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1.发明公开公开(公告)号：US20240076422A1
公开(公告)日：2024-03-07
申请号：US18460381
申请日：2023-09-01
发明人： Jing-Cherng TSAI , Jen-Long WU , Wen-Hao KANG , Kuei-Pin LIN , Jing-Yu LEE , Jun-Ye HONG , Zih-Yu SHIH , Cheng-Hung CHIANG , Gang-Wei SHEN , Yu-Chuan SUNG , Chung-Hua WENG , Hsing-Ya CHEN
IPC分类号： C08F4/16 , C08F4/02 , C08F4/12 , C08F4/18 , C08F110/02
CPC分类号： C08F4/16 , C08F4/025 , C08F4/12 , C08F4/18 , C08F110/02
摘要： A supported metallocene catalyst includes a carrier and a metallocene component. The carrier includes an inorganic oxide particle and an alkyl aluminoxane material. The inorganic oxide particle includes at least one inorganic oxide compound selected from the group consisting of an oxide of Group 3A and an oxide of Group 4A. The alkyl aluminoxane material includes an alkyl aluminoxane compound and an alkyl aluminum compound that is present in amount ranging from greater than 0.01 wt % to less than 14 wt % base on 100 wt % of the alkyl aluminoxane material. The metallocene component is supported on the carrier, and includes one of a metallocene compound containing a metal from Group 3B, a metallocene compound containing a metal from Group 4B, and a combination thereof. A method for preparing the supported metallocene catalyst and a method for preparing polyolefin using the supported metallocene catalyst are also disclosed.
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公开(公告)号：US20180305527A1
公开(公告)日：2018-10-25
申请号：US15972506
申请日：2018-05-07
CPC分类号： C08L23/06 , C08F2/44 , C08F4/16 , C08F110/02 , C08F210/02 , C08K3/08 , C08K3/22 , C08K3/24 , C08K9/02 , C08K2201/011 , C08L23/08 , G01K17/04 , G01N23/20 , G01N2030/486
摘要： Methods of preparing high-density polyethylene (HDPE) nanocomposites by in situ polymerization with a zirconocene catalyst, a methylaluminoxane cocatalyst, a calcium zirconate nanofiller in a solvent. The calcium zirconate nanofiller, which is dispersed across the polyethylene matrix, is found to enhance catalyst activity, and other properties of the HDPE nanocomposites produced, including but not limited to flame retardency, crystallinity and surface morphology.
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公开(公告)号：US20180237552A1
公开(公告)日：2018-08-23
申请号：US15959505
申请日：2018-04-23
发明人： Yiqun Fang , Demin Xu , Ming-Yung Lee
IPC分类号： C08F4/52 , C08F4/10 , C08F110/06 , C08F4/16 , C08F4/654
CPC分类号： C08F4/52 , C08F4/10 , C08F4/16 , C08F110/06 , C08F4/6546 , C08F4/654 , C08F2500/12
摘要： Heterocyclic organic compounds are used as electron donors in conjunction with solid Ziegler-Natta type catalyst in processes in which polyolefins such as polypropylene are produced. The electron donors may be used in the preparation of solid catalyst system, thus serving as “internal electron donors,” or they may be employed during or prior to polymerization with the co-catalyst as “external electron donors.”
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公开(公告)号：US09994700B2
公开(公告)日：2018-06-12
申请号：US15607522
申请日：2017-05-28
CPC分类号： C08L23/06 , C08F2/44 , C08F4/16 , C08F110/02 , C08F210/02 , C08K3/08 , C08K3/22 , C08K3/24 , C08K9/02 , C08K2201/011 , C08L23/08 , G01K17/04 , G01N23/20 , G01N2030/486
摘要： Methods of preparing high-density polyethylene (HDPE) nanocomposites by in situ polymerization with a zirconocene catalyst, a methylaluminoxane cocatalyst, a calcium zirconate nanofiller in a solvent. The calcium zirconate nanofiller, which is dispersed across the polyethylene matrix, is found to enhance catalyst activity, and other properties of the HDPE nanocomposites produced, including but not limited to flame retardency, crystallinity and surface morphology.
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公开(公告)号：US09688836B2
公开(公告)日：2017-06-27
申请号：US14796885
申请日：2015-07-10
CPC分类号： C08L23/06 , C08F2/44 , C08F4/16 , C08F110/02 , C08F210/02 , C08K3/08 , C08K3/22 , C08K3/24 , C08K9/02 , C08K2201/011 , C08L23/08 , G01K17/04 , G01N23/20 , G01N2030/486
摘要： Methods of preparing high-density polyethylene (HDPE) nanocomposites by in situ polymerization with a zirconocene catalyst, a methylaluminoxane cocatalyst, a calcium zirconate nanofiller in a solvent. The calcium zirconate nanofiller, which is dispersed across the polyethylene matrix, is found to enhance catalyst activity, and other properties of the HDPE nanocomposites produced, including but not limited to flame retardency, crystallinity and surface morphology.
