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11.发明授权Manufacture of polyethers from bis-(4-hydroxyphenyl)-sulfone and bis-(4-chlorophenyl)-sulfone in N-methylpyrrolidone using an alkali metal carbonate as catalysts 失效使用碱金属碳酸盐作为催化剂在N-甲基吡咯烷酮中制备双 - （4-羟基苯基） - 砜和双 - （4-氯苯基） - 砜的聚醚
公开(公告)号：US4200728A
公开(公告)日：1980-04-29
申请号：US912176
申请日：1978-06-05
申请人： Gerd Blinne , Claus Cordes
发明人： Gerd Blinne , Claus Cordes
CPC分类号： C08G65/4093 , C08G75/23
摘要： Polyethers, preferably containing sulfone groups, are obtained by a multi-stage condensation process at from 100.degree. to 230.degree. C. from substantially equivalent amounts of bis-(4-hydroxyphenyl)-sulfone and a dichlorobenzene compound in a polar aprotic solvent in the presence of an anhydrous alkali metal carbonate, with or without the addition of a compound which forms an azeotrope.
摘要翻译： 优选含有砜基的聚醚通过多级缩合方法在100-230℃下从基本上相当量的双 - （4-羟基苯基） - 砜和二氯苯化合物在极性非质子溶剂中获得， 存在无水碱金属碳酸盐，加入或不加入形成共沸物的化合物。
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12.发明授权Manufacture of polyethers from bisphenols and dihalides in the absence of solvent and in the presence of alkali metal carbonate 失效在不存在溶剂和碱金属碳酸盐存在下，从双酚和二卤化物制备聚醚
公开(公告)号：US4200727A
公开(公告)日：1980-04-29
申请号：US952800
申请日：1978-10-19
申请人： Gerd Blinne , Claus Cordes
发明人： Gerd Blinne , Claus Cordes
CPC分类号： C08G65/4093 , C08G65/38
摘要： Polyethers are manufactured by polycondensing about equivalent amounts of a bisphenol and of a dihalogen compound in the presence of an anhydrous alkali metal carbonate, in the absence of a solvent or diluent. The polyethers may be used for the manufacture of moldings, fibers, films, adhesives and coating compositions.
摘要翻译： 在无溶剂或稀释剂存在下，在无水碱金属碳酸盐存在下，将约等量的双酚和二卤化合物缩聚制备聚醚。 聚醚可用于制造模制品，纤维，薄膜，粘合剂和涂料组合物。
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13.发明授权Production of filler-containing thermoplastic molding compositions and molding compositions obtainable in this way 失效生产含有填料的热塑性成型组合物和以这种方式获得的成型组合物
公开(公告)号：US5659009A
公开(公告)日：1997-08-19
申请号：US560518
申请日：1995-11-17
申请人： Gunter Pipper , Walter Goetz , Claus Cordes , Josef Georg Floss , Guenter Mattern , Peter Hildenbrand , James Hurley , Karl Schlichting , Graham Edmund McKee , Gerd Blinne
发明人： Gunter Pipper , Walter Goetz , Claus Cordes , Josef Georg Floss , Guenter Mattern , Peter Hildenbrand , James Hurley , Karl Schlichting , Graham Edmund McKee , Gerd Blinne
摘要： In a process for producing filler-containing thermoplastic molding compositions by mixing fillers with thermoplastics in the melt,a) the fillers are mixed in a mixing apparatus in the melt with a low molecular weight thermoplastic having a melt viscosity of at most 30 Pas (measured at 20.degree. C. above the melting point of the thermoplastic compound and at a shear gradient of 1,000 s.sup.-1),b) the product thus obtained is removed from the mixing apparatus, cooled and comminuted, andc) the comminuted product is then subjected in the solid phase to a post-condensation.
摘要翻译： 在通过在熔体中将填料与热塑性塑料混合来制造含填料的热塑性模塑组合物的方法中，a）将填料与熔体中的混合装置与熔体粘度至多为30Pa·s的低分子量热塑性混合物 在热塑性化合物的熔点以上20℃，剪切梯度为1000s -1），b）将由此得到的产物从混合装置中取出，冷却并粉碎，然后c）粉碎产物 在固相中进行后冷凝。
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公开(公告)号：US5410015A
公开(公告)日：1995-04-25
申请号：US86461
申请日：1993-07-06
申请人： James Hurley , Walter Goetz , Gerd Blinne
发明人： James Hurley , Walter Goetz , Gerd Blinne
CPC分类号： C08K5/13
摘要： Thermoplastic polyamide molding materials contain, as essential components,A) from 39 to 99% by weight of a polyamide or a mixture of different polyamides andB) from 1 to 30% by weight of a phenol of the general formula IR.sub.3 E I and E is a trivalent, aliphatic, C.sub.1 -C.sub.10 -hydrocarbon radical, triazinetriyl or a trivalent C.sub.6 - or C.sub.10 -aryl radical, andc) from 0 to 60% by weight, based on the amount of polyamide, of fibrous or particulate fillers or a mixture thereof.
