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    Process for the production of a primary aminoanthraquinone by conversion of an n-cyclohexylaminoanthraquinone
    12.
    发明授权
    Process for the production of a primary aminoanthraquinone by conversion of an n-cyclohexylaminoanthraquinone 失效
    通过转化正环己基氨基蒽醌生产伯氨基蒽醌的方法

    公开(公告)号：US3342831A

    公开(公告)日：1967-09-19

    申请号：US38826564

    申请日：1964-08-07

    Applicant: BASF AG

    Inventor： WILLY BRAUN ,  MANFRED RUSKE

    IPC: C09B1/22 ,  C09B1/24 ,  C09B1/50 ,  C09B1/58

    CPC classification number: C09B1/50 ,  C09B1/22 ,  C09B1/24 ,  C09B1/585

    Abstract: Primary amines of the antraquinone series are made by allowing strong sulphuric acid, oleum, chlorosulphonic acid or a melt of aluminium chloride and a melting point depressant to act on a cyclohexylamino-anthraquinone which may be substituted in the anthraquinonyl radical. When sulphuric acid or oleum is used, nitrile or amido groups may be wholly or partly saponified or sulphonic acid groups may be introduced. Preferably the acid reagent is a mixture of aluminium chloride and a compound having the general formula X1COX2 in which X1 denotes hydrogen, halogen, alkyl or amino, and X2 denotes an unsubstituted, mono-allyl- or diallyl-substituted amino group, or, if X1 is hydrogen, an O-metal group, or X1 and X2 when taken together denote an alkylenamino or an a ,o -diamino alkylene radical with 3 to 6 methylene groups which together with the CO group form an inner amide, the amido nitrogen of which may be substituted with an alkyl group. Detailed examples are given in which the products contain chloro, sulphonic acid, cyano, methoxy, carboxylic acid cyclohexylamide, carboxylic acid, hydroxy, or carboxylic amide radicals in addition to amino groups.

    Abstract translation: 蒽醌系列的伯胺通过使强硫酸，发烟硫酸，氯磺酸或氯化铝熔体和熔点降低剂作用于可在蒽醌基中取代的环己基氨基 - 蒽醌来制备。 当使用硫酸或发烟硫酸时，腈或酰氨基可以全部或部分皂化，或者可以引入磺酸基团。 优选地，酸试剂是氯化铝和具有通式X1COX2的化合物的混合物，其中X1表示氢，卤素，烷基或氨基，X2表示未取代的单烯丙基或二烯丙基取代的氨基，或如果 X1是氢，O-金属基，或X1和X2，它们一起表示亚烷基氨基或具有3至6个亚甲基的a，o-二氨基亚烷基，其与CO基一起形成内酰胺，酰氨基氮 其可以被烷基取代。 给出了除了氨基以外，产物含有氯，磺酸，氰基，甲氧基，羧酸环己酰胺，羧酸，羟基或羧酰胺基的详细实例。

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