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公开(公告)号：US20170080406A1
公开(公告)日：2017-03-23
申请号：US14858512
申请日：2015-09-18
发明人： Jeremy M. PRAETORIUS , Eric D. SCHWERDTFEGER , Max P. MCDANIEL , Ted H. CYMBALUK , Connor D. BOXELL , Alan L. SOLENBERGER , Kathy S. CLEAR
CPC分类号： B01J23/26 , B01J21/08 , B01J35/1019 , B01J35/1023 , B01J35/1047 , B01J37/0203 , B01J37/0236 , B01J37/08 , C08F10/02 , C08F110/02 , C08F4/22 , C08F4/24 , C08F4/025 , C08F4/16 , C08F2500/12
摘要： A method comprising a) drying a support material comprising silica at temperature in the range of from about 150° C. to about 220° C. to form a dried support; b) contacting the dried support with methanol to form a slurried support; c) subsequent to b), cooling the slurried support to a temperature of less than about 60° C. to form a cooled slurried support; d) subsequent to c), contacting the cooled slurried support with a titanium alkoxide to form a titanated support; and e) thermally treating the titanated support by heating to a temperature of equal to or greater than about 150° C. for a time period of from about 5 hours to about 30 hours to remove the methanol and yield a dried titanated support.
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公开(公告)号：US20170066852A1
公开(公告)日：2017-03-09
申请号：US15290721
申请日：2016-10-11
申请人： Georgy Kipiani , Timo Leinonen , Peter Denifl , Reijo Mulari , Tommi Krogerus
发明人： Georgy Kipiani , Timo Leinonen , Peter Denifl , Reijo Mulari , Tommi Krogerus
IPC分类号： C08F10/06
CPC分类号： C08F10/06 , C08F4/16 , C08F4/52 , C08F4/6546 , C08F4/6548 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F210/06 , C08F210/12
摘要： The invention relates to a particulate Group 2 metal/transition metal olefin polymerisation catalyst component comprising a special 1,3-diether as internal donor, to a process for preparing same and to the use of such a catalyst component for preparing a catalyst used in the polymerisation of olefins.
摘要翻译： 本发明涉及包含作为内给体的特殊1,3-二醚的颗粒组2金属/过渡金属烯烃聚合催化剂组分，其制备方法以及这种催化剂组分用于制备用于 烯烃的聚合。
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8.发明授权公开(公告)号：US09499646B2
公开(公告)日：2016-11-22
申请号：US15153044
申请日：2016-05-12
CPC分类号： C08F30/04 , C07F7/003 , C08F4/06 , C08F4/12 , C08F4/16 , C08F299/0464 , C08G18/222 , G03F7/004 , G03F7/0042 , G03F7/027 , G03F7/038 , G03F7/2002 , G03F7/30 , G03F7/40
摘要： A negative resist composition including a complex represented by the general formula (1); and a polymerization initiator, in which M represents hafnium (Hf) or zirconium (Zr), X represents a ligand comprising a conjugate base of an acid which has an acid dissociation constant (pKa) of 3.8 or less and has a polymerizable group, Y represents a ligand having no polymerizable group, and n represents an integer of 1 to 4. [MXnY4-n] (1)
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9.发明授权公开(公告)号：US09366960B2
公开(公告)日：2016-06-14
申请号：US14558977
申请日：2014-12-03
IPC分类号： G03F7/004 , G03F7/038 , G03F7/20 , C08G18/22 , C08F4/06 , G03F7/30 , G03F7/40 , C08F30/04 , C08F299/04
CPC分类号： C08F30/04 , C07F7/003 , C08F4/06 , C08F4/12 , C08F4/16 , C08F299/0464 , C08G18/222 , G03F7/004 , G03F7/0042 , G03F7/027 , G03F7/038 , G03F7/2002 , G03F7/30 , G03F7/40
摘要： A negative resist composition including a complex represented by the general formula (1); and a polymerization initiator. in which M represents hafnium (Hf) or zirconium (Zr), X represents a ligand including a conjugate base of an acid which has an acid dissociation constant (pKa) of 3.8 or less and has a polymerizable group, Y represents a ligand having no polymerizable group, and n represents an integer of 1 to 4. [MXnY4-n] (1)
摘要翻译： 包含由通式（1）表示的络合物的负性抗蚀剂组合物; 和聚合引发剂。 其中M表示铪（Hf）或锆（Zr），X表示包含酸分解常数（pKa）为3.8以下且具有聚合性基团的酸的共轭碱的配体，Y表示不具有 可聚合基团，n表示1〜4的整数。[MXnY4-n]（1）
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公开(公告)号：US09359465B2
公开(公告)日：2016-06-07
申请号：US14017761
申请日：2013-09-04
IPC分类号： C08F4/00 , C08F132/00 , C08G18/32 , C08F10/10 , C08G18/62 , C07C17/013 , C07C19/075 , C07C31/18 , C07C51/00 , C07C209/08 , C07C211/01 , C08F110/10
CPC分类号： C08F8/00 , C07C17/013 , C07C19/075 , C07C31/18 , C07C51/00 , C07C209/08 , C07C211/01 , C08F8/06 , C08F8/10 , C08F8/12 , C08F8/20 , C08F8/26 , C08F8/30 , C08F8/32 , C08F10/10 , C08F110/10 , C08F2810/30 , C08F2810/40 , C08G18/3206 , C08G18/6204 , C08G18/7671 , C08F4/16 , C08F2/38 , C08F8/28
摘要： The present invention generally relates to alcohol-terminated polyisobutylene (PIB) compounds, and to a process for making such compounds. In one embodiment, the present invention relates to primary alcohol-terminated polyisobutylene compounds, and to a process for making such compounds. In still another embodiment, the present invention relates to polyisobutylene compounds that can be used to synthesize polyurethanes, to polyurethane compounds made via the use of such polyisobutylene compounds, and to processes for making such compounds. In yet another embodiment, the present invention relates to primary alcohol-terminated polyisobutylene compounds having two or more primary alcohol termini and to a process for making such compounds. In yet another embodiment, the present invention relates to primary terminated polyisobutylene compounds having two or more primary termini selected from amine groups or methacrylate groups.
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