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公开(公告)号:US11118274B2
公开(公告)日:2021-09-14
申请号:US16741038
申请日:2020-01-13
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tyler S. Matthews , Steven J. Hamrock , Marina M. Kaplun , Krzysztof A. Lewinski , Sean M. Luopa
Abstract: Described herein is a process for the reduction of carbon dioxide comprising: providing an electrochemical device comprising an anode, a cathode, and a polymeric anion exchange membrane therebetween, wherein the polymeric anion exchange membrane comprises an anion exchange polymer, wherein the anion exchange polymer comprises at least one positively charged group selected from a guanidinium, a guanidinium derivative, an N-alkyl conjugated heterocyclic cation, or combinations thereof; introducing a composition comprising carbon dioxide to the cathode; and applying electrical energy to the electrochemical device to effect electrochemical reduction of the carbon dioxide.
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公开(公告)号:US20210075026A1
公开(公告)日:2021-03-11
申请号:US17047029
申请日:2019-04-11
Applicant: 3M Innovative Properties Company
Inventor: Andrew J. L. Steinbach , Andrew T. Haug , Krzysztof A. Lewinski , Amy E. Hester , Grant M. Thoma , Cedric Bedoya , Zhenhua Zeng , Jeffrey P. Greeley
Abstract: Catalysts comprising a Ta layer having an outer layer with a layer comprising Pt directly thereon, wherein the Ta layer has an average thickness in a range from 0.04 to 30 nanometers, wherein the layer comprising Pt has an average thickness in a range from 0.04 to 50 nanometers, and wherein the Pt and Ta are present in an atomic ratio in a range from 0.01:1 to 10:1. Catalyst described herein are useful, for example, in fuel cell membrane electrode assemblies.
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公开(公告)号:US10570524B2
公开(公告)日:2020-02-25
申请号:US15327404
申请日:2015-08-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tyler S. Matthews , Steven J. Hamrock , Marina M. Kaplun , Krzysztof A. Lewinski , Sean M. Luopa
IPC: C25B3/00 , C25B1/10 , C25B9/10 , C25B13/08 , C25B9/08 , C25B13/02 , C25B1/00 , C25B3/04 , B01J41/13 , C08J5/22
Abstract: Described herein is a process for the reduction of carbon dioxide comprising: providing an electrochemical device comprising an anode, a cathode, and a polymeric anion exchange membrane therebetween, wherein the polymeric anion exchange membrane comprises an anion exchange polymer, wherein the anion exchange polymer comprises at least one positively charged group selected from a guanidinium, a guanidinium derivative, an N-alkyl conjugated heterocyclic cation, or combinations thereof; introducing a composition comprising carbon dioxide to the cathode; and applying electrical energy to the electrochemical device to effect electrochemical reduction of the carbon dioxide.
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公开(公告)号:US20170183789A1
公开(公告)日:2017-06-29
申请号:US15327404
申请日:2015-08-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tyler S. Matthews , Steven J. Hamrock , Marina M. Kaplun , Krzysztof A. Lewinski , Sean M. Luopa
Abstract: Described herein is a process for the reduction of carbon dioxide comprising: providing an electrochemical device comprising an anode, a cathode, and a polymeric anion exchange membrane therebetween, wherein the polymeric anion exchange membrane comprises an anion exchange polymer, wherein the anion exchange polymer comprises at least one positively charged group selected from a guanidinium, a guanidinium derivative, an N-alkyl conjugated heterocyclic cation, or combinations thereof; introducing a composition comprising carbon dioxide to the cathode; and applying electrical energy to the electrochemical device to effect electrochemical reduction of the carbon dioxide.
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公开(公告)号:US11990626B2
公开(公告)日:2024-05-21
申请号:US15733735
申请日:2019-04-11
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Andrew J. L. Steinbach , Andrew T. Haug , Krzysztof A. Lewinski , Amy E. Hester , Grant M. Thoma , Cedric Bedoya
CPC classification number: H01M4/921 , H01M2008/1095
Abstract: Catalyst comprising an Ir layer having an outer layer with a layer comprising Pt directly thereon, wherein the Ir layer has an average thickness in a range from 0.04 to 30 nanometers, wherein the layer comprising Pt has an average thickness in a range from 0.04 to 50 nanometers, and wherein the Pt and Ir are present in an atomic ratio in a range from 0.01:1 to 10:1. Catalysts described herein are useful, for example, in fuel cell membrane electrode assemblies.
