摘要:
There are provided electrically conducting polymer compositions comprising an electrectically conductive polymer or copolymer and an organic solvent wettable fluorinated acid polymer. Electrically conductive polymer materials are derived from thiophene, pyrrole, aniline and polycyclic heteroaromatic precursor monomers. Non-conductive polymers derived from alkenyl, alkynyl, arylene, and heteroarylene precursor monomers. The organic-solvent wettable fluorinated acid polymer is fluorinated or highly fluorinated and may be colloid-forming. Acidic groups include carboxylic acid groups, sulfonic acid groups, sulfonimide groups, phosphoric acid groups, phosphonic acid groups, and combinations thereof. The compositions can be used in organic electronic devices.
摘要:
Disclosed are compositions comprising: at least one monomer of the formula: where SiR′RR″ is SiCl3, Si(alkyl)Cl2, Si(alkyl)(O-alkyl)2, or Si(O-alkyl)3; n and y are each 0 or an integer from 1 to 10; and at least one particle comprising silica, alumina, zirconia, or mixtures thereof.
摘要:
There is provided a transparent conductor including conductive nanoparticles and at least one of (a) a fluorinated acid polymer and (b) a semiconductive polymer doped with a fluorinated acid polymer. The nanoparticles are carbon nanoparticles, metal nanoparticles, or combinations thereof. The carbon and metal nanoparticles are selected from nanotubes, fullerenes, and nanofibers. The acid polymers are fluorinated or highly fluorinated and have acidic groups including carboxylic acid groups, sulfonic acid groups, sulfonimide groups, phosphoric acid groups, phosphonic acid groups, and combinations thereof. The semiconductive polymers comprise homopolymers and copolymers derived from monomers selected from substituted and unsubstituted thiophenes, pyrroles, anilines, and cyclic heteroaromatics, and combinations of those. The compositions may be used in organic electronic devices (OLEDs).
摘要:
There is provided an electrically conductive polymer composition, comprising a first electrically conductive polymer doped with an organic solvent wettable fluorinated acid polymer in admixture with a second electrically conductive polymer doped with an organic solvent non-wettable fluorinated acid polymer.
摘要:
Buffer compositions comprising semiconductive oxide particles and at least one of (a) a fluorinated acid polymer and (b) a semiconductive polymer doped with a fluorinated acid polymer are provided. Semiconductive oxide particles include metal oxides and bimetallic oxides. Acid polymers are derived from monomers or comonomers of polyolefins, polyacrylates, polymethacrylates, polyimides, polyamides, polyaramids, polyacrylamides, polystyrenes. The polymer backbone, side chains, pendant groups or combinations thereof may be fluorinated or highly fluorinated. Semiconductive polymers include polymers or copolymers derived from thiophenes, pyrroles, anilines, and polycyclic heteroaromatics. Methods for preparing buffer compositions are also provided.
摘要:
The present invention relates to electrically conductive polymer compositions, and their use in electronic devices. The compositions are an aqueous dispersion of at least one electrically conductive polymer doped with a non-fluorinated polymeric acid, at least one high-boiling polar organic solvent, and an additive selected from the group consisting of fullerenes, carbon nanotubes, and combinations thereof.
摘要:
Methods and compositions are described for electrically conductive polymer compositions having a pH greater than 1.8 and a hole transporting material.
摘要:
Aqueous dispersion compositions of polydioxythiophene, polymeric acid colloids, and water-miscible organic liquid and methods of making such compositions. The compositions are useful in organic electronic devices.
摘要:
Compositions are provided comprising aqueous dispersions of electrically conducting organic polymers and a plurality of nanoparticles wherein pH can be adjusted for improved organic electronic device performance. Films deposited from invention compositions are useful as buffer layers in electroluminescent devices, such as organic light emitting diodes (OLEDs) and electrodes for thin film field effect transistors. Buffer layers containing nanoparticles may have a much lower conductivity than buffer layers without nanoparticles. In addition, when incorporated into an electroluminescent (EL) device, buffer layers according to the invention contribute to higher stress life of the EL device.
摘要:
There is provided an electrically conductive polymer composition. The composition contains an electrically conductive polymer and a fully-fluorinated acid polymer having acidic anion groups. A first portion of the acidic anion groups are complexed with the electrically conductive polymer. A second portion of the acidic anion groups are in the form of a salt with cations, which can be inorganic cations, organic cations, or combinations thereof. The cation concentration is in the range of 5×10−5 to 0.2 mole cation per gram solids, where the solids are primarily the total of the electrically conductive polymer plus the fully-fluorinated acid polymer.