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公开(公告)号：US4202953A
公开(公告)日：1980-05-13
申请号：US6431
申请日：1979-01-25
摘要： A process for the production of polyolefins using an improved catalyst which exhibits enhanced activity in the polymerization or copolymerization of olefins such that the yields of the polymers or copolymers are increased with a minimum catalyst residue remaining. The catalyst is produced by reacting a magnesium dihalide anhydride with an aluminum alkoxy compound to produce a carrier on which a titanium compound and/or a vanadium compound is applied. The molar ratio of magnesium dihalide to aluminum compound ranges between 1:0.001 to 1:20, and most effectively is in the range of 1:0.05 to 1:5.
摘要翻译： 使用改进的催化剂生产聚烯烃的方法，其在烯烃的聚合或共聚中表现出增强的活性，使得聚合物或共聚物的产率随着剩余的最小催化剂残余物而增加。 该催化剂是通过使二卤化镁酐与一种烷氧基铝化合物反应制得一种其上涂有钛化合物和/或钒化合物的载体。 二卤化镁与铝化合物的摩尔比范围在1:0.001- 1:20之间，最有效地在1:0.05至1:5的范围内。
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公开(公告)号：US4324876A
公开(公告)日：1982-04-13
申请号：US209318
申请日：1980-11-24
CPC分类号： C08F10/00
摘要： A process for the homopolymerization or copolymerization of olefins is disclosed. The process is carried out in the presence of a catalyst system comprising the combination of an organometallic compound with a component resulting from the mutual contact of (i) an inorganic magnesium compound of a spherical shape having an average particle size of from 1 to 100 microns; (ii) a compound represented by the formula AlX.sub.3.OR'R" (where X represents a halogen atom, and R' and R" represent a hydrocarbon residual group having 1 to 20 carbon atoms; and (iii) a titanium compound represented by the formula Ti(OR).sub.4 (where R represents a hydrocarbon residual group having 1 to 20 carbon atoms). The resulting polymers are provided with a spherical particle shape.
摘要翻译： 公开了一种烯烃均聚或共聚合的方法。 该方法在催化剂体系的存在下进行，所述催化剂体系包含有机金属化合物与由（i）平均粒度为1至100微米的球形的无机镁化合物的相互接触所形成的组分的组合 ; （ii）由式AlX3.OR'R“表示的化合物（其中X表示卤素原子，R'和R”表示碳原子数为1〜20的烃残基;（iii）钛化合物 由式Ti（OR）4（其中R表示具有1至20个碳原子的烃残基）表示，所得聚合物具有球形颗粒形状。
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公开(公告)号：US4315999A
公开(公告)日：1982-02-16
申请号：US189823
申请日：1980-09-23
CPC分类号： C08F10/00 , C08F4/022 , C08F2410/04 , Y10S526/906
摘要： An olefin is polymerized using a catalyst obtained by contacting (1) at least one of silicon or aluminum dioxide, (2) a compound of the formula ROH wherein R is a hydrocarbon radical having 1 to 20 carbon atoms, and (3) a substance obtained by supporting a titanium or a vanadium compound on a magnesium or manganese halide.
摘要翻译： 使用通过使（1）硅或二氧化铝中的至少一种与（2）式ROH的化合物（其中R是具有1至20个碳原子的烃基）的化合物和（3）物质 通过在镁或锰卤化物上负载钛或钒化合物获得。
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公开(公告)号：US4093789A
公开(公告)日：1978-06-06
申请号：US705607
申请日：1976-07-15
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/903 , Y10S526/906
摘要： According to the present invention, there is provided a process for preparing polyolefins by polymerizing or copolymerizing olefins in the presence of a catalyst consisting of a solid component and an organometallic compound component, characterized in that said solid component is obtained by copulverizing(1) a magnesium halide and/or a manganese halide,(2) an aromatic hydrocarbon,(3) a tetravalent titanium compound, and(4) a trivalent titanium compoundAnd in that said organometallic compound component is a mixture of(5) a trialkylaluminum and(6) a compound represented by the general formula AlR.sub.n X.sub.3-n wherein R is alkyl having 1 to 10 carbon atoms and may be the same or different, X is halogen and O
摘要翻译： 根据本发明，提供一种通过在由固体成分和有机金属化合物成分组成的催化剂存在下聚合或共聚烯烃制备聚烯烃的方法，其特征在于所述固体组分通过共混（1）A （2）芳族碳氢化合物，（3）四价钛化合物，和（4）多价钛化合物，以及所述有机元素化合物组分是（5）三烯丙基铝和（ 6）由通式AlRnX 3-n表示的化合物，其中R是具有1至10个碳原子的烷基并且可以相同或不同，X是卤素且O
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公开(公告)号：US4083802A
公开(公告)日：1978-04-11
申请号：US706589
申请日：1976-07-19
摘要： A process for the production of polyolefins is disclosed, which is carried out in the presence of catalysts prepared according to the invention. The catalysts comprise a carrier resulting from the reaction of anhydrous magnesium halide, silicon tetrachloride and a compound represented by the general formulaROHwhere R is a hydrocarbon group of 1 to 20 carbon atoms, and a transition metal compound supported on said carrier. Such catalysts are activated by an organometal compound of a metal of the Groups I to IV of the Periodic Table when in use.
