Storage stable blend comprising a long chain polyol, a short chain diol
and a urethane
    12.
    发明授权
    Storage stable blend comprising a long chain polyol, a short chain diol and a urethane 失效
    储存稳定的共混物,包括长链多元醇,短链二醇和氨基甲酸酯

    公开(公告)号:US4839087A

    公开(公告)日:1989-06-13

    申请号:US185252

    申请日:1988-04-20

    申请人: Timothy A. Tufts

    发明人: Timothy A. Tufts

    IPC分类号: C08G18/66 C08K5/205

    摘要: Disclosed is a storage stable blend of a long chain polyol and a short chain diol wherein the diol is present in an amount whereby the diol and polyol form an incompatible blend. The blend is rendered storage stable by the addition of a compatibilizing amount of a urethane.

    摘要翻译: 公开了长链多元醇和短链二醇的储存稳定共混物,其中二醇的存在量为二醇和多元醇形成不相容的共混物。 通过加入相容剂量的氨基甲酸酯使共混物保持稳定。

    Resinous molding compositions of a phenol, an oxazoline and an epoxy
compound
    13.
    发明授权
    Resinous molding compositions of a phenol, an oxazoline and an epoxy compound 失效
    苯酚,恶唑啉和环氧化合物的树脂成型组合物

    公开(公告)号:US4652620A

    公开(公告)日:1987-03-24

    申请号:US784399

    申请日:1985-10-04

    IPC分类号: C08G59/56 C08G59/06

    摘要: The disclosure is directed to thermoset resinous compositions having utility in the area of surface coating and molding applications, the latter including the preparation of high performance composites and the use in reaction injection molding processes. The contemplated compositions are obtained by polymerizing a reaction mixture comprising a polyfunctional 2-oxazoline compound, a compound or oligomer containing a plurality of aromatic hydroxyl groups and a polyfunctional epoxide.

    摘要翻译: 本公开涉及在表面涂层和模塑应用领域具有实用性的热固性树脂组合物,后者包括制备高性能复合材料以及在反应注射成型工艺中的用途。 考虑的组合物通过聚合包含多官能2-恶唑啉化合物,含有多个芳族羟基的化合物或低聚物和多官能环氧化物的反应混合物而获得。

    Thermoset molding compositions catalyzed by 1,4-benzoquinone salts of
1,8-diaza-bicyclo(5.4.0)undec-7-ene
    14.
    发明授权
    Thermoset molding compositions catalyzed by 1,4-benzoquinone salts of 1,8-diaza-bicyclo(5.4.0)undec-7-ene 失效
    由1,8-二氮杂 - 双环(5.4.0)十一碳-7-烯的1,4-苯醌盐催化的热固性成型组合物

    公开(公告)号:US4880846A

    公开(公告)日:1989-11-14

    申请号:US277884

    申请日:1988-11-30

    IPC分类号: C08G18/20

    CPC分类号: C08G18/2063 C08G2120/00

    摘要: Disclosed is a process for the catalyzed reaction of an isocyanate and an active hydrogen compound wherein the reaction is conducted in the presence of a novel catalyst comprising the salt of 1,8-diazobicyclo(5.4.0)undec-7-ene and 1,4-benzoquinone. Preferred catalyzed reaction mixtures comprise Reaction Injection Molding urethanes (RIM). The novel catalyst salts provide a controlled induction period prior to the onset of gelation of the reaction mixture while providing complete cure of the reaction mixture thereafter.

    摘要翻译: 公开了一种异氰酸酯和活性氢化合物的催化反应的方法,其中反应在包含1,8-二氮双环(5.4.0)十一碳-7-烯和1,1-二氮杂双环(5.4.0)十一碳-7-烯的盐的新型催化剂的存在下进行, 4-苯醌。 优选的催化反应混合物包括反应注射成型聚氨酯(RIM)。 新型催化剂盐在反应混合物凝胶化开始之前提供受控的诱导期,同时提供完全固化反应混合物。

    Amino/ortho carboxylic acid ester catalyst system for isocyanate
trimerization
    15.
    发明授权
    Amino/ortho carboxylic acid ester catalyst system for isocyanate trimerization 失效
    用于异氰酸酯三聚的氨基/邻羧酸酯催化剂体系

    公开(公告)号:US4880845A

    公开(公告)日:1989-11-14

    申请号:US277873

    申请日:1988-11-30

    IPC分类号: C08G18/10 C08G18/16

    摘要: The present invention is directed to an isocyanate-functional composition useful for forming a coating, adhesive, elastomer, or like article. Cure of the composition preferably involves trimerization of the isocyanate groups in the presence of an amino catalyst including a tertiary amine, an amine salt, and quaternary ammonium salts. The novel catalyst system used in achieving cure of the isocyanate-functional compound-containing liquid curable composition comprises an amino catalyst and an ortho-carboxylic acid ester.

