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144 条记录 (耗时 0.023 秒)

    Polycarbonate molding materials containing graft rubber
    13.
    发明授权
    Polycarbonate molding materials containing graft rubber 有权
    聚碳酸酯成型材料含有接枝橡胶

    公开(公告)号：US06890979B2

    公开(公告)日：2005-05-10

    申请号：US10220769

    申请日：2001-02-27

    申请人： Herbert Eichenauer ,  Thomas Eckel ,  Holger Warth ,  Dieter Wittmann

    发明人： Herbert Eichenauer ,  Thomas Eckel ,  Holger Warth ,  Dieter Wittmann

    IPC分类号： C08J5/00 ,  C08F279/02 ,  C08F279/04 ,  C08K5/521 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L101/00 ,  C08L67/00

    CPC分类号： C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08L55/02 ,  C08L2666/02 ,  C08L2666/14

    摘要： A thermoplastic molding composition having improved mechanical properties is disclosed. The composition contains (A) aromatic polycarbonate and/or polyester carbonate (B) at least one graft rubber, obtained by emulsion polymerization of styrene and acrylonitrile in the presence of at least two rubber latices of type (B1) and (B2) where (B1) has a particle diameter d50 of ≦350 nm, a particle size distribution range of 30 nm to 100 nm, and a gel content of 70 wt. %, and (B2) has a particle diameter of ≧350 nm, a particle size distribution range of 50 nm to 500 nm, and a gel content of ≧70 wt. %, and the difference in the average particle diameter of B1 and B2 is ≧50 nm, (C) an optional copolymer of styrene and or acrylonitrile and for methyl methacrylate and/or N-substituted maleinimide, and optionally (D) flame retardant as well as optionally conventional additives.

    摘要翻译： 公开了具有改进的机械性能的热塑性模塑组合物。 该组合物含有（A）芳族聚碳酸酯和/或聚酯碳酸酯（B）至少一种接枝橡胶，其通过在至少两种类型（B1）和（B2）的橡胶胶乳的存在下通过苯乙烯和丙烯腈的乳液聚合获得，其中（ B1）的粒径分布范围为30nm〜100nm，凝胶含量为70wt。％以下的粒径d <50nm。 ％，（B2）的粒径> 350nm，粒度分布范围为50nm〜500nm，凝胶含量≥70wt。 ％，B1和B2的平均粒径差为> 50nm，（C）任选的苯乙烯和/或丙烯腈共聚物和甲基丙烯酸甲酯和/或N-取代的马来酰亚胺，和任选的（D）阻燃剂 以及任选的常规添加剂。

    ABS polymer compositions having a uniform matt surface
    18.
    发明授权
    ABS polymer compositions having a uniform matt surface 失效
    ABS聚合物组合物具有均匀的无光泽表面

    公开(公告)号：US5605963A

    公开(公告)日：1997-02-25

    申请号：US383832

    申请日：1995-02-06

    申请人： Edgar Leitz ,  Herbert Eichenauer ,  Karl-Erwin Piejko ,  Dieter Wittmann ,  Ekkehard Frohberg

    发明人： Edgar Leitz ,  Herbert Eichenauer ,  Karl-Erwin Piejko ,  Dieter Wittmann ,  Ekkehard Frohberg

    IPC分类号： C08L9/00 ,  C08L21/00 ,  C08L55/00 ,  C08L55/02 ,  C08L51/04

    CPC分类号： C08L55/02

    摘要： ABS polymer compositions consisting ofA) 5 to 80 parts by weight of at least one ABS polymer prepared by mass polymerization or solution polymerization, having rubber particles with an average particle diameter of from 800 to 15,000 nm and a rubber content of from 1 to 20% by weight,B) 1 to 50 parts by weight of at least one ABS polymer prepared by emulsion polymerization, having an average particle diameter of from 50 to 500 nm and a rubber content of from 20 to 80% by weight,C) 0 to 70 parts by weight of at least one thermoplastic vinyl resin prepared by radical polymerization of at least two monomer components selected from styrene, .alpha.-methylstyrene, methyl methacrylate, acrylonitrile, N-phenylmaleimide andD) 0.5 to 10 parts by weight of at least one polybutadiene prepared by emulsion polymerization, having an average particle diameter d.sub.50 in the latex form of from 80 to 500 nm and a gel content of from 10 to 95% by weight.

