摘要:
An aqueous highly cross-linked two-component polyurethane coating system is described with reduced hydrophilicity and improved resistance to chemicals which can be obtained by a) producing a binder component based on an aqueous solution or dispersion of low-molecular hydroxyfunctional and/or aminofunctional oligourethanes or polyurethanes and b) by subsequently reacting the binder component a) with a cross-linking component (H) in a ratio of 3:1 to 5:1, wherein water-dispersible polyisocyanates are used as the cross-linking component (H).
摘要:
Disclosed is a functionalized polyurethane resin containing a binder component, a hardener component and, optionally, a formulation component. The binder component consists essentially of urethane dispersions with defined structural components which, in turn, consist of special reaction products. Such polyurethane resins are used for the production of fluorine-modified polyurethane coatings and generally in construction or industrial applications for the permanent oil-, water- and dirt-resistant coating of mineral and non-mineral surfaces on the basis of, for example, hydraulically setting components.
摘要:
An aqueous highly cross-linked two-component polyurethane coating system is described with reduced hydrophilicity and improved resistance to chemicals which can be obtained by a) producing a binder component based on an aqueous solution or dispersion of low-molecular hydroxyfunctional and/or aminofunctional oligourethanes or polyurethanes and b) by subsequently reacting the binder component a) with a cross-linking component (H) in a ratio of 3:1 to 5:1, wherein water-dispersible polyisocyanates are used as the cross-linking component (H).
摘要:
A description is given of azetidine derivatives and methods for producing them, and of their use as a latent curing component for resins having functional groups which are reactive toward amino groups. The particular advantages of the curing component proposed in accordance with the invention, such as effective producibility, high environmental friendliness, and excellent storage stability of the resin/curing agent mixtures, make these azetidine derivatives outstandingly suitable for one-component, moisture-hardening polymer compositions, which are of special interest in particular for the production of (floor) coatings, sealants, and adhesives.
摘要:
A description is given of electrosterically stabilized polyurethane resins having an improved profile of properties, obtainable by a) preparing a hydrophilic and solvent-free macromonomer (A)(ii) with monomodal molecular mass distribution, by a1)reacting 50 to 100 parts by weight of a hydrophilic alkyl- or arylpolyalkylene glycol (A)(i) with 1 to 100 parts by weight of a polyisocyanate component (B)(i) optionally in the presence of a catalyst in the absence of solvents, and subsequently a2) reacting the uniform preadduct from stage a1) completely with 0.5 to 200 parts by weight of a compound (C) in the absence of solvents, and b) by preparing the polyurethane dispersion, by b1)reacting 2 to 50 parts by weight of the hydrophilic and solvent-free macromonomer (A)(ii) with 25 to 250 parts by weight of the polyisocyanate component (B)(i), optionally in the presence of 0 to 50 parts by weight of a solvent component (D) and also of a catalyst, b2) reacting the polyurethane preadduct from stage b1) with 50 to 100 parts by weight of a polymeric polyol (A)(iii) and optionally with 0.5 to 10 parts by weight of a low molecular mass polyol component (A)(iv), optionally in the presence of a catalyst, b3)reacting the homogeneous polyurethane preadduct from stage b2) with 2 to 20 parts by weight of a polyol component (A)(v), optionally in the presence of a catalyst, b4) admixing the homogeneous polyurethane prepolymer from stage b3), before or during dispersion in 50 to 1500 parts by weight of water, with 2 to 20 parts by weight of a neutralizing component (E), b5)dispersing the optionally (partially) neutralized polyurethane prepolymer from stage b4) in 50 to 1500 parts by weight of water, which optionally further contains 0 to 100 parts by weight of a formulating component (F), and finally b6)reacting the (partially) neutralized polyurethane prepolymer dispersion from stage b5) with 3 to 60 parts by weight of a chain extender component (G) and also, subsequently or simultaneously, with 0 to 30 parts by weight of a chain stopper component (H). The performance properties of the polyurethane dispersions of the invention in terms of absence of solvent, and also material properties, are excellent. Also deserving of emphasis are the simplicity and reproducibility of the process and the storage stability of the products.
摘要:
The invention relates to the use of diazepine derivates of general formula (I) and/or (II), wherein R1, R2, R3 and R5 independently represent H, C1-C20-alkyl, C3-C8-cycloakyl, C6-C10-aryl or alkylaryl comprising C1-C4-alkyl and C6-C10-aryl groups, R4═H, C1-C6-alkyl(iden), as latent hardening components for resinous substances comprising functional groups which can react with amines. Based on the particular advantages of the inventive hardening components, such as good producibility, environmentally friendly and having an excellent shelf life of the resin/hardening mixture, said diazepine derivatives are outstanding for single-componented, moisture-hardening polymer masses, which are particularly useful in the production of sealing materials, adhesives and coating materials.
摘要:
Alkanesulfonic acid microcapsules and the use thereof as an additive for acidizing applications in carbonatic rock formations, especially for increasing the permeability of underground carbonatic mineral oil- and/or natural gas-bearing and/or hydrothermal rock formations and for dissolving carbonatic and/or carbonate-containing impurities in the production of mineral oil and/or natural gas or geothermal power generation are described. Additionally described is an acidic formulation comprising the inventive microcapsules and the use thereof for the aforementioned purpose, and a corresponding process.
摘要:
Alkanesulfonic acid microcapsules and the use thereof as an additive for acidizing applications in carbonatic rock formations, especially for increasing the permeability of underground carbonatic mineral oil- and/or natural gas-bearing and/or hydrothermal rock formations and for dissolving carbonatic and/or carbonate-containing impurities in the production of mineral oil and/or natural gas or geothermal power generation are described. Additionally described is an acidic formulation comprising the inventive microcapsules and the use thereof for the aforementioned purpose, and a corresponding process.
摘要:
A process is described for producing homo-, co- and block copolymers by controlled radical polymerization in aqueous solution, wherein a monomer component (A) consisting of at least one radically polymerizable monomer, an initiator component (B) consisting of at least one radical initiator, a polysaccharide component (C) consisting of at least one cyclic polysaccharide (derivative) and a regulator component (D) consisting of at least one compound of the general formula (Ia) or/and (Ib) are reacted in the presence of water, in which R1 to R6 can each independently denote hydrogen, an optionally substituted C1-C20 alkyl residue, C3-C8 cycloalkyl residue, C7-C34 aralkyl residue or optionally an aromatic C6-C14 hydrocarbon residue and R2 and R5 can additionally denote polymer residues having an average molecular mass (number average) of 100 to 50,000 Daltons, and at least two but at most four of the residues R1 to R6 represent an aromatic hydrocarbon residue. In this manner it is possible to produce polymers with a very narrow molecular weight distribution. Moreover, due to the much lower amounts of initiator and regulator compared to the prior art, the polymers contain only very small amounts of regulator and initiator decomposition products.