利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

80 条记录 (耗时 0.031 秒)

    Blocked mercaptosilane coupling agents for filled rubbers
    18.
    发明授权
    Blocked mercaptosilane coupling agents for filled rubbers 有权

    公开(公告)号：US07074876B2

    公开(公告)日：2006-07-11

    申请号：US09986515

    申请日：2001-11-09

    申请人： Richard W. Cruse ,  Robert J. Pickwell ,  Keith J. Weller ,  Eric R. Pohl

    发明人： Richard W. Cruse ,  Robert J. Pickwell ,  Keith J. Weller ,  Eric R. Pohl

    IPC分类号： C07F7/04 ,  C07F7/08 ,  C07F7/10 ,  C07F9/165 ,  C07F9/38

    CPC分类号： C07F9/4075 ,  C07F7/1804 ,  C07F9/1651 ,  C08J3/203 ,  C08J2321/00 ,  C08K3/013 ,  C08K3/36 ,  C08K5/0025 ,  C08K5/5406 ,  C08K5/548 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L2666/08

    摘要： Disclosed herein is a blocked mercaptosilane selected from the group consisting of [[(ROC(═O))p—(G)j]k—Y—S]r—G—(SiX3)s; and  (1) [(X3Si)q—G]a—[Y—[S—G—SiX3]b]c  (2) wherein Y is a polyvalent species (Q)zA(═E) selected from the group consisting of —C(═NR)—; —SC(═NR)—; —SC(═O)—; —OC(═O)—; —S(═O)—; —S(═O)2—; —OS(═O)2—; (—NR)S(═O)2—; —SS(═O)—; —OS(═O)—; (—NR)S(═O)—; —SS(═O)2—; (—S)2P(═O)—; —(—S)P(═O)—; —P(═O)(—)2; (—S)2P(═S)—; —(—S)P(═S)—; —P(═S)(—)2; (—NR)2P(═O)—; (—NR)(—S)P(═O)—; (—O)(—NR)P(═O)—; (—O)(—S)P(═O)—; (—O)2P(═O)—; —(—O)P(═O)—; —(—NR)P(═O)—; (—NR)2P(═S)—; (—NR)(—S)P(═S)—; (—O)(—NR)P(═S)—; (—O)(—S)P(═S)—; (—O)2P(═S)—; —(—O)P(═S)—; and —(—NR)P(═S)—; wherein the atom A attached to unsaturated heteroatom E is attached to the sulfur which in turn is linked via a group G to the silicon atom; each R is chosen independently from hydrogen, straight, cyclic, or branched alkyl that may or may not contain unsaturation, alkenyl groups, aryl groups, and aralkyl groups, with each R containing from 1 to 18 carbon atoms;each G is independently a monovalent or polyvalent group derived by substitution of alkyl, alkenyl, aryl, or aralkyl, wherein G can contain from 1 to 18 carbon atoms, with the proviso that G is not such that the blocked mercaptosilane would contain an α,β-unsaturated carbonyl that can undergo polymerization reactions, and if G is univalent, G can be a hydrogen atom;X is independently selected from the group consisting of —Cl, —Br, RO—, RC(═O)O—, R2C═NO—, R2NO—, R2N—, —R, and —(OSiR2)t(OSiR3) wherein each R is as above and at least one X is not —R;p is 0 to 5; r is 1 to 3; z is 0 to 2; q is 0 to 6; a is 0 to 7; b is 1 to 3; j is 0 to 1, but it may be 0 only if p is 1; c is 1 to 6; t is 0 to 5; s is 1 to 3; k is 1 to 2; with the provisos that (I) if A is carbon, sulfur or sulfonyl, then (i) a+b is 2 and (ii) k is 1; (II) if A is phosphorus, then a+b is 3 unless both (i) c is greater than 1 and (ii) b is 1, in which case a is c+1; and (III) if A is phosphorus, then k is 2.