摘要翻译： 公开了一种生产聚烯烃的方法，其在根据本发明制备的催化剂的存在下进行。 催化剂包含由无水卤化镁，四氯化硅和通式ROH表示的化合物（其中R是1至20个碳原子的烃基）和负载在所述载体上的过渡金属化合物反应而产生的载体。 这种催化剂在使用时由元素周期表第I至IV族金属的有机金属化合物活化。
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公开(公告)号：US5266666A
公开(公告)日：1993-11-30
申请号：US766749
申请日：1991-09-27
CPC分类号： C08F10/00
摘要： Ethylene and optionally an .alpha.-olefin are polymerized in the presence of a catalyst comprising a solid catalyst component and an organometallic compound, said solid catalyst component being obtained by mutually contacting the following components:(A) a reaction product obtained by the reaction of a magnesium halide and a compound represented by the general formula Ti(OR.sup.1).sub.4 wherein R.sup.1 is a hydrocarbon radical having 1 to 20 carbon atoms;(B) a reaction product obtained by the reaction of an aluminum halide and a compound represented by the general formula Si(OR.sup.2).sub.4 wherein R.sup.2 is a hydrocarbon radical having 1 to 20 carbon atoms; and(C) a compound represented by the following general formula: ##STR1## wherein R.sup.3 and R.sup.5, which may be the same or different, are each a hydrocarbon radical having 1 to 20 carbon atoms, R.sup.4 is a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and m is an integer in the range of 1.ltoreq.m.ltoreq.100, with the proviso that, in the case of m.gtoreq.2, R.sup.4 s may be the same or different.
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公开(公告)号：US4252929A
公开(公告)日：1981-02-24
申请号：US97791
申请日：1979-11-27
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： According to the present invention, there is provided a process for preparing polyolefins comprising polymerizing or copolymerizing olefins using as catalyst a titanium-containing solid and an organometallic compound of a metal of Groups I to IV of the Periodic Table, said titanium-containing solid consisting of a reaction product obtained by copulverizing (1) a magnesium halide and/or a manganese halide, (2) an organohalide and (3) a tetravalent and/or a trivalent titanium compound(s).
摘要翻译： 根据本发明，提供了一种制备聚烯烃的方法，其包括使用含钛固体和周期表第I至IV族金属的有机金属化合物作为催化剂聚合或共聚烯烃，所述含钛固体包括 通过共混（1）卤化镁和/或卤化锰得到的反应产物，（2）有机卤化物和（3）四价和/或三价钛化合物。
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公开(公告)号：US4209601A
公开(公告)日：1980-06-24
申请号：US887008
申请日：1978-03-16
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： The present invention discloses improved catalysts for polymerizing or copolymerizing olefins and a process for the production of polyolefins comprising a polymerization or copolymerization of olefins by the use of said catalysts. According to the invention there is provided a process for the production of polyolefins by polymerizing or copolymerizing olefins using as the catalyst a solid component containing a titanium compound and/or a vanadium compound and an organometallic compound, said solid component comprising a substance obtained by co-pulverizing (1) a metal halide selected from the group consisting of magnesium halides and manganese halides, (2) a compound represented by the general formula B(OR).sub.n X.sub.3-n X3 in which n is a number of the range 0
摘要翻译： 本发明公开了用于聚合或共聚烯烃的改进的催化剂和用于生产聚烯烃的方法，其包括通过使用所述催化剂聚合或共聚烯烃。 根据本发明，提供了一种通过使用作为催化剂使含有钛化合物和/或钒化合物和有机金属化合物的固体组分作为催化剂聚合或共聚烯烃的方法，所述固体组分包含通过共聚物获得的物质 粉碎（1）选自卤化镁和卤化锰的金属卤化物，（2）由通式B（OR）nX3-n X3表示的化合物，其中n是0
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公开(公告)号：US4006101A
公开(公告)日：1977-02-01
申请号：US608898
申请日：1975-08-29
摘要： A process for the production of polyolefins is disclosed, which is carried out in the presence of catalysts prepared according to the invention. The catalysts comprise a carrier resulting from the reaction of anhydrous magnesium halide, silicon tetrachloride and an alcohol represented by the general formulaROHwhere R is an organic group of 1 to 20 carbon atoms, and a titanium and/or a vanadium compound supported on said carrier. Such catalysts are activated by an organoaluminum and/or an organozinc compound when in use.
摘要翻译： 公开了一种生产聚烯烃的方法，其在根据本发明制备的催化剂的存在下进行。 催化剂包含由无水卤化镁，四氯化硅和由通式ROH表示的醇反应得到的载体，其中R是1至20个碳原子的有机基团，并且钛和/或钒化合物负载在所述 载体 当使用时，这种催化剂被有机铝和/或有机锌化合物活化。
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公开(公告)号：US4962167A
公开(公告)日：1990-10-09
申请号：US271108
申请日：1988-11-14
CPC分类号： C08F110/02 , C08F10/02
摘要： A process for preparing an ultra-high molecular weight polyethylene by the polymerization of ethylene using a catalyst comprising a solid catalyst component and an organometallic compound, characterized in that said solid catalyst component is a product obtained by contacting the following [A] and [B] together:[A] the reaction product of a magnesium dihalide and a titanium compound represented by the general formula Ti(OR).sub.4 wherein R is a hydrocarbon group having 1 to 20 carbon atoms;[B] the reaction product of an aluminum trihalide and a silicon compound represented by the general formula Si(OR').sub.4 wherein R' is a hydrocarbon group having 1 to 20 carbon atoms.
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