    摘要翻译： ABS聚合物组合物，由A）5-80重量份的至少一种通过大量聚合或溶液聚合制备的ABS聚合物，具有平均粒径为800至15,000nm的橡胶颗粒和橡胶含量为1至20 B）1〜50重量份的通过乳液聚合制备的至少一种ABS聚合物，平均粒径为50〜500nm，橡胶含量为20〜80重量％，C）0 至70重量份的至少一种通过自由基聚合至少两种选自苯乙烯，α-甲基苯乙烯，甲基丙烯酸甲酯，丙烯腈，N-苯基马来酰亚胺和D）的单体组分制备的热塑性乙烯基树脂，D）至少0.5至10重量份 一种通过乳液聚合制备的聚丁二烯，其胶乳形式的平均粒径d50为80-500nm，凝胶含量为10-95重量％。

    Molding compounds containing oxetanyl groups
    20.
    发明授权
    Molding compounds containing oxetanyl groups 失效
    含有OXETANYL组的成型化合物

    公开(公告)号：US5155168A

    公开(公告)日：1992-10-13

    申请号：US633464

    申请日：1990-12-24

    申请人： Holger Lutjens ,  Dieter Wittmann ,  Karl-Erwin Piejko ,  Christian Lindner ,  Gerd Fengler

    发明人： Holger Lutjens ,  Dieter Wittmann ,  Karl-Erwin Piejko ,  Christian Lindner ,  Gerd Fengler

    IPC分类号： C08L51/00 ,  C08K5/1525 ,  C08L51/04 ,  C08L51/06 ,  C08L55/00 ,  C08L55/02 ,  C08L69/00 ,  C08L101/00 ,  C08L101/02

    CPC分类号： C08L51/04 ,  C08L69/00

    摘要： Polymer mixtures ofA) 5 to 98 parts by weight and preferably 20 to 95 parts by weight of an aromatic polycarbonate,B) 2 to 70 parts by weight and preferably 5 to 60 parts by weight of a graft polymer of resin-forming monomers on a particulate diene and/or acrylate rubber having an average particle diameter (d.sub.50) of from 80 to 800 nm and preferably from 100 to 600 nm,C) 0 to 80 parts by weight and preferably 0.5 to 40 parts by weight of an uncrosslinked thermoplastic vinyl copolymer having a softening temperature above 30.degree. C.,in which either the resin-forming monomers in B) or a monomer of the thermoplastic vinyl copolymer C) or both have contained a monomer corresponding to formula (I) ##STR1## in which R.sup.1 =H, CH.sub.3 ; R.sup.2 =C.sub.1-8 alkylene; R.sup.3 =C.sub.1-4 alkylene, in such a quantity that the structural elements containing oxetanyl groups emanating therefrom make up from 0.05 to 5% by weight and the use of the thermoplastic molding compounds.

    摘要翻译： A）5至98重量份，优选20至95重量份的芳族聚碳酸酯的聚合物混合物，B）2至70重量份，优选5至60重量份的树脂形成单体的接枝聚合物 平均粒径（d50）为80〜800nm，优选为100〜600nm的颗粒状二烯和/或丙烯酸酯橡胶，C）0〜80重量份，优选0.5〜40重量份的未交联的热塑性塑料 软化温度高于30℃的乙烯基共聚物，其中B）中的树脂形成单体或热塑性乙烯基共聚物C）的单体或两者都含有对应于式（I）的单体（I） ）其中R1 = H，CH3; R2 = C1-8亚烷基; R3 = C1-4亚烷基，其含有由其发出的氧杂环丁烷基的结构元素占0.05至5重量％，以及使用热塑性模塑料。