摘要翻译： 热塑性聚酰胺成型材料作为必要成分含有A）39〜99重量％的聚酰胺或不同聚酰胺的混合物，B）1〜30重量％的通式I R3EI的苯酚和E是 三价，脂族，C 1 -C 10 - 烃基，三嗪三基或三价C 6 - 或C 10 - 芳基，和c）基于聚酰胺的量，0至60重量％的纤维或颗粒填料或混合物 其中。
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公开(公告)号：US5200450A
公开(公告)日：1993-04-06
申请号：US769431
申请日：1991-10-01
申请人： Gerd Blinne , Walter Goetz , James Hurley , Herbert Gutsche , Klaus Muehlbach
发明人： Gerd Blinne , Walter Goetz , James Hurley , Herbert Gutsche , Klaus Muehlbach
CPC分类号： C08L71/126 , C08K5/07 , C08L77/00
摘要： The thermoplastic molding compositions contain as essential componentsA) from 96 to 99.9% by weight of at least one polyamide,B) from 0.1 to 4% by weight of one or more dialkyl ketones of the general formula I ##STR1## where R and R' are each alkyl of from 10 to 30 carbon atoms, and also, based on the sum total of A) and B),C) from 0 to 40% by weight of an impact modifying rubber,D) from 0 to 60% by weight of fibrous or particulate fillers or a mixture thereof, andE) from 0 to 120% by weight of a modified polyphenylene ether.
摘要翻译： 热塑性模塑组合物含有作为必要成分的A）96-99.9％（重量）的至少一种聚酰胺，B）0.1-4％（重量）一种或多种通式I的二烷基酮，其中R和 R'分别为10-30个碳原子的烷基，并且还基于A）和B）的总和，C）0至40重量％的抗冲击改性橡胶，D）0至60重量％ 的纤维或颗粒填料或其混合物，和E）0至120重量％的改性聚苯醚。
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公开(公告)号：US5192477A
公开(公告)日：1993-03-09
申请号：US758721
申请日：1991-09-09
申请人： Walter Betz , Gerd Blinne
发明人： Walter Betz , Gerd Blinne
CPC分类号： C08J7/14 , C23C18/24 , C08J2377/00 , H05K1/0346 , H05K3/381
摘要： A process for the surface treatment of moldings based on polyamides by treatment with an aqueous acid, wherein the aqueous acid used is a 30-85% strength solution of H.sub.3 PO.sub.4 yields moldings which are readily metallizable. Metallized moldings obtained by this process are useful in the production of automobiles and in the electronics industry.
摘要翻译： 一种通过用酸水溶液处理基于聚酰胺的模制品表面处理的方法，其中所用的含水酸为H 3 PO 4的30-85％强度溶液，产生容易镀金的模制品。 通过该方法获得的金属化模制品可用于生产汽车和电子工业。
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公开(公告)号：US5030689A
公开(公告)日：1991-07-09
申请号：US260039
申请日：1988-10-20
申请人： Christoph Plachetta , Walter Goetz , Gerd Blinne
发明人： Christoph Plachetta , Walter Goetz , Gerd Blinne
IPC分类号： C08L77/00
CPC分类号： C08L77/00
摘要： Thermoplastic molding compositions contain as essential components(A) 10-89% by weight of a copolyamide of(A.sub.1) 80-99% by weight of recurring units derived from adipic acid and hexamethylenediamine and(A.sub.2) 1-20% by weight of units derived from .epsilon.-caprolactam,(B) 10-80% by weight of polyhexamethyleneadipamide,(C) 1-40% by weight of an impact-modifying rubber and in addition(D) 0-60% by weight of a fibrous or particulate filler or a mixture thereof.
摘要翻译： 热塑性成型组合物含有（A）10-89重量％的（A1）共聚酰胺80-99重量％的由己二酸和六亚甲基二胺衍生的重复单元和（A2）1-20重量％的单元 衍生自ε-己内酰胺，（B）10-80重量％的聚六亚甲基己二酰胺，（C）1-40重量％的冲击改性橡胶，另外（D）为0-60重量％的纤维或颗粒 填料或其混合物。
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公开(公告)号：US4861858A
公开(公告)日：1989-08-29
申请号：US142954
申请日：1988-01-12
申请人： Hans-Jakob Kock , Bernd Hisgen , Michael Portugall , Erhard Seiler , Gerd Blinne
发明人： Hans-Jakob Kock , Bernd Hisgen , Michael Portugall , Erhard Seiler , Gerd Blinne
CPC分类号： C08G63/605 , C09K19/3809
摘要： Wholly aromatic thermotropic polyesters are based on(A) 30 to 60 mol % of 4-hydroxybenzoic acid,(B) 20 to 35 mol % of terephthalic acid and(C) 20 to 35 mol % of a mixture of(C.sub.1) trimethylhydroquinone and(C.sub.2) resorcinolthe molar ratio of C.sub.1 :C.sub.2 being within the range from 0.4:1 to 0.7:1 and the molar ratio of B:C within the range from 0.9:1 to 1.1:1.