    摘要翻译: 本发明涉及用于形成涂料,粘合剂,弹性体等物品的异氰酸酯官能组合物。 组合物的固化优选包括在包括叔胺,胺盐和季铵盐的氨基催化剂存在下异氰酸酯基团的三聚。 用于实现含异氰酸酯官能化合物的液体可固化组合物的固化的新型催化剂体系包含氨基催化剂和邻羧酸酯。

    High impact cross-linked polyurethanes
    17.
    发明授权
    High impact cross-linked polyurethanes 失效
    高冲击交联聚氨酯

    公开(公告)号:US4658008A

    公开(公告)日:1987-04-14

    申请号:US767990

    申请日:1985-08-21

    申请人: Timothy A. Tufts

    发明人: Timothy A. Tufts

    IPC分类号: C08G18/66 C08G18/65 C08G18/32

    摘要: Polyurethane molding compositions characterized in providing tough, high temperature resistant cross-linked products during the in-mold curing cycle thereby obviating the need for post curing in order to obtain potentially optimum physical strength properties.

    摘要翻译: 聚氨酯模塑组合物的特征在于在模内固化周期期间提供坚韧耐高温的交联产物,从而避免后固化的需要,以获得潜在的最佳物理强度性能。

    Thermoplastic polyester low profile additives for vinyl ester/polyester
resinous compositions
    18.
    发明授权
    Thermoplastic polyester low profile additives for vinyl ester/polyester resinous compositions 失效
    乙烯基酯/聚酯树脂组合物的热塑性聚酯低分子添加剂

    公开(公告)号:US5254642A

    公开(公告)日:1993-10-19

    申请号:US940972

    申请日:1992-09-12

    IPC分类号: C08L63/10 C08L67/06 C08F20/20

    CPC分类号: C08L63/10 C08L67/06

    摘要: The present invention is based on the unexpected discovery that the low profile additives (LPA) disclosed in U.S. Pat. No. 5,116,917 provide effective shrinkage control when used with various blends of vinyl ester and polyester resin systems. This LPA is unique in that its low profile efficiency is not affected by the different reactivities displayed by blends of vinyl ester resin and polyester resin at different blend ratios. This LPA is equally effective in formulations of all vinyl ester resin, all polyester resin, or any combination of such two resins. The present invention, then, is directed to a thermosettable resinous composition of between about 0 and 95 wt-% of a thermosettable vinyl ester resin; between about 5 and 100 wt-% of a thermosettable polyester resin; and between about 5 and 40 wt-% of a low profile additive comprising a non-gelling, saturated polyester formed from dibasic acid and an EO/PO block copolymer having an EO/PO molar ratio ranging from about 0.1 to 0.9, said polyester having an acid value of greater than about 10. The EO/PO polyether polyol can be built on a combination of diol, triol or other compound with active hydrogen groups, so long as the LPA product does not gel.

    摘要翻译: 本发明基于意想不到的发现,即在美国专利No. 当与乙烯基酯和聚酯树脂体系的各种共混物一起使用时,提供了有效的收缩率控制。 该LPA是独特的,因为其低轮廓效率不受不同共混比下乙烯基酯树脂和聚酯树脂的共混物显示的不同反应性的影响。 该LPA在所有乙烯基酯树脂,所有聚酯树脂或这两种树脂的任何组合的配方中同样有效。 然后,本发明涉及可热固的乙烯基酯树脂的约0至95重量%的热固性树脂组合物; 约5-100重量%的热固性聚酯树脂; 和约5至40重量%的低分子添加剂,其包含由二元酸形成的非胶凝的饱和聚酯和EO / PO摩尔比为约0.1至0.9的EO / PO嵌段共聚物,所述聚酯具有 大于约10的酸值。只要LPA产物不凝胶,可以将EO / PO聚醚多元醇构建在二醇,三醇或其它化合物与活性氢基团的组合上。

    Thermoplastic polyester low profile additives for vinyl ester resinous
compositions
    19.
    发明授权
    Thermoplastic polyester low profile additives for vinyl ester resinous compositions 失效
    用于乙烯基酯树脂组合物的热塑性聚酯低分子添加剂

    公开(公告)号:US5116917A

    公开(公告)日:1992-05-26

    申请号:US625975

    申请日:1990-12-11

    IPC分类号: C08L63/10

    CPC分类号: C08L63/10

    摘要: The present invention is directed to a thermosettable vinul ester resinous composition and low profile additive. The improvement comprises the low profile additive comprising a non-gelling, saturated polyester formed from dibasic acid and an ethylene oxide/propylene oxide polyether polyol having an EO/PO molar ratio ranging from about 0.1 to 0.9. The polyester has an acid value of greater than about 10 and preferably has a molecular weight of greater than about 6,000. The EO/PO polyether polyol can be built on a combination of diol, triol or other compound with active hydrogen groups, so long as the LPA product does not gel.

    摘要翻译: 本发明涉及一种可热固化的戊烯酯树脂组合物和低调添加剂。 该改进包括由二元酸形成的非胶凝的饱和聚酯和EO / PO摩尔比范围为约0.1至0.9的环氧乙烷/环氧丙烷聚醚多元醇的低分子添加剂。 聚酯的酸值大于约10,优选具有大于约6,000的分子量。 EO / PO聚醚多元醇可以二醇,三醇或其它化合物与活性氢基团的组合构成,只要LPA产物不凝胶即可。