公开(公告)号：US11365908B2

公开(公告)日：2022-06-21

申请号：US17536970

申请日：2021-11-29

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Sheng Peng ,  Mario Joseph Nappa

IPC: F25B13/00 ,  C07C17/357 ,  C07C21/18

Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.

公开(公告)号：US20210292627A1

公开(公告)日：2021-09-23

申请号：US17336575

申请日：2021-06-02

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Velliyur Nott Mallikarjuna Rao ,  Mario Joseph Nappa ,  Allen Capron Sievert

IPC: C09K5/04 ,  C07C17/00 ,  C07C17/087 ,  C07C17/20 ,  C07C17/23 ,  C07C17/354 ,  C07C19/08 ,  C07C19/10

Abstract: A process is disclosed for making CF3CF═CHF. The process involves reacting CF3CClFCCl2F with H2 in a reaction zone in the presence of a catalyst to produce a product mixture comprising CF3CF═CHF. The catalyst has a catalytically effective amount of palladium supported on a support selected from the group consisting of alumina, fluorided alumina, aluminum fluoride and mixtures thereof and the mole ratio of H2 to CF3CClFCCl2F fed to the reaction zone is between about 1:1 and about 5:1. Also disclosed are azeotropic compositions of CF3CClFCCl2F and HF and azeotropic composition of CF3CHFCH2F and HF.

公开(公告)号：US10995047B2

公开(公告)日：2021-05-04

申请号：US16446840

申请日：2019-06-20

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Mario Joseph Nappa ,  Xuehui Sun ,  David Richard Corbin

IPC: C07C17/389 ,  C07C17/25 ,  C07C17/087

Abstract: This disclosure relates to processes which involve: contacting a mixture comprising at least one fluoroolefin and at least one impurity with at least one zeolite to reduce the concentration of the at least one impurity in the mixture; and the at least one zeolite is selected from the group consisting of zeolites having pore opening of at least 4 Angstroms and no more than about 5 Angstroms, zeolites having pore opening of at least about 5 Angstroms and Sanderson electronegativity of no more than about 2.6, and mixtures thereof; provided that the at least one zeolite is not zeolite 4A. This disclosure also relates to processes for making at least one hydrotetrafluoropropene product selected from the group consisting of CF3CF═CH2, CF3CH═CHF, and mixtures thereof; and relates to processes for making at least one hydrochlorotrifluoropropene product selected from the group consisting of CF3CCl═CH2, CF3CH═CHCl, and mixtures thereof.

公开(公告)号：US20190194514A1

公开(公告)日：2019-06-27

申请号：US16244609

申请日：2019-01-10

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： BARRY ASHER MAHLER ,  Mario Joseph Nappa

IPC: C09K5/04

Abstract: Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, is HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, CHF═CHCl, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

公开(公告)号：US09943717B2

公开(公告)日：2018-04-17

申请号：US14710733

申请日：2015-05-13

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Mario Joseph Nappa

IPC: B24B1/00 ,  C09K3/14 ,  A62D1/00 ,  C07C17/25 ,  C08J9/14 ,  C09K3/30 ,  C09K5/04 ,  B01F17/00 ,  C09K3/00 ,  C09K21/08 ,  C11D7/30 ,  F25B39/02 ,  H01B3/56 ,  F28C3/08 ,  C11D7/50 ,  B24D11/00 ,  B24D18/00 ,  B24D3/02

CPC classification number: A62D1/00 ,  B01F17/0085 ,  C07C17/25 ,  C08J9/144 ,  C08J9/146 ,  C08J9/149 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2300/22 ,  C08J2300/24 ,  C08J2323/06 ,  C08J2323/12 ,  C08J2325/06 ,  C08J2361/04 ,  C08J2375/04 ,  C09K3/00 ,  C09K3/14 ,  C09K3/30 ,  C09K5/044 ,  C09K5/045 ,  C09K21/08 ,  C09K2205/122 ,  C09K2205/126 ,  C11D7/30 ,  C11D7/5018 ,  F25B39/02 ,  F28C3/08 ,  H01B3/56

Abstract: The present disclosure relates to compositions comprising 2,3,3,3-tetrafluoropropene that may be useful as heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, extinguishing agents, and fire suppression agents in liquid or gaseous form. Additionally, the present disclosure relates to compositions comprising 1,1,2,3-tetrachloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane, which may be useful in processes to produce 2,3,3,3-tetrafluoropropene.

公开(公告)号：US09328042B2

公开(公告)日：2016-05-03

申请号：US14813383

申请日：2015-07-30

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Sheng Peng ,  Andrew Jackson ,  Mario Joseph Nappa

IPC: C07C17/02 ,  C07C17/00 ,  C07C17/20 ,  C07C17/04 ,  C07C17/25

CPC classification number: C07C17/04 ,  C07C17/087 ,  C07C17/25 ,  Y02P20/125 ,  C07C19/01 ,  C07C21/20 ,  C07C21/18

Abstract: The present invention provides an efficient and cost effect synthesis route from a specific starting material of 2,3-dichloro-1,3-butadiene to the desired product of Z-1,1,1,4,4,4-hexafluoro-2-butene.