摘要翻译： 全芳族热致聚酯基于（A）30-60mol％的4-羟基苯甲酸，（B）20-35mol％的对苯二甲酸和（C）20-35mol％的（C1）三甲基对苯二酚和 （C2）间苯二酚，C1：C2的摩尔比在0.4:1至0.7:1的范围内，B:C的摩尔比在0.9:1至1.1:1的范围内。
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公开(公告)号：US4764582A
公开(公告)日：1988-08-16
申请号：US084165
申请日：1987-08-11
申请人： Bernd Hisgen , Hans-Jakob Kock , Michael Portugall , Erhard Seiler , Gerd Blinne
发明人： Bernd Hisgen , Hans-Jakob Kock , Michael Portugall , Erhard Seiler , Gerd Blinne
IPC分类号： C08G63/60 , C08G63/68 , C08G63/682 , C08G63/685 , C08G69/44 , C09K19/38 , D01F6/84 , C08G63/54 , C08G63/44
CPC分类号： C09K19/3809 , C08G63/605 , C08G63/685
摘要： Wholly aromatic thermotropic polyesters are based on(A) from 25 to 60 mol % of a mixture of(A.sub.1) 4-hydroxybenzoic acid and(A.sub.2) 3-hydroxybenzoic acid, 4-aminobenzoic acid and/or 3-aminobenzoic acid or their chlorine, bromine, C.sub.1 -C.sub.8 -alkyl or C.sub.1 -C.sub.8 -alkoxy derivatives substituted in the nucleus, the molar ratio of A.sub.1 to A.sub.2 being from 5:1 to 41:1,(B) from 20 to 37.5 mol % of a mixture of(B.sub.1) terephthalic acid and(B.sub.2) isophthalic acid, the molar ratio of B.sub.1 to B.sub.2 being from 1.04:1 to 19:1, and(C) from 20 to 37.5 mol % of a mixture of(C.sub.1) hydroquinone and(C.sub.2) 4,4'-dihydroxydiphenyl, the molar ratio of C.sub.1 to C.sub.2 being from 0.1:1 to 2.67:1 and the molar ratio of B to C being from 0.9:1 to 1.1:1.
摘要翻译： 全芳族热致聚酯基于（A）25至60摩尔％的（A1）4-羟基苯甲酸和（A2）3-羟基苯甲酸，4-氨基苯甲酸和/或3-氨基苯甲酸或其氯的混合物 ，在核中取代的溴，C 1 -C 8 - 烷基或C 1 -C 8 - 烷氧基衍生物，A1与A2的摩尔比为5：1至41：1，（B）为20至37.5摩尔％ （B1）对苯二甲酸和（B2）间苯二甲酸，B1与B2的摩尔比为1.04：1至19：1，（C）20至37.5摩尔％的（C1）氢醌与（C2 ）4,4'-二羟基二苯基，C1与C2的摩尔比为0.1:1至2.67:1，B与C的摩尔比为0.9:1至1.1:1。
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公开(公告)号：US4751128A
公开(公告)日：1988-06-14
申请号：US79995
申请日：1987-07-31
申请人： Michael Portugall , Bernd Hisgen , Hans-Jakob Kock , Erhard Seiler , Gerd Blinne
发明人： Michael Portugall , Bernd Hisgen , Hans-Jakob Kock , Erhard Seiler , Gerd Blinne
CPC分类号： C08G63/605 , C09K19/3809
摘要： Fully aromatic themotropic polyesters are based on(A) from 30 to 60 mol % of 4-hydroxybenzoic acid,(B) from 20 to 35 mol % of a mixture of(B.sub.1) terephthalic acid and(B.sub.2) isophthalic acid, the molar ratio of B.sub.1 to B.sub.2 being from 1.04:1 to 19:1, and(C) from 20 to 35 mol % of a mixture of(C.sub.1) hydroquinone,(C.sub.2) 4,4'-dihydroxydiphenyl and(C.sub.3) from 0 to 5 mol % of a dihydroxy compound of the general formula I ##STR1## where R and R' are each C.sub.1 -C.sub.4 -alkyl, halogen or aryl, n is 1, 2 or 3 and m is 0 or 1, the molar ratio of C.sub.1 to C.sub.2 being from 0.1:1 to 2.67:1 and the molar ratio of B to C being from 0.9:1 to 1.1:1.
摘要翻译： 全芳族各向同性聚酯基于（A）30〜60摩尔％的4-羟基苯甲酸，（B）为20〜35摩尔％的（B1）对苯二甲酸和（B2）间苯二甲酸的混合物，摩尔比 （C1）氢醌，（C2）4,4'-二羟基联苯和（C3）0-5的混合物的（C）为20〜35摩尔％ mol％的通式I的二羟基化合物（I）其中R和R'各自为C 1 -C 4 - 烷基，卤素或芳基，n为1,2或3，m为0或1， C1与C2的比例为0.1：1至2.67：1，B与C的摩尔比为0.9：1至1.1：1。
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