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公开(公告)号:US20160115261A1
公开(公告)日:2016-04-28
申请号:US14891632
申请日:2014-05-13
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Alessandro Mignogna , Reynald Chevalier , Simona Guidotti , Dario Liguori , Giampiero Morini , Martin Schneider
IPC: C08F110/06
CPC classification number: C08F110/06 , C07C271/44 , C07C2601/14 , C07C2602/08 , C08F4/6545 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F2500/15
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from specific diphenol derivatives.
Abstract translation: 一种用于烯烃聚合的固体催化剂组分,包括Mg,Ti,Cl和至少一种电子给体化合物,它是通过与Mg化合物和至少具有Ti-卤素键的电子与电子接触而获得的反应产物 供体选自具体的二酚衍生物。
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公开(公告)号:US20150141594A1
公开(公告)日:2015-05-21
申请号:US14406470
申请日:2013-06-05
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Alessandro Mignogna , Simona Guidotti , Igor Kashulin , Giampiero Morini , Ilya Nifant'ev , Joachim T.M. Pater
CPC classification number: C08F4/52 , C08F4/10 , C08F4/16 , C08F110/08 , C08F4/651 , C08F2500/15 , C08F2500/17 , C08F110/06 , C08F2500/12
Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups equal to or different from each other, are C1-C15 hydrocarbon groups, the R1-R2 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which can be fused together to form one or more cycles; n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0 and that diisobutyl o-phenylenediacetate is excluded.
Abstract translation: 包含Mg,Ti和其中R基彼此相同或不同的下式(I)的电子给体化合物的烯烃聚合催化剂组分是C 1 -C 15烃基,R 1 -R 2基, 相同或不同的是氢,卤素或C 1 -C 15烃基,任选地含有选自卤素,P,S,N和Si的杂原子,其可以一起稠合形成一个或多个循环; n和m是0-3的整数,条件是它们中的至少一个不同于0,并且排除邻苯二乙酸二异丁酯。
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公开(公告)号:US10246532B2
公开(公告)日:2019-04-02
申请号:US15557704
申请日:2016-03-08
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Reynald Chevalier , Alessandro Mignogna , Giampiero Morini
IPC: C08F110/06 , C07F7/28
Abstract: A solid catalyst component which exhibits high activity and stereospecificity in the polymerization of olefins made from or containing Mg, Ti and an electron donor of formula (I) where R and R1 are selected from the group consisting of C1-C20 hydrocarbon groups, C6-C14 aryl or alkylaryl groups hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N, and O; R2 to R11 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups which can be optionally fused together to form one or more cycles with the proviso that R6 and R11 cannot join together to form a phenyl ring.
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公开(公告)号:US10113013B2
公开(公告)日:2018-10-30
申请号:US15128830
申请日:2015-03-24
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Alessandro Mignogna , Giampiero Morini
IPC: C08F4/642 , C08F4/02 , C08F4/659 , C08F110/06 , C08L57/00 , C07C271/44 , C08F10/14
Abstract: The present disclosure relates to a solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the formula (I): where each Q is a group —COOR1, in which R1 is selected from C1-C15 hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N and O; or a group —CON(R2)2, in which R2 groups, equal to or different from each other, are hydrogen or R1 groups which can be fused together to form one or more cycles, and A is a bivalent bridging group with the proviso that the Q groups cannot be simultaneously a group —COOR1 or —CON(R2)2.
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公开(公告)号:US10005860B2
公开(公告)日:2018-06-26
申请号:US15428940
申请日:2017-02-09
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Alessandro Mignogna , Reynald Chevalier , Igor Kashulin , Ilya Nifant'ev , Giampiero Morini , Martin Schneider
IPC: C08F110/06 , C07C327/26 , C07C327/28 , C07C329/10 , C07C333/04
CPC classification number: C08F110/06 , C07C327/26 , C07C327/28 , C07C329/10 , C07C333/04 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6545
Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I) In which X and Y are selected from, R1, and —OR1 and —NR2, B is oxygen or sulphur S is sulphur, R1 is selected from C1-C15 hydrocarbon groups, optionally contain a heteroatom selected from halogen, P, S, N, O and Si, which can be fused together to form one or more cycles, R is hydrogen or R1 and A is a bivalent bridging group with chain length between the two bridging bonds being 1-10 atoms.
