公开(公告)号：US20190040260A1

公开(公告)日：2019-02-07

申请号：US16076383

申请日：2017-02-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Christoph Schuell ,  Christiane Strerath ,  Naiyong Jing ,  Siegfried Goeb

IPC: C08L101/08 ,  C08L101/10 ,  C08L101/04 ,  C08L101/02 ,  C08L101/14 ,  C08F230/02

Abstract: The present disclosure relates to an amphiphilic copolymer comprising: a) repeating monomeric units comprising a pendant zwitterionic moiety; b) repeating monomeric units comprising a pendant group comprising a fluorine-containing group and at least one heteroatom; and c) optionally, secondary repeating monomeric units comprising a pendant group comprising a functional group selected from the group consisting of phosphate groups, phosphonate groups, sulfonate groups, alkoxysilane groups, carboxylate groups, and any combinations thereof; and wherein the repeating monomeric units of the amphiphilic copolymer independently comprise an ethylenically unsaturated polymerizable group selected from the group of (meth)acrylate ester containing groups. In another aspect, the present disclosure is directed to a protective coating composition comprising: a) an amphiphilic co polymer as described above, and b) a solvent comprising water.

公开(公告)号：US20150232673A1

公开(公告)日：2015-08-20

申请号：US14428702

申请日：2013-09-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Naiyong Jing ,  Christiane Strerath ,  Fuxia Sun ,  Justin A. Riddle ,  Xuan Jiang ,  Xue-hua Chen

IPC: C09D5/16

CPC classification number: C09D5/1618 ,  C09D1/00 ,  C09D5/16

Abstract: A method of making a coatable composition includes: a) providing a initial composition comprising silica nanoparticles dispersed in an aqueous liquid medium, wherein the silica nano articles have a particle size distribution with an average particle size of less than or equal to 100 nanometers, and wherein the silica sol has a pH greater than 6; b) acidifying the initial composition to a pH of less than or equal to 4 using inorganic acid to provide an acidified composition; and c) dissolving at least one metal compound in the acidified composition to provide a coatable composition. Coatable compositions and soil-resistant compositions, preparable by the method, are also disclosed. Soil-resistant articles including the soil-resistant compositions are also disclosed.

Abstract translation: 制备可涂覆组合物的方法包括：a）提供包含分散在水性液体介质中的二氧化硅纳米颗粒的初始组合物，其中所述二氧化硅纳米制品具有平均粒度小于或等于100纳米的粒度分布，以及 其中所述硅溶胶的pH大于6; b）使用无机酸将初始组合物酸化至pH小于或等于4，以提供酸化组合物; 和c）将至少一种金属化合物溶解在酸化的组合物中以提供可涂覆的组合物。 还公开了可通过该方法制备的可涂敷组合物和抗土组合物。 还公开了包括耐土壤组合物的耐土壤制品。

公开(公告)号：US20150203790A1

公开(公告)日：2015-07-23

申请号：US14419076

申请日：2013-08-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Christiane Strerath ,  Naiyong Jing ,  Yifan Zhang ,  Michelle Legatt ,  Diane Wolk

IPC: C11D1/12 ,  C11D3/08 ,  B08B17/02 ,  C09D133/02

CPC classification number: C11D1/123 ,  B08B17/02 ,  B08B17/065 ,  C08K3/36 ,  C08K9/04 ,  C08K9/06 ,  C09D5/1618 ,  C09D7/62 ,  C09D133/02 ,  C11D3/08

Abstract: This invention relates to coating compositions useful for the prevention and/or removal of limescale and/or soap scum. More specifically, the present invention is directed to a coating composition comprising acidified silica nanoparticles and a sulfonated polymer. The present invention is further directed to a method for the prevention and/or removal of limescale and/or soap scum from the surface of a substrate. The invention also relates to the use of such a coating composition for the prevention and/or removal of limescale and/or soap scum from the surface of a substrate.

Abstract translation: 本发明涉及可用于预防和/或去除石灰垢和/或肥皂浮渣的涂料组合物。 更具体地，本发明涉及包含酸化二氧化硅纳米颗粒和磺化聚合物的涂料组合物。 本发明进一步涉及一种从基材表面预防和/或去除石灰垢和/或皂垢的方法。 本发明还涉及这种涂料组合物用于从基材表面防止和/或除去石灰垢和/或皂垢的用途。

公开(公告)号：US20140367040A1

公开(公告)日：2014-12-18

申请号：US14344800

申请日：2012-09-24

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Steffen Traser ,  Jan D. Forster ,  Christiane Strerath ,  Jayshree Seth ,  Arlin L. Weikel ,  Maureen A. Kavanagh ,  Jason D. Clapper ,  Kevin M. Lewandowski ,  Zhong Chen

IPC: C09J7/02

Abstract: The present invention is directed to a multilayer pressure sensitive adhesive (PSA) film, having a first pressure sensitive adhesive layer and at least an opposing layer, wherein the first pressure sensitive adhesive layer comprises a pressure-sensitive adhesive composition with a (meth)acrylic-based elastomeric material comprising a reaction product of polymerizable material comprising: (a) a first monomer which is an alkyl (meth)acrylate ester of a primary alcohol R1—OH, the alkyl (meth)acrylate ester being of Formula (I) CH2═C(R2)—(CO)—OR1 (I) wherein R1 is an alkyl having 14 to 25 carbon atoms and the primary alcohol R1—OH has an iso index equal to at least 2 but no greater than 4; R2 is hydrogen or methyl; and (b) a second monomer having an ethylenically unsaturated group; wherein the at least one opposing layer comprises at least one filler material. The invention is also directed to a method for the manufacturing of such a multilayer PSA film and its use.

Abstract translation: 本发明涉及具有第一压敏粘合剂层和至少相对层的多层压敏粘合剂（PSA）膜，其中第一压敏粘合剂层包含具有（甲基）丙烯酸类的压敏粘合剂组合物 其包含可聚合材料的反应产物，其包含：（a）第一单体，其为伯醇R 1 -OH的（甲基）丙烯酸烷基酯，（I）（甲基）丙烯酸烷基酯 ≡C（R2） - （CO）-OR1（Ⅰ）其中R1是具有14-25个碳原子的烷基，伯醇R1-OH具有等于至少2但不大于4的iso指数; R2是氢或甲基; 和（b）具有烯属不饱和基团的第二单体; 其中所述至少一个相对层包括至少一种填料。 本发明还涉及制造这种多层PSA膜的方法及其用途。