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公开(公告)号:US11973232B2
公开(公告)日:2024-04-30
申请号:US17045101
申请日:2019-03-27
Applicant: 3M Innovative Properties Company
Inventor: Andrew J. L. Steinbach , Andrew T. Haug , Amy Hester , Krzysztof A. Lewinski , Sean M. Luopa , Grant M. Thoma , Jonah D. Erlebacher
CPC classification number: H01M4/9058 , C22C5/04 , H01M4/926
Abstract: Nanoporous oxygen reduction catalyst material comprising at least 90 collectively Pt, Ni, and Ta. The nanoporous oxygen reduction catalyst material is useful, for example, in fuel cell membrane electrode assemblies.
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公开(公告)号:US11094953B2
公开(公告)日:2021-08-17
申请号:US15575454
申请日:2016-05-04
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Krzysztof A. Lewinski , Sean M. Luopa
IPC: H01M8/1004 , C25B1/04 , C25B9/23 , C25B9/73 , C25B11/031 , H01M4/88 , H01M4/90 , B82Y40/00
Abstract: Electrode membrane assembly having an oxygen evolution reaction electrodes, the electrode membrane assembly comprising nanostructured whiskers with at least one of metallic Ir or Ir oxide thereon. These oxygen evolution reaction electrodes when paired with suitable hydrogen evolution electrodes are useful, for example, in generating H2 and O2 from water.
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公开(公告)号:US09562872B2
公开(公告)日:2017-02-07
申请号:US14399381
申请日:2013-05-13
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Stefan H. Gryska , Krzysztof A. Lewinski , Michael C. Palazzotto
CPC classification number: G01N27/223 , G01N27/121 , G01N27/126 , G01N27/225
Abstract: A humidity sensor element includes a dielectric substrate, a nonporous conductive electrode disposed on the dielectric substrate, a permeable conductive electrode having a thickness in a range of from 4 to 10 nanometers and permeable by water vapor, and a detection layer disposed between the nonporous conductive electrode and the permeable conductive electrode. Both conductive electrodes have respective conductive leads attached thereto. The detection layer includes a sulfonated copolymer including monomeric units comprising (I) and (II), Wherein x and y are independently integers in the range of from 2 to 6, and wherein each M independently represents H or an alkali metal. A humidity sensor including the humidity sensor element is also disclosed.
Abstract translation: 一种湿度传感器元件,包括电介质基板,设置在电介质基板上的无孔导电电极,厚度在4至10纳米之间且可透过水蒸汽的可渗透导电电极,以及设置在无孔导电 电极和可渗透导电电极。 两个导电电极都有相应的导电引线。 检测层包括包含(I)和(II)的单体单元的磺化共聚物,其中x和y独立地为2至6的整数,并且其中每个M独立地表示H或碱金属。 还公开了一种包括湿度传感器元件的湿度传感器。
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公开(公告)号:US11955645B2
公开(公告)日:2024-04-09
申请号:US17047029
申请日:2019-04-11
Applicant: 3M Innovative Properties Company
Inventor: Andrew J. L. Steinbach , Andrew T. Haug , Krzysztof A. Lewinski , Amy E. Hester , Grant M. Thoma , Cedric Bedoya , Zhenhua Zeng , Jeffrey P. Greeley
CPC classification number: H01M4/9041 , H01M4/8657 , H01M4/9058 , H01M4/92
Abstract: Catalysts comprising a Ta layer having an outer layer with a layer comprising Pt directly thereon, wherein the Ta layer has an average thickness in a range from 0.04 to 30 nanometers, wherein the layer comprising Pt has an average thickness in a range from 0.04 to 50 nanometers, and wherein the Pt and Ta are present in an atomic ratio in a range from 0.01:1 to 10:1. Catalyst described herein are useful, for example, in fuel cell membrane electrode assemblies.
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公开(公告)号:US11560632B2
公开(公告)日:2023-01-24
申请号:US16586574
申请日:2019-09-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jiyoung Park , Krzysztof A. Lewinski , Sean M. Luopa , Andrew J. L. Steinbach
IPC: C25B1/04 , C25B13/08 , C25B9/23 , C25B11/081 , C25B9/73
Abstract: A water electrolyzer comprises a membrane, a cathode and an anode. The membrane comprises a first membrane layer comprising a first ion-conductive polymer, a second membrane layer comprising a second ion-conductive polymer, and a platinized nanostructured layer disposed between the first layer and the second layer. The platinized nanostructured layer comprises close-packed whiskers having at least one of platinum or platinum oxide disposed thereon. The cathode is disposed on the membrane and comprises a first catalyst consisting essentially of both metallic Pt and Pt oxide. The anode is disposed on the opposite surface of the membrane and comprises a second catalyst comprising at least 95 percent by weight of collectively metallic Ir and Ir oxide, calculated as elemental Ir, based on the total weight of the second catalyst, wherein at least one of metallic Ir or Ir oxide is present. Membranes and methods of making them are also disclosed.
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