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公开(公告)号:US20150158957A1
公开(公告)日:2015-06-11
申请号:US14402941
申请日:2013-05-17
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Alessandro Mignogna , Simona Guidotti , Giampiero Morini , Joachim T.M. Pater
IPC: C08F10/06
CPC classification number: C08F10/06 , C08F10/00 , C08F4/6543 , C08F4/651 , C08F110/06 , C08F2500/12
Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which R2-R8 groups, equal or different to each other, are selected from hydrogen, halogen and C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, O, P, S, N, and Si and R9 groups are selected from C1-C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, O, P, S, N, and Si.
Abstract translation: 用于包含Mg,Ti的烯烃聚合的催化剂组分和其中R 2 -R 8基彼此相同或不同的下式(I)的电子给体化合物选自氢,卤素和C 1 -C 15烃基, 任选地含有选自卤素,O,P,S,N和Si的杂原子,R 9基团选自任选含有选自卤素,O,P,S,N和Si的杂原子的C 1 -C 15烃基。
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公开(公告)号:US20140243489A1
公开(公告)日:2014-08-28
申请号:US14352625
申请日:2012-10-11
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Ilya Nifant'ev , Alessandro Mignogna , Vladimir Bagrov , Simona Esposito , Simona Guidotti , Giampiero Morini , Joachim T.M. Pater , Fabrizio Piemontesi , Sophia A. Toloraya
IPC: C08F4/649
CPC classification number: C08F4/6498 , C08F10/00 , C08F4/6543 , C08F4/651
Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R to R12 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, with the proviso that R groups cannot be hydrogen and that the carboxylate groups are in trans configuration with respect to each other.
Abstract translation: 用于包含Mg,Ti和下式(I)的电子给体化合物的烯烃聚合的催化剂组分其中R至R12基团彼此相同或不同的是氢,卤素或C 1 -C 15烃基,任选地 含有选自卤素,P,S,N和Si的杂原子,条件是R基团不能是氢,并且羧酸酯基团相对于反式构型。
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公开(公告)号:US11407844B2
公开(公告)日:2022-08-09
申请号:US17312264
申请日:2019-12-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Alessandro Mignogna , Dario Liguori , Giampiero Morini , Gianni Vitale
Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from diphenol derivatives.
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公开(公告)号:US10221256B2
公开(公告)日:2019-03-05
申请号:US15574807
申请日:2016-05-18
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Alessandro Mignogna , Igor Kashulin , Giampiero Morini , Ilya Nifant'ev
IPC: C08F4/651 , C08F110/06
Abstract: A solid catalyst component for the polymerization of olefins, made from or containing Mg, Ti and an electron donor of formula (I) where independently, Z is a bridging group, the R2 groups, equal to or different from each other, are hydrogen or a C1-C20 hydrocarbon radicals, m is a number satisfying the valences of Z and n is an integer ranging from 1 to 10, R1 and R4 are selected from C1-C15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N, O; and R3 group, is hydrogen or R4 groups.
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公开(公告)号:US10017590B2
公开(公告)日:2018-07-10
申请号:US15557011
申请日:2016-03-07
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Alessandro Mignogna , Giampiero Morini , Reynald Chevalier
CPC classification number: C08F110/06 , C08F4/6455 , C08F4/6457 , C08F4/649 , C08F4/6495 , C08F4/6498 , C08F2410/01 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6543
Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, halogen and an electron donor of formula (I) or (II) When activated with an aluminum alkyl and optionally an external electron donor, solid catalyst component can give high activity and stereospecificity in the polymerization of olefins.
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