PREPARATION OF PRECIPITATED ZN PP CATALYSTS WITH INTERNAL PORE STRUCTURE USING NANOPARTICLES
    19.
    发明申请
    PREPARATION OF PRECIPITATED ZN PP CATALYSTS WITH INTERNAL PORE STRUCTURE USING NANOPARTICLES 审中-公开
    使用纳米粒子制备具有内部结构的ZN PP催化剂

    公开(公告)号:US20140322535A1

    公开(公告)日:2014-10-30

    申请号:US14262250

    申请日:2014-04-25

    Applicant: Borealis AG

    Abstract: Process for the preparation of a catalyst being in the form of solid particles comprising the steps of preparing a solution of a complex of a metal which is selected from one of the groups 1 to 3 of the periodic table (IUPAC) and an electron donor by reacting a compound of said metal with said electron donor in an organic liquid reaction medium; adding to said solution solid material obtaining a suspension, said solid material does not comprise catalytically active sites, has a specific surface area below 500 m2/g, and has a mean particle size below 200 nm; combining said suspension at a temperature of at least 50° C. with at least one transition metal compound resulting in a precipitation of said catalyst being in the form of a solid particle, wherein said transition metal compound is selected from one of the groups 4 to 10 of the periodic table (IUPAC) or a compound of actinide or lanthanide; and optionally separating said catalyst; said catalyst being in the form of solid particles, which have a specific surface area of less than 20 m2/g, and contain said solid material.

    Abstract translation: 用于制备固体颗粒形式的催化剂的方法包括以下步骤:通过以下步骤制备选自元素周期表(IUPAC)中的1至3族之一的金属与电子给体的络合物的溶液: 使所述金属的化合物与所述电子给体在有机液体反应介质中反应; 加入所述溶液固体材料获得悬浮液,所述固体材料不包含催化活性位点,比表面积低于500m2 / g,平均颗粒尺寸低于200nm; 将所述悬浮液在至少50℃的温度下与至少一种过渡金属化合物结合,导致所述催化剂以固体颗粒的形式沉淀,其中所述过渡金属化合物选自组4至 10的周期表(IUPAC)或锕系元素或镧系元素的化合物; 并任选分离所述催化剂; 所述催化剂为比表面积小于20m 2 / g的固体颗粒形式,并含有所述固体材料。

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