Abstract translation: 本发明提供了一种从2,3-二氯-1,3-丁二烯的特定原料到Z-1,1,1,4,4,4-六氟-2 丁烯。

公开(公告)号：US12180134B2

公开(公告)日：2024-12-31

申请号：US18528224

申请日：2023-12-04

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Mario Joseph Nappa ,  Xuehui Sun ,  David Richard Corbin

IPC: C07C17/389 ,  C07C17/087 ,  C07C17/25

Abstract: This disclosure relates to processes which involve: contacting a mixture comprising at least one fluoroolefin and at least one impurity with at least one zeolite to reduce the concentration of the at least one impurity in the mixture; and the at least one zeolite is selected from the group consisting of zeolites having pore opening of at least 4 Angstroms and no more than about 5 Angstroms, zeolites having pore opening of at least about 5 Angstroms and Sanderson electronegativity of no more than about 2.6, and mixtures thereof; provided that the at least one zeolite is not zeolite 4A. This disclosure also relates to processes for making at least one hydrotetrafluoropropene product selected from the group consisting of CF3CF═CH2, CF3CH═CHF, and mixtures thereof; and relates to processes for making at least one hydrochlorotrifluoropropene product selected from the group consisting of CF3CCl═CH2, CF3CH═CHCl, and mixtures thereof.

公开(公告)号：US20240360055A1

公开(公告)日：2024-10-31

申请号：US18653386

申请日：2024-05-02

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Xuehui Sun ,  Mario Joseph Nappa ,  Karl Krause

IPC: C07C17/087 ,  B01J23/16 ,  B01J23/18 ,  B01J27/08 ,  C07C17/08 ,  C07C17/20 ,  C07C17/25 ,  C07C19/08 ,  C07C19/10

CPC classification number: C07C17/087 ,  B01J23/16 ,  B01J23/18 ,  B01J27/08 ,  C07C17/08 ,  C07C17/206 ,  C07C17/25 ,  C07C19/08 ,  C07C19/10 ,  C07C2527/12 ,  C07C2527/133

Abstract: A method hydrofluorinates an olefin of the formula: RCX=CYZ to produce a hydrofluoroalkane of formula RCXFCHYZ or RCXHCFYZ, where X, Y, and Z are independently the same or different and are selected from the group consisting of H, F, Cl, Br, and C1-C6 alkyl which is partially or fully substituted with chloro or fluoro or bromo; and R is a C1-C6 alkyl which is unsubstituted or substituted with chloro or fluoro or bromo. The method includes reacting the olefin with HF in the vapor phase, in the presence of SbF5, at a temperature ranging from about −30° C. to about 65° C. and compositions formed by the process.

公开(公告)号：US12023536B2

公开(公告)日：2024-07-02

申请号：US18103695

申请日：2023-01-31

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Mario Joseph Nappa

IPC: A62D1/00 ,  C07C17/25 ,  C08J9/14 ,  C09K3/00 ,  C09K3/14 ,  C09K3/30 ,  C09K5/04 ,  C09K21/08 ,  C09K23/00 ,  C11D7/30 ,  C11D7/50 ,  F25B39/02 ,  F28C3/08 ,  H01B3/56

CPC classification number: A62D1/00 ,  C07C17/25 ,  C08J9/144 ,  C08J9/146 ,  C08J9/149 ,  C09K3/00 ,  C09K3/14 ,  C09K3/30 ,  C09K5/044 ,  C09K5/045 ,  C09K21/08 ,  C09K23/017 ,  C11D7/30 ,  C11D7/5018 ,  F25B39/02 ,  F28C3/08 ,  H01B3/56 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2300/22 ,  C08J2300/24 ,  C08J2323/06 ,  C08J2323/12 ,  C08J2325/06 ,  C08J2361/04 ,  C08J2375/04 ,  C09K2205/122 ,  C09K2205/126

Abstract: The present disclosure relates to compositions comprising 2,3,3,3-tetrafluoropropene that may be useful as heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, extinguishing agents, and fire suppression agents in liquid or gaseous form. Additionally, the present disclosure relates to compositions comprising 1,1,2,3-tetrachloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane, which may be useful in processes to produce 2,3,3,3-tetrafluoropropene.

公开(公告)号：US20240191914A1

公开(公告)日：2024-06-13

申请号：US18414971

申请日：2024-01-17

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： SHENG PENG ,  Mario Joseph Nappa

IPC: F25B13/00 ,  C07C17/357 ,  C07C19/08 ,  C07C21/18

CPC classification number: F25B13/00 ,  C07C17/357 ,  C07C19/08 ,  C07C21/18

Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.