, Zn, Ga, Pd, Ag, Cd, In, Sn, Pb; and wherein 0

    摘要翻译: 用于表面改性的过渡金属氰化物配位化合物(TMCCC)组合物的系统,方法和制品,包含该组合物的改进的电极及其组合物的制造方法。 根据AxMn(y-k)Mjk [Mnm(CN)(6-p-q)(NC)p(Che)rq] z的组成,化合物,器件及其用途。 (Che)rw(Vac)(1-z).nH 2 O(其中Vac是Mn(CN)(6-p-q)(NC)p(Che)rq空位); 其中Che是酸螯合剂; 其中:A = Na,K,Li; 并且M = Mg,Al,Ca,Sc,Ti,V,Cr,Fe,Co,Ni,Cu,Zn,Ga,Pd,Ag,Cd,In,Sn,Pb; 并且其中0

    Surface-modified cyanide-based transition metal compounds
    4.
    发明授权
    Surface-modified cyanide-based transition metal compounds 有权
    表面改性氰化物基过渡金属化合物

    公开(公告)号:US09299981B1

    公开(公告)日:2016-03-29

    申请号:US14755607

    申请日:2015-06-30

    摘要: A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition. The composition, compound, device, and uses thereof according to AxMn(y-k)Mjk[Mnm(CN)(6-p-q)(NC)p(Che)rq]z.(Che)rw(Vac)(1-z).nH2O (wherein Vac is a Mn(CN)(6-p-q)(NC)p(Che)rq vacancy); wherein Che is an acid chelating agent; wherein: A=Na, K, Li; and M=Mg, Al, Ca, Sc, Ti, V, Cr, Fe, Co, Ni, Cu, Zn, Ga, Pd, Ag, Cd, In, Sn, Pb; and wherein 0

    摘要翻译: 用于表面改性的过渡金属氰化物配位化合物(TMCCC)组合物的系统,方法和制品,包含该组合物的改进的电极及其组合物的制造方法。 根据AxMn(yk)Mjk [Mnm(CN)(6-pq)(NC)p(Che)rq] z。(Che)rw(Vac)(1-z)的组合物,化合物, (其中Vac是Mn(CN)(6-pq)(NC)p(Che)rq空位); 其中Che是酸螯合剂; 其中:A = Na,K,Li; 并且M = Mg,Al,Ca,Sc,Ti,V,Cr,Fe,Co,Ni,Cu,Zn,Ga,Pd,Ag,Cd,In,Sn,Pb; 并且其中0

    Preparation of nanosized copper (I) compounds
    7.
    发明授权
    Preparation of nanosized copper (I) compounds 失效
    纳米尺寸铜(I)化合物的制备

    公开(公告)号:US07700796B2

    公开(公告)日:2010-04-20

    申请号:US10413754

    申请日:2003-04-16

    IPC分类号: C01G3/05

    摘要: A method of making nanosized copper (I) compounds, in particular, copper (I) halides, pseudohalides, and cyanocuprate complexes, in reverse micelles or microemulsions is disclosed herein. The method of the invention comprises (a) dissolving a copper (II) compound in the polar phase of a first reverse micelle or microemulsion, (b) dissolving a copper (II) to copper (I) reducing agent or a pseudohalide salt in the polar phase of a second sample of the same reverse micelle or microemulsion, (c) mixing the two reverse micelle/microemulsions samples to form nanometer sized copper (I) compounds and (d) recovering said nanometer sized copper (I) compounds. The present invention is also directed to the resultant nanosized copper (I) compounds, such as copper (I) chloride, copper (I) cyanide, and potassium cyanocuprate complexes having an average particle size of about 0.1 to 600 nanometers.

    摘要翻译: 本文公开了一种在反胶束或微乳液中制备纳米尺寸铜(I)化合物,特别是卤化铜(I),拟卤化物和氰基偶联物络合物的方法。 本发明的方法包括(a)将铜(II)化合物溶解在第一反胶束或微乳液的极性相中,(b)将铜(II)溶解在铜(I)还原剂或拟卤化物盐中, 相同反胶束或微乳液的第二样品的极性相,(c)混合两个反胶束/微乳液样品以形成纳米尺寸的铜(I)化合物和(d)回收所述纳米尺寸的铜(I)化合物。 本发明还涉及所得到的纳米尺度铜(I)化合物,例如氯化铜(I),氰化铜(I)和平均粒度约为0.1至600纳米的氰基钴酸钾配合物。

    Catalyst
    9.
    发明授权
    Catalyst 失效
    催化剂

    公开(公告)号:US3948803A

    公开(公告)日:1976-04-06

    申请号:US473628

    申请日:1974-05-28

    申请人: Robert L. Carney

    发明人: Robert L. Carney

    IPC分类号: B01J27/26 C01C3/11

    CPC分类号: B01J27/26 C01C3/11

    摘要: Catalyst compositions comprising a compound of the formula MX(CuCN).sub.n, wherein M is lithium or magnesium, X is chloro, bromo, or iodo and n is one, two or three, in solution in a solvent selected from e.g. tetrahydrofuran, tetrahydropyran and diethyl ether are useful in reactions for the alkylation of a Grignard reagent by an organic halide or an organic sulfonate ester.

    摘要翻译: 催化剂组合物,其包含式MX(CuCN)n的化合物,其中M为锂或镁,X为氯,溴或碘,n为1,2或3个, 四氢呋喃,四氢吡喃和二乙醚可用于通过有机卤化物或有机磺酸酯烷基化格利雅